丙酮醛

While acetone was used as substrate, the configuration of aldol product was related to the amount of water.

而对丙酮与芳香醛的反应，发现选择性和Aldol产物的构型与所用水量有关。

Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体，初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用，20℃和20mol％催化剂量下，获得了32.5％ee和72％收率的产物。

The catalytic efficiency of 7a was the best when acetone was used as Aldol donor, and the Aldol products were obtained with up to 78% ee in the presence of 10 mol% 7a.

对丙酮与醛的反应，7a的催化效果最好，在10％催化剂存在下产物ee值高达78％。

The condensation reaction of citral with acetone catalyzed by aqueous sodium hydroxide solution to give pseudoionone was studied in detail.

前言 丙酮和柠檬醛在氮氧比钠水溶液的催化作用「生成假性紫罗兰酮是国内外应用得较为f一泛的合成紫罗兰酮的方法。

This paper uses orthogonal experiment to research on the synthesis technique of pseudo-ally lionone from citral and allylacetone. The product structure had analysed by IR.

利用正交试验法对柠檬醛和烯丙基丙酮合成假性烯丙基紫罗兰酮的工艺进行了研究，并用红外光谱对产品进行了结构分析和鉴定。

Using citral and acetone as starting materials, the aldolcondensation was carried out, and then the final product wasobtained by distillation under vacuum.

以柠檬醛和丙酮为起始原料进行醇醛缩合反应，经减压蒸馏得到最终产物。

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物，其结构分别为二氢松柏醇二氢对羟基桂皮酸酯，香草醛，罗布麻宁，对羟基苯甲醛，丁香醛，丁香酸，丁香乙酮，α-羟基丁香丙酮，松柏醛，二氢松柏醇，2-羟基苯丙醇和3-羟基－4-甲氧基苯乙醇。

Preparation of the lateral chain-4-benzyloxy-3-hydroxy butyronitrile is introduced as the substrate, the REFORMATSKY reaction is performed, then obtains the dicarbonyl ester, in the structure of which containing a chiral hydroxyl group, then performs the chiral reduction, take off the benzyl group after the protection reaction with acetonylidene,then obtains the lateral chain by oxidation.

手性侧链醛的合成：采用-4-苄氧基-3-羟基丁腈作为底物，通过REFORMATSKY反应缩合得到含有手性羟基的二羰物酯，再手性还原，丙酮叉保护后氢解脱苄，最后氧化得到侧链醛。

Heptanone was synthesized from n - butyl aldehyde and propanone via cross al-dol condensation, dehydration, catalyzed hydrogenation.

用氧化镁或氧化钙负载氢氧化钠固体碱作缩合催化剂，钯/炭作为加氢催化剂，由丁醛和丙酮经交叉酮醛缩合、脱水、催化加氢制得2-庚酮。

Some technologies,including olefines from methanol,oxalates and ethylene glycol from carbon monoxide,carbon dioxide-based polymers,chemicals from the syngas prepared by biomass gasification,acetone and butanol by fermentation,and chemicals from acetylene,ethanol,glycerol,furfural,hydroxymethyl furfural and starch,were reviewed.

包括甲醇制烯烃，一氧化碳制草酸酯和乙二醇，乙炔化学品，二氧化碳聚合物，生物质气化合成化工产品，发酵法生产丙酮、丁醇，乙醇衍生化工产品，甘油合成化工产品，糠醛和羟甲基糠醛合成化工产品，淀粉合成化工产品等重要的石油替代化学品生产技术被介绍。

Now, however, all children continue in "comprehensive" schools, and the eleven-plus determines which courses of study the child will follow.

然而现在，所有的孩子都要在综合学校继续学习，所以这次考试只是决定他们将要学习哪些课程。

Cultivatable land , and led to a general recognition that development must not be carried at the cost of agriculture .

城区的迅速扩大在很多情况下侵占了宝贵的可耕地，使人们普遍认识到发展不能以牺牲农业为代价。