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The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

通过研究阐明:紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移,νC=O振动吸收峰在聚合24h后红移;TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01,α为2.28,优于其它功能单体参与得到的聚合物识别特性;TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间,作为色谱固定相具有良好的通量和低的柱压;在乙腈流动相中,TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动,低温有利于分子印迹固定相分离甾醇结构类似物;TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融,Tp=257.40℃,聚合物CP的降解温度在267.79℃,MIP降解温度在343.11℃,制备的固相微萃取头初步经GC/MS 270℃的耐热性测定;不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应;分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性,可作为此类化合物的吸附材料,特别对孕酮强保留的富集特性,可作为孕酮的选择性识别吸附剂,其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡,具有作为传感器核心敏感材料的潜力;对比萃取奶粉中17β-雌二醇性能,MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留,回收率依次为85.5%,43.7%和30.7%。

Gower VC, Thompson AM. Localization of inducible heat shock protein mRNA in the guinea pig cochlea with a nonradioactive in situ hybridization technique.

但在正常对照组和GM组之间,HSP70 在SV的表达差异更显著[3],即在GM耳中毒后, HSP70在SV中的表达比在SGC中的表达强。

Firstly, the eigenvalue problem of a class of second order elliptic equation with critical potential and indefinite weights is considered. Then, using critical point theory, Trudinger-Moser inequality and the properties of the first eigenvalue, we prove the existence of a nontrivial solution for a class of nonlinear elliptic with critical potentialand indefinite weights in R~2. Secondly, we prove the existence of nontrivial solutions for a class of subcritical and critical elliptic systems with indefinite part in R~2 byusing a generalized linking theorem, Trudinger-Moser inequality and concentration-compactness principle.5. The existence of at least three weak solutions for discrete boundary value problem is established by using a three critical point theorem introduced by Ricceri.

首先,讨论了R~2中一类带不定权且含临界位势的二阶椭圆型方程的特征值问题,并借此特征值问题的第一特征值性质,利用山路引理及Trudinger-Moser不等式,证明了R~2中一类带不定权且含临界位势的非线性椭圆型方程非平凡解的存在性;其次,利用广义环绕定理,Trudinger-Moser不等式及集中列紧原理,得到了R~2上一类具有强不定部分的半线性椭圆型方程组在非线性项分别为次临界增长和临界增长情形下非平凡解的存在性。

Linear correlation was analyzed by diluting HBsAg-positive samples with normal healthy sera in series.

正常人血清标本中分别加入一定比例的上述样品至S/Co比值在阈值并重复检测40次作重复性实验;气泡检出试验是在样品中加入50μL气体并重复检测20次;正常人血清连续系列稀释HBsAg强阳性标本并检测线性范围试验。

Under the male-supremacy system in ancient western society, the marital rape in the criminal-law theory could undoubtedly have not a leg to stand on with the "male immunity" supported by "wife's commitment" and other arguments. Since the latter half of the 20th century, when a feminist movement for equal political, economic and sexual rights swept across western countries with an irresistible momentum in the on-going industrial revolution, people have begun to cast doubt upon the "male immunity" and write off the principle in the crime of rape.

古代西方在传统夫制社会下的男强女弱、男主女从的模式之下,刑法理论中的婚内强奸难以占得一席之地,主要缘于以"妻子承诺论"和"促使女方报复论"为理论支撑的"丈夫豁免"。20世纪中后期以来,在工业革命的背景下,西方各国开始了一场规模空前、势不可挡的以追求政治、经济、性权利平等为目标的女权运动,人们开始逐步反思检讨"丈夫豁免"的正当性,摒弃了强奸罪中的"丈夫除外"原则。

It was showed that the imprinted polymer has good affinity and marked selectivity for the template molecule, and can be used to determine the trace amount of TBZ in biological and environemtal samples in an off-line mode. This methodology may be important for accurate investigation and determination of TBZ levels in the environmental and biological matrices.

研究结果表明,戊唑醇分子印迹聚合物对模板分子具有很强的亲和性和显著的选择性,可离线富集各种环境和生物样品中痕量的戊唑醇,在戊唑醇检测中具有实际的应用价值。

In the Triassic-early Jurassic,the emplacement mechanism of monzonitic granite and orthoclase granite is domina...

晚三叠世-早侏罗世二长、正长花岗岩体就位过程中构造扩展机制起主导作用,岩浆底辟作用也较强;早侏罗世碱性花岗岩体岩浆就位过程中以强力的气球膨胀作用为主,构造扩展机制为辅。

In the Triassic-early Jurassic, the emplacement mechanism of monzonitic granite and orthoclase granite is dominated by tectonic extension and the diapirism is strong. The strong balloon swelling is dominant and tectonic extension is subordinate during the emplacement mechanism of early Jurassic alkali granite.

晚三迭世-早侏罗世二长、正长花岗岩体就位过程中构造扩展机制起主导作用,岩浆底辟作用也较强;早侏罗世碱性花岗岩体岩浆就位过程中以强力的气球膨胀作用为主,构造扩展机制为辅。

Pepsin: Powerful enzyme in gastric juice that partially digest s proteins in food.

胃蛋白:胃液中一种消化能力极强的,能部分消化食物中的蛋白质。

In university, I found my aim and pertinence in math learning and focused upon the application of math in the field of communication.

在之后的大学学习生活中,我对相关方面的数学学习有了更强的针对性和目的性,更加侧重于在通信领域中的实际应用。

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Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气,收缩臀部肌肉;拱起身体,尽量抬起头来,右腿伸直朝向天花板(膝微屈,以避免肌肉紧张)。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化,但却比去年同期高8%。

However, to get a true quote, you will need to provide detailed personal and financial information.

然而,要让一个真正的引用,你需要提供详细的个人和财务信息。