主要产物

Aside from pancreatic enzymes activiation and autodigestive process, recent investigations have established that the upregulation of inflammatory mediator are believed to be the critical steps in the progression of mild pancreatitis to severe pancreatitis. Tumor necrosis factor-, ThyomboxaneA2 ,ProstaglandinsI2 are all important inflammatory mediator. TNF-( is one of cytokines. It is important to the over-production of ICAM-1,VCAM-1, TXA2 andPGI2. The ICAM-1 and VCAM-1 mediate both leukocytes adhesion and migration through the endothelium into tissues to connect with injuried target cells. The TXA2 and PGI2 are the production of arachidonic acid. They are responsible for the tissue ischaemia.

肿瘤坏死因子（Tumor necrosis factor-， TNF-、血栓素A2（ThyomboxaneA2，TXA2），前列环素（ProstaglandinsI2，PGI2）均是炎症反应中重要的炎性介质，其中肿瘤坏死因子-是非常重要的细胞因子之一，它由活化的单核细胞产生，在细胞间黏附分子（Intercellular adhesion molecule-1，ICAM-1）及血管细胞黏附分子(Vascular cell adhesion molecule-1，VCAM-1的表达、血栓素A2及前列环素过量生成方面起着重要的作用，前两者是介导白细胞与内皮细胞黏附，迁移于组织并与受损的靶细胞相结合的主要媒介，是炎症反应中的重要介质，后两者是花生四烯酸的代谢产物，亦是重要的炎性介质，参与构成血液循环障碍。

The synthesis of high purity azelaic acid through oxidation of oleic acid with 50% hydrogen peroxide was studied by using tungstic acid as a catalyst and ionic liquid as a basic reaction system .

以油酸为原料，50%的H2O2为氧化剂，在离子液体作为主要溶剂的条件下，采用钨酸为催化剂所得中间产物用自制的过氧乙酸继续氧化裂解合成了高纯度壬二酸。

The major products of the thermal decomposition of silver behenate were metallic silver and behenic acid.

山嵛酸银的主要热分解产物是金属银和山嵛酸。

The thermal behavior of silver behenate has been studied by infrared spectroscopy, X-ray diffraction, combined thermogravimetry-differential thermal analysis-mass spectrometry. The results indicated that complicated phase transitions took place while heating silver behenate,but there were two distinct thermal transitions. During the first transition at 138°C, the alkyl chains of silver behenate were transformed from an ordered into disordered state.

通过采用粉末X射线衍射、红外光谱、热重-差热分析与质谱联用技术，对山嵛酸银纳米晶体的热行为研究发现，山嵛酸银受热发生了一系列相转变，它有两个明显的突变：即在138℃左右，山嵛酸银的烷基链从高度有序转变为无序状态；在231℃左右，山嵛酸银发生了热分解，其主要分解产物为银纳米粒子和山嵛酸。

This thesis includes five parts as follows.1. The backgrounds and some relative concepts of this work are briefly introduced. The photochemistry of benzamides and compounds with thiourea functional group is also concisely reviewed.2. Total of fourteen benzamides with different substituted groups have been synthesized and structurally characterized. Better photoreaction time for that kind of compounds at given concentrations is confirmed by tracking its'UV spectrum and GC chromatogram. A representative dibenzophenone photoproduct has been determined by X-ray crystallography. The mechanisms of photoreaction of benzamide have been proposed.3. Total of seven N-chloro(phenylmethylenebenzenamines with different substituted groups and sixty-one thiourea derivatives have been synthesized and structurally characterized.

论文的主要内容如下：1、简要介绍本论文工作的研究背景，并对苯甲酰胺和具有硫脲官能团类化合物的光化学研究进展进行简要的总结。2、合成与表征了14个具有不同取代基的苯甲酰胺类化合物，利用紫外光谱和气相色谱确定了此类化合物较佳光照时间，测定了一个具有代表性光解产物的单晶结构，提出了苯甲酰胺类化合物的光反应机理。3、合成与表征了7个带有不同取代基的氯代苯甲酰亚胺中间体及61个硫脲衍生物，测定了两个具有代表性化合物的单晶结构。

The main intermediates were also identified by GC-MS, and they were organic acid and benzoquinone.

GC-MS分析表明，苯酚降解的中间产物主要为苯醌和有机酸。

The main intermediates were also identified by GCMS,and they were organic acid and benzoquinone.

GCMS分析表明，苯酚降解的中间产物主要为苯醌和有机酸。

After reaction for 30 minutes, the removal rate of TOC is 40% lower than that of aniline, which shows a series of intermediate by-products, mainly benzoquinone, as detected by HPLC and IC, are resulted from the decomposition of aniline.

反应30min后，TOC 去除率比苯胺去除率低40%左右，表明伴随着苯胺的分解，生成一系列中间产物，通过HPLC和IC检测主要为苯醌等。

After reaction for 30 minutes, the removal rate of TOC is 40% lower than that of aniline, wh ic h shows a series of intermediate by-products, mainly benzoquinone, as detected by HPLC and IC, are resulted from the decomposition of aniline.

反应30min后，TOC去除率比苯胺去除率低40%左右，表明伴随着苯胺的分解，生成一系列中间产物，通过HPLC和IC检测主要为苯醌等。

Bilirubinic decomposition product has more powerful antioxidation than vitamin E;dissociative ferrum also plays roles on harmful product such as hydroxy radical and superoxide anion etc;As an important signal molecules,CO play significant roles on neuron information transfer and vascular tone regulation;people pay attention to HO,which is the main enzymatic system producting endogenous CO increasingly.

其中胆绿素的分解产物具有较维生素E更强的抗氧化作用；Fe~(2+)参与催化生成有害的活性氧代谢物，如羟自由基，超氧阴离子等；CO作为一种气体信使分子，在神经元信息传递和血管紧张度调节中起重要作用，HO作为产生内源性CO的主要酶系统日益受到关注。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。