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临界温度

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The coexistence curves and light scattering data for a critical solution of benzonitrile + octane have been reported. The critical exponents relating to the difference in the density variables between two coexisting phasesβ, the osmotic compressibilityγ, and the correlation length v have been deduced and the values were consistent with the 3D-Ising value in the range close to the critical point. The experimental results of the coexistence curves have also been analyzed to examine the Wegner correction terms and the behavior of the diameter of the coexistence curves.

用折射率法和不同角度的光散射法测量了苯甲腈+正辛烷二元体系在临界温度附近的液-液共存曲线和一相区不同温度下的渗透压缩系数及关联长度,得到与共存曲线相关的临界指数β,与渗透压缩系数相关的的临界指数γ和与关联长度相关的的临界指数γ,发现在近临界点体系符合3D-Ising模型,讨论了共存曲线直径和Wagner校正项。

The finite difference method is adopted to calculate the temperature field on cross-section of the column, the critical temperature and the critical time, the thickness of fire resisting covering of CFST columns, All of the results were verified by experiments.

简要地介绍了钢管混凝土的耐火性能,分析了影响耐火度的因素以及用有限差分法计算火灾时的构件截面的温度场、构件的临界温度和临界时间、防火涂层厚度的结果。

Only when heat reservoir temperature is higher than critical heat reservoir temperature can the performance of GAX cycle be improved.

得出了GAX循环性能与热源温度之间的变化关系:在蒸发温度为3 ℃、冷却水为32 ℃的条件下, GAX循环系统最低临界热源温度为110 ℃;在蒸发温度为3 ℃时, GAX循环系统最低临界热源温度值随冷却水温度的提高而升高;只有热源温度高于临界温度值时, GAX循环性能系数才能得到提高。

Isotropy s-wave model is adopted and the critical superconducting temperature is determined by chemical potential and Thouless condition.

从我们的计算结果可以看出,电子比热系数在临界温度以上区域已随温度的减小而减小,这表明在临界温度以上的温区有赝隙存在。

The optimum reaction conditions were found finally. The results showed that the suitable conditions are under methanol solvent reaction temperature 40℃,the concentration of catalyzer TS-1 0.6%.,reaction time 60 minutes,propylene pressure 0.4Mpa under methanol solvent.Under Supercritical fluid system,the reaction temperature was 33.7℃(supercritical and near critical temperature),the reaction pressure was 7.58Mpa(near critical pressure and critical pressure range. propylene ), propylene pressure 0.65Mpa, reaction time 45min, cosolvent molality 4%.

而超临界体系下反(来源:4e56ABC论文网www.abclunwen.com)应温度适宜在近超临界和临界温度(33.7℃)以上,反应压力也是接近临界压力或者处于临界压力范围(7.58Mpa),丙烯压力是0.65Mpa,反应时间45min,共溶剂甲醇摩尔浓度4%,在此反应条件下,反应的转化率98%,选择性96%,收率94%,与传统条件相比较,收率提高了20%左右。

The saturated liquid densities of HFC227ea and the vapor-liquid coexistence curve were measured, the critical temperature and critical density were determined by the critical opalescence phenomenon, and then the critical pressure was determined by vapor pressure equation.

测量了HFC-227ea饱和液体密度和临界区的气液共存线,确定了HFC-227ea的临界温度、临界压力、临界密度;推算了HFC-227ea的饱和气体密度,并验证了其可信度;关联了饱和气液密度,提出了高精度的HFC-227ea饱和气液密度关联式;关联了临界区气液共存线,可精确再现HFC-227ea临界区性质,并根据临界幂定律导出了HFC-227ea的临界指数和临界幅值。

The critical parameters were determined as ρc = 442± 4kg/ m3, TC = 346.16 ± 0.05K and pc = 3.781± 0.006MPa by observing the disappearance of vapor-liquid meniscus and the critical opalescence .

基于汽液界面消失位置和临界乳光现象,测定了临界密度ρ_c=442±4kg/m~3、临界温度T_c=346.16±0.05K,由本文蒸汽压方程算出临界压力ρ_c=3.781±0.006MPa。

The light scattering data were well described by the crossover model proposed by Anisimov and Sengers, and the effective critical exponentsγandυshowed nonmonotonic crossovers from the 3D-Ising values to the mean-field ones as the temperature departed from the critical point. The coexistence curves exhibited that the values of effective critical exponents for the order parameter of the refractive-index decreased as the distance from the critical point increased, however after the regular terms were subtracted, the nonmonotonic crossovers from Ising to mean-field critical behavior were exhibited. The influence of sodium bromide on the trend of the crossover was small.

静态光散射数据符合Sengers和Anismov等提出的临界跨接理论,关联长度和渗透压缩系数的有效临界指数存在非单调跨接,盐对于跨接程度的影响不明显;共存曲线研究发现,随着偏离临界温度,折射率的有效临界指数逐渐减小,但是当与共存曲线相关的正规项的影响被排除以后,体系表现出从3D-Ising到平均场行为的非单调跨接,盐对于跨接程度的影响不明显。

First, the mixing rule of temperature calculation equation was modified. The content and acentric factor of second component were introduced into the interaction parameter, and a new equation of critical temperature for mixture were set up as

对二元体系临界温度计算公式中的混合规则进行修正,首次将组成和表示物质结构的偏心因子引入其中,建立了温度相互作用参数的表达式和新的二元体系临界温度计算公式。

Firstly, based on the analysis of viscosity data, combined with other methods, a new method is proposed to calculate the viscosity of saturated vapor of halides. The calculation can be done on condition that the critical temperature, critical pressure, critical specific volume, molecular weight and the eccentric factor are known.

在理论研究上,一方面对于卤代烃的饱和蒸气粘度进行了研究分析,并结合其他理论推算方法的优点,提出了一种推算卤代烃的饱和蒸气粘度的新方法,该方法在已知临界温度、临界压力、临界比容、分子质量、偏心因子的情况下,便可以计算在有效对比温度范围内的饱和蒸气的粘度,本方法的适用范围是对比温度T〓在0.5-0.95之间,其对饱和蒸气粘度推算的平均偏差不超过5%。

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