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The results of batch experiments showed that the anaerobic biodegradation kinetics of 2-CNB and 4-CNB by granular sludge were follwed by first-order reaction. The nitro groups of 2-CNB and 4-CNB were more easily attacked by electron than chlorines and they were reductively biotransformed to amino groups under anaerobic conditions. The acclimated anaerobic granular sludge, which could dechlorinate 4-chloroanline to aniline, showed that it had the ability of para-dechlorinating. The anaerobic biodegradating on pathway of 2-CNB and 4-CNB were suggested as follows:AbstractIn ZVI(zero-valent iron, Fe0)-reduction system, the nitro groups of 2-CNB and 4-CNB were reductively transformed to amino groups.

2分批试验结果证明,颗粒污泥降解2-CNB和4-CNB遵循一级动力学,在厌氧条件下,CNB发生序列的硝基还原与脱氯作用,苯环上的硝基比氯原子更容易受到亲电子攻击,发生还原反应生成氨基;所获得的颗粒污泥具有对位脱氯活性,可使4-CA进一步脱氯形成苯胺。2-CNB和4-CNB厌氧降解的建议性途径为: ZVI(Zero-valentiron)对2-CNB和4-CNB的作用主要是将苯环上的硝基还原为氨基;在ZVI与污泥共还原转化体系中,ZVI对氯代硝基苯的硝基转化具有一定的促进作用,但因ZVI对中间产物的吸附特性,终产物形成速率趋慢。

The stable polymers was formed through thechemical crosslinking reaction between the hydrolysates of semicellulose and the decompositionproducts of lignin.

半纤维素水解产物与木素的降解产物发生化学交联反应,形成了稳定性极高的体型聚合物,降低了木材的吸湿性,使得压缩变形得以固定,这应该是压缩变形固定的主要原因。

The lime slaking rate is the important factor of the quality of the hydrated production.

消化产物的特性主要有生石灰的转化率、消化产物的粒径和比表面积等。

The cytochemical localization of POD showed that the peroxidase was found in cells ofboth cultivars after inoculation. The activity of POD in resistant cultivar was higher than that innot only the uninoculated controls but also the inoculated susceptible ones and localized morewidely, such as localized in mesophyll cell wall, intercellular spaces, membranes of chloroplastand mitochondrion and vacuolar membrane. Whereas the POD in susceptible cultivar waslocalized mainly in cell walls but little in plasma membrane with a lower range and intensitythan that in resistant cultivar.

对过氧化物酶的细胞定位研究发现,无论抗病杨树还是感病杨树,接种后均发现细胞中有过氧化物酶反应产物,通过分析发现,毛白杨过氧化物酶的活性不仅明显高于未接种的对照,也明显高于接种处理后的北京杨,并且定位更广泛,在细胞壁、细胞间隙、叶绿体膜、线粒体膜及液泡膜上均有大量定位,而北京杨酶反应产物主要分布于细胞壁上,在细胞膜、核膜局部有少量定位,定位范围及强度均小于毛白杨。

Sucrose is not only the product of photosynthesis, but also the major transport form for photosynthetic carbon assimilates.

蔗糖是绿色植物光合作用的最终产物之一,也是绝大多数高等植物体内光合产物运输与分配的主要形式。

Comparing with the result of methyl iodide in intense laser field, some differences are observed:(1) at the same laser field intensity, the highest charged fragment ion of methyl bromide was Br(superscript 3+), lower than I(superscript 6+) of methyl iodide;(2) the dehydrogenation channel was observed in the multiphoton dissociation or Coulomb explosion of methyl bromide, but was not observed in the case of methyl iodide;(3) HBr(superscript +) was observed, but there was no similar channel in the case of methyl iodide;(4) for methyl bromide, the valid charge distance of Coulomb explosion increases with the product of p and q; while in the case of methyl iodide, the distance remained almost the same;(5) the producing channel of CH(superscript + subscript m)(m=0, 1, 2) is different from the ionization-dissociation of methyl iodide in which the stepwise dissociation of CH3(superscript +) was thought to be the main channel, CH(superscript + subscript m)(m=0, 1, 2) of methyl bromide are mainly from the products of the direct dissociation of the dehydrogenated parent ions instead of the stepwise dissociation of CH3(superscript +).

与碘甲烷在强场中的实验结果对比发现:(1)在相同的激光场强下,碘甲烷电离解离的最高价碎片离子为I(上标 6+)而溴甲烷为Br(上标 3+);(2)溴甲烷质谱中存在母体离子的脱氢产物CHBr和CHBr(上标 2+),而对于碘甲烷,没有检测到这些通道,C-I键首先断开;(3)质谱中存在H^79Br和H^81Br,而碘甲烷的电离解离中不存在HI产物;(4)溴甲烷库仑两体爆炸的有效电荷间距随着两碎片电荷乘积的增大而增大,而对于碘甲烷此间距几乎不随电荷乘积变化;(5)CH(m=0, 1, 2)的主要生成通道可能与碘甲烷不同,不是来自CH3的顺序脱氢,而是来自脱氢母体离子的直接解离。

The corrosion products of aluminum exposed in the SO2-containing atmosphere are mainly of sulfates, and is therefore it is more serious corrosion in this environment.

对腐蚀产物结构的测定,在含SO2的气氛中铝的腐蚀产物主要是由硫酸盐组成,因而其腐蚀较为严重。

Human fibroblast interferon mRNA was prepared from poly I:C-cycloheximide superinduced human diploid cells by phenol-octanol exhaustion method followed by oligo-cellulose chromatography.

其主要实验根据是:超诱导细胞mRNA含量明显高于正常细胞;干扰素mRNA在非洲鲫鱼卵母细胞内转译的产物具有明显的抗病毒活性;转译时~14C-苯丙氨酸的掺入明显高于正常细胞;种属特异性实验及酶的敏感性实验证明转译产物中存在的抗病毒物质是一种人的干扰素蛋白质。

The main by-product s and their separation and recovery technologies were discussed for cyclohexanone gas-phase Beckmann rearrangement.

探讨环己酮肟气相Beckmann重排主要副产物及其分离回收方法,研究1-氮杂-2-乙氧基-1-环庚烯、1,3,4,5-四氧吖庚因-2-酮及其同分异十句体等副产物回收利用生成已内酰胺的方法。

The experiments for determining the reaction kinetics of Daqing atmospheric residue were performed in a continuous flow, expanded bed rector. Four-lumped reaction kinetic model was developed to account for various feed and product fractions of Daqing atmospheric residue (gases, gas oil, residue and coke). The amounts of olefins and alkyls in the gas products were further analyzed to determine reaction kinetics of gas product distributions. Hence, a combined five-lumped reaction kinetic model was obtained for catalytic pyrolysis of Daqing atmospheric residue. The kinetic constants both in four-lump model and five-lump model were evaluated. A simulator for catalytic pyrolysis process was developed by incorporating the five-lumped kinetic model into the hydrodynamic flow model.

其次利用改进的固定流化床装置考察大庆常压渣油催化裂解反应规律,筛选反应工艺参数;分析了催化裂解工艺存在的主要化学反应类型,提出了渣油一次反应和二次反应网络图;将反应原料油作为单独集总组分,而将产品中的轻质油、气体、焦炭分别作为集总,从而建立了四集总动力学模型;在此基础上,把气体产物中的目的产物低碳烯烃独立划分,得到五集总动力学模型;采用最小二乘法分析实验数据,分别得到四集总动力学模型和五集总动力学模型中各集总间相互反应转化的反应速率常数。

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