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The results show that this reaction proceeds in two step: 1 silylene and formaldehyde form an intermediate complex, which is a kind of exothermal reaction with no barrier; 2 the intermediate complex isomerizes to sive the product. The barrier for the second step is 51.4kJ·mol^-^1 at MP2/6-31G^*//6-31G^* level (with zero-point energies correction). In view of dynamics and thermodynamics, it is between 300~400K that the reaction will have not only larger spontaneous tendency and equilibrium constant but also quicker reaction rate.

结果表明,此反应历程由两步组成:1硅烯与甲醛生成一中间配合物,是一无势垒的放热反应,2中间配合物异构化为产物,此步势垒经零点能校正后只有51.4kJ·mol^-^1(MP2/6-31G^*//6-31G^*);从热力学和动力学的综合角度考虑,该反应在300~400K温度下进行为宜,如此,反应既有较大的自发趋势和平衡常数,又具有较快的反应速率。

The regulating reservoir water leakage enters the oxygen unit, through the biological degeneration function, enable the organic pollutant to obtain the thorough degeneration, the good oxygen unit enters the water to enter the precipitation unit, the precipitation unit water leakage flows automatically enters the middle basin; In the middle basin by the pump promotion to the micro flocculation unit, in the water before the residual soluble organic matter and the filtration throws the coagulant response production suspended solid which adds through the filtration pot filtration, the micro flocculation filtration water leakage enters the disinfection area, achieves the sterilization goal in the disinfection area using the chlorine dioxide strong oxidability.

调节池出水进入好氧单元,通过生物的降解作用,使有机污染物得到彻底的降解,好氧单元进水进入沉淀单元,沉淀单元出水自流进入中间水池;在中间水池由泵提升至微絮凝单元,水中残留溶解性有机物与过滤前投加的混凝剂反应生成悬浮固体通过过滤罐滤除,微絮凝过滤出水进入消毒区,在消毒区内利用二氧化氯的强氧化性达到杀菌目的。

Wood could be liquefied into soluble reactive intermediates, which could further reactedwith phenol or by themselves. Phenolation and recondensation were a pair of competingreactions. Decomposition, phenolation and recondensation dominated the whole liquefactiondynamic process and determined the structural characteristics of liquefied wood.

4木材组分在液化过程中逐渐分解为较小分子量的液化中间产物,这些中间产物的活性较高,可以继续与苯酚或互相之间发生酚化或再缩聚反应,酚化反应和再缩聚反应是一对互相竞争的反应,降解、酚化和再缩聚三种反应主宰着整个液化动力学过程,也决定着液化产物的结构特征。

Some writers use the term "intersexuality" very broadly and extend it to cover relatively simple conditions such as a very prominent clitoral glans or a very small penis or hypospadia or even undescended testicles .

某些作者使用术语&中间性&非常宽泛,把它扩展到一些相比而言相对简单的生理结构特徵的改变,譬如把非常突出的阴蒂头或非常细小的阴茎或尿道下裂甚或隐睾症等也称为&中间性&。

Previous studies show different interneuron changes in different models of epilepsy, which are focused on the onset of epilepsy, but not the onset of the spontaneous recurrent seizures.

在不同癫痫模型和患者海马观察含PV、CR、CB中间神经元数量变化的报道已有较多,但既往的研究着重于颞叶癫痫的始发过程上,而对颞叶癫痫发生后向自发性复发性发作演变过程中这三种中间神经元变化的研究较少。

Our society hasn't achieved ideal olive-shape, however expanding at utmost the middle class is one of the policies of our Party and government.

我国社会目前还远没达到理想的两头小、中间大的橄榄型社会,但是极力扩大中间阶层的人数却是我们党和政府的强国政策之一。

In the thesis, the PKI end system realizes application security and variety by encapsuling SSL protocol into application layer and offering the application interface in it directly.

同时,安全中间层着眼于本地信息安全,对文件存在状态做全局性管理,并依据中间件实现原理,设计了网络传输发送和接收的安全代理功能,并支持对网络数据的统一调配,同时还研究了算法的相对安全性和用户的加密算法接口。

This article according to the characteristic of traditional signature and stamper, combinic the demands of signature and seal in e-Government-affair work information system, inosculates the technology of middleware and e-Government-affair security, makes use of Object Oriented and component technology, integrates correlation knowledge of compositive cryptogram, PKI, seal digital image, ActiveX etc, studies and achieves digital e-signature-seal middleware based on Web which is used in Internet/Intranet environment.

本文根据传统签名、盖章的特点,结合高校、政府等办公信息系统中的盖章签名需求,把WEB安全技术和中间件技术相融合,利用面向对象和组件技术,集成密码学、公开密钥体系PKI、印章数字图像、ActiveX控件等相关知识,研究并设计了一个应用于Internet/Intranet环境中的基于WEB的电子印章中间件。

Such a process includes the preparation of an initial stabilized peptized solution including a titanium precursor material, an organic solvent, an acid agent, the mixing of said initial solution with a large amount of water, the pH of the obtained intermediate solution being less then 3, subjecting said intermediate solution and its dispersion to a heat-treatment, the exchange of water by an organic solvent with low surface tension to obtain a final solution that is finally dispersed.

这样一种方法包括制备包含钛母体材料、有机溶剂、酸介质之开头的稳定化胶溶溶液,将此起始溶液同大量水混合,所得到中间溶液的pH小于3,使此中间溶液及其分散体系经受热处理,用低表面张力的有机溶剂更换水来获得末了加以分散的最终溶液。

The effects of various correction elements and regulation parameters on the reheat steam turbine and their regularity have been discussed in detail according to a dynamic analogy test of the power-frequency electro-hydraulic control equipment for reheat steam turbines.

在中间再过热汽轮机功—频电液调节装置动态模拟试验的基础上,本文着重探讨电液调节装置的各校正元件、各调节参数对中间再过热汽轮机的影响及其规律性,并提出主要调节参数的合理范围。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力