中间体

The Ni and Zn-doped spiculate α-FeOOH were prepared by the coprecipitation method and citric acid method using FeCl2、Zn(NO3)2、Ni(NO3)2 and NaOH as raw material and spiculate α-FeOOH as intermediate. Then they successively were enwraped by citric acid complex of the Ni and Zn and heat treated to get spiculate nano-Ni0.5Zn0.5Fe2O4. The particles size and slenderness ratio of spiculate nano-Ni0.5Zn0.5Fe2O4 were successfully controlled by the doped mass of Ni and Zn in the coprecipitation process.

以FeCl2、Zn(NO3)2、Ni(NO3)2和NaOH为原料，借助针状α-FeOOH做为中间体，有效的把共沉淀法和柠檬酸法相结合，制得掺有镍和锌的针状纳米α-FeOOH，在其表面包裹镍和锌的柠檬酸络合物后，经热处理制得了针状的纳米Ni0.5Zn0.5Fe2O4 ，并通过控制共沉淀法过程中镍和锌的掺入量，有效的控制了针状纳米Ni0.5Zn0.5Fe2O4 的粒径和长径比。

Besides these, the steric bulk was also important for the separation of the isomers of camptothecin synthetic intermediate.

此外， 空间位阻在喜树碱中间体的光学异构体分离中也起了一定的作用。

As for the ester exchange reaction on phosphorus, it was found that N-phosphoryl histidine the fastest one among all of the N-phosphoryl aminoacids. The results studied by MNDO method indicate that due to theparticipation of imidazole group, the formation of hexa-coordinatephosphorus intermediate made the iso-propoxyl which is opposite toimidazole group more active than the other ones and much easier to leave.When iso-propoxyl left, a new penta-coordinate phosphorus intermediate wasformed, and it is sterically favorable to be attacked by an alcohol from theopposite direction of imidazole.

对于磷上酯交换反应，实验中发现N-磷酰组氨酸反应速度明显高于其它N-磷酰氨基酸，理论研究表明，侧键咪唑基参与下六配位磷中间体形成后，位于咪唑基对面的异丙氧基反应活性大大提高，即从咪唑基的对面位置发生异丙氧基的离去和另一分子醇的进攻，在能量上和空间上都是有利的。N-磷酰丝氨酸的磷上酯交换反应有着类似的特点。

The potential of succinic acid as an important chemical intermediates had been realized and fermentation is one of the best ways to make it possible in economical aspect.

琥珀酸作为一种重要的化学中间体的潜力已经为人们所认识，而发酵法生产琥珀酸是使这一潜力变为经济上可行的最好方法之一。

Keywords acylhydrazone;sulfamic acid;N-aminophthalimide;fine chemical intermediate

酰腙； 氨基磺酸； N-氨基邻苯二甲酰亚胺；精细化工中间体

Hollow fiber membrane extraction is more advantageous in environmental treatment through removal of sulfanilic acid from wastewater.

通过去除水中对氨基苯磺酸的实验表明，中空纤维膜萃取在治理染料中间体废水方面具有非常明显的优势。

Aliphatic diamine sulphonate was synthesized by the reaction of ethylenediamine with sodium 2-chloroethanesulfonate.

乙二胺基乙磺酸钠是水性聚氨酯合成中重要的亲水性扩链剂，又可作为有机中间体、生化试剂应用于其它领域。

Whereafter,we achieved a highly enantioselective approach towards the synthesis ofβ-substituted chiral ketones utilizing Oppolzer\'s sultam as chiral auxiliary.The-and-enantiomer of target chiral ketones were obtained with up to 99%ee.

应用手性辅剂樟脑磺内酰胺的手性诱导作用，高对映选择性地合成了一系列β-芳基取代手性酮，其ee值高达99%，可用于药物及其它精细化工中间体的不对称合成。3。

Meanwhile, our calculations suggest that the tautomeric equilibrium should be via the same intermediate.

同时，各互变异构体可能经过同一中间体。

The calculations of harmonic vibrational frequencies with B3LYP/6-31Gtheoretically supported that o-dinitrosobenzene is the intermediate of "self-self"tautomeric rearrangement of benzofuroxan.

谐振动频率的B3LYP/6-31G计算还支持了邻二亚硝基苯为苯并氧化呋咱&自-自&互变重排反应的中间体。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。