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丙酮醇

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Secondly,a mixture of acetone and methyl formate was added into the methanol solution of sodium methoxide to prepare sodium formyl acetone by Claisen reaction.

以金属钠为原料,甲醇为溶剂,先制成甲醇钠的饱和甲醇溶液,再滴加丙酮和甲酸甲酯进行Claisen酯缩合制得丁酮烯醇钠,最后在强酸作用下与甲醇进行缩醛化反应合成了4,4-二甲氧基-2-丁酮,过程总收率达到73.1%,纯度98.7%。

Phosphoenolpyruvate is one of the two phosphoryl group donor s in the synthesis of ATP during glycolysis.

磷酸烯醇式丙酮酸是糖酵解中合成ATP的两种磷酸基的供体之一。

Phosphoenolpyruvate is one of the two phosphoryl group donors in the synthesis of ATP during glycolysis.

磷酸烯醇式丙酮酸是糖酵解中合成ATP的两种磷酸基的供体之一。

MMA is produced by the method of acetone-cyanhydrin mainly in our country. The synthetic route is complex, the technical line is long, and the yield is low with high cost after many steps. Hydrocyanic acid is used as raw material, the treatment of numerous waste acid is difficult . Furthermore, concentrated sulfuric acid consumed in this method corrodes equipments and pollutes the environment seriously.

我国MMA的生产以丙酮腈醇法占主导地位,合成路线复杂,生产工艺长,多步反应后产率低,成本高,其采用有剧毒的氢氰酸为原料,产生大量难于处理的废酸,所消耗的浓硫酸对设备腐蚀性大,对环境污染严重,因此开发新的MMA工艺路线很有必要。

Methacrylic Acid is one of the most important organic materials, and there is large demand indomestic and international market. The traditional preparation method of MAA has lots of limitation suchas high cost, huge pollution, and virulent raw materials. So its necessary to search a new green route toreplace the ACH route.

甲基丙烯酸是一种重要的有机化工原料,目前国内外对MAA的需求量很大,而传统的丙酮氰醇法制备MAA存在成本高、环境污染大、原料剧毒等缺点,所以需要寻找一条新的绿色工艺路线代替传统工艺。

Phosphoglycerate is converted to 2-phosphoglycerate by phosphoglycerate mutase.

2-磷酸甘油酸在烯醇化酶的催化下生成磷酸烯醇式丙酮酸。

Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives

三甲基一氯硅烷、二氯甲烷、AE活性酯、三甲基碘硅烷、特戊酸、特戊酰氯、三乙胺、噻二唑、四氮唑乙酸、二甲基乙酰胺、四氢呋喃、四甲基胍、异丙醇、五氯化磷、异辛酸钠、苯乙酸、苯乙酸钠、六甲基二硅胺烷、乙酰乙酸乙酯、甲基异丁酮、磷酸二氢钾、三氧化二铝、DL蛋氨酸、N,N-二甲基苯胺、NN-二乙基苯胺、乙二胺四乙酸四钠、无水硫酸钠、硫酸铵、硫酸钾、醋酸钠、碳酸钠、碳酸二甲酯、甲酸、药用氯化钠、草酸、片碱、丙酮、正丁醇、冰醋酸、醋酸乙酯、醋酸丁酯、甲醇、乙醇、甲醛、液碱(30%)、盐酸(工业级、精制级、试剂级)、硫酸(98%)、氨水、碳酸钙、二氧化氯、6-APA、7-ACA、7-ADCA 、7-ANCA、舒巴坦、头孢他啶活性酯、邓盐(羟甲基钾、前体酸钾、二氢甲基钠)、树脂、生物酶、水处理剂、消沫剂、破乳剂、絮凝剂、活性碳、各种药用辅料、各种添加剂

Light oil, ferrocene, EPA light hydrocarbon, dimethyl ether, xylene, acetone, hydroquinone, potassium permanganate, petroleum ether, naphtha, thiol, butane, sodium hydroxide , synthesis gas reactor

轻质油,二茂铁,轻烃碳五,二甲醚,二甲苯,丙酮,对苯二酚,高锰酸钾,石油醚,石脑油,硫醇,丁烷,氢氧化钠,合成液化气反应罐

SW480 and SW620 cells were also used to study the gene regulation with high carbohydrate intake, where it was shown that during glycolysis eight genes, HK1 (nuclear gene encoding mitochondrial protein, transcript variant 1), GPI, GAPD (glyceraldehyde-3-phosphate dehydrogenase), PGK1 (phosphoglycerate kinase 1), PGK2 (phosphoglycerate kinase 2), ENO2 (enolase 2), PKM2 (pyruvate kinase, muscle, transcript variant 2) and GLUT1 (facilitated glucose transporter, member 1) are over-expressed. In our study, we also found that during hypoxia of cancer tissues the resulting up-regulation of HIF-2α(hypoxia-inducible factor 2, alpha subunit) would in turn up-regulate the GLU1 gene, further activating glycolysis.

另一方面,在高碳水化合物的调控研究上,吾人也利用SW480和SW620细胞株分析证实醣解水解活化过程中,其六碳醣激酶-1(HK1)、葡萄糖磷酸异构酶、3-磷酸甘油醛脱氢酶、磷酸甘油酸激酶-1(PGK1)、磷酸甘油酸激酶-2(PGK2)、烯醇酶-2(ENO2)、丙酮酸激酶-2(PKM2)以及葡萄糖输送蛋白-1(GLUT1)等共有8个基因是连续上升的过度表现;此外,吾人也发现当癌细胞在缺氧的组织中,其缺氧转录子-2α基因(HIF-2α)表现上升后,会活化GLU1基因上升,进一步活化醣解代谢的进行。

The resonant peak shifted towards longer wavelength with the increasing volume fraction of methanol,ethanol,propyl alcohol,acetone and formaldehyde with high sensitivities and linear relations.

结果表明,谐振波长随甲醇、乙醇、丙醇等醇类化合物,以及丙酮、甲醛等蒸气体积分数的上升而向长波方向移动,具有高的灵敏度,且两者基本呈线性关系。

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