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丙酮醇

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In comparison with acetyl acetate method we found that in the reaction process the concentration of enol-like compound had some effect on the reaction rate.

通过与乙酰丙酮法的比较,认为在反应过程中,成环物质的烯醇型的化合物含量对反应速度有影响,烯醇型的化合物含量越高,反应温度越低。

Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.

结果 从该植物中分离得到12个酚性化合物,其结构分别为二氢松柏醇二氢对羟基桂皮酸酯,香草醛,罗布麻宁,对羟基苯甲醛,丁香醛,丁香酸,丁香乙酮,α-羟基丁香丙酮,松柏醛,二氢松柏醇,2-羟基苯丙醇和3-羟基-4-甲氧基苯乙醇。

Manganese oxides supported on SBA-15 Mn(subscript xO/SBA-15 were prepared by incipient wetness impregnation of SBA-15 with furfuryl alcohol solution of manganese acetylacetonate or manganese nitrate followed by removal of the carbon resulted from carbonized FA.

采用溶液浸渍法将乙酰丙酮锰或硝酸锰的糠醇溶液分别灌注到SBA-15的孔道内,一定条件下将糠醇碳化后再将碳烧除,即可得到高度分散的MnO/SBA-15复合催化剂。

The effect of silicon atom in substrate on the reaction rate and the stereoselectivity of enzymatic reactions was revealed by comparison of horse liver alcohol dehydrogenase-catalyzed stereoselective dehydrogenation of the three isomers of acetyltrimethyl propanone and their carbon analogues in aqueous/organic biphasic systems.

本项目通过对比在水-有机溶剂两相系统中,马肝醇脱氢酶催化三甲基硅烷丙酮的三个异构体及其碳类似物的光学选择性脱氢反应,揭示了底物中的硅原子对酶反应速度、立体选择性的影响规律,成功地合成了高对映体纯度的手性有机硅醇,并实现了辅酶的再生。

A series of secondary pollutants with small molecule are produced from these reagents,such as ethanol,aldehyde,acetone,acetonitrile,propionitrile,isobutanol...

药剂在降解的过程中会产生乙醇、乙醛、丙酮、乙腈、丙腈、异丁醇、戊醇等一系列小分子二次污染物。

Then with V∶V=11 9∶1 0,and by bubbling of air at 65-70 ℃ for 5-8 h,pyruvaldehyde was produced in 59 6% yield.

丙酮醛的总收率达 37 8%。n∶n∶n(1,2 丙二醇)=1 0∶4 0∶(1 5~ 2 5 ),以水为溶剂,在 6 0~ 70℃间歇通入氮气 1 5h ,边加原料边蒸馏,制得产率为5 0 %的丙酮醛。

The formation mechanism and the role of the solvents played were explored. Ethylene glycol was found to serve as the reducing agent while acetylacetone had effects on maintaining equilibrium conditions, suppressing the coalesces, enhancing the reducing ability of ethylene glycol, and directing the growth of multiply twinned palladium particles.

通过对产物形成的机理及溶剂所起的作用进行深入研究,发现乙二醇是还原剂,乙酰丙酮则具有维持平衡条件、减少团聚、增强乙二醇的还原能力及诱导钯多重孪晶的生长等作用。

Acetone and tert-butyl alcohol were two major organic products for the photocatalysis of MTBE.

MTBE之光催化含碳有机产物以丙酮和第三丁醇(tert-Butyl Alcohol, TBA)为主,水气的增加使反应路径由生成丙酮为主朝向生成TBA为主。

In order to study the aldol condensation of 2,15-hexadecanedione on the surface of aluminium, the intermolecular condensationmechanism of acetone occurring on aluminum was simulated by usingsemi-empirical AM1 method embodied in MOPAC 6.0 program package.

为了研究2,15-十六烷二酮在氧化铝表面的环合机理,选择小分子丙酮为模型化合物,用量子化学半经验AM1方法研究双分子丙酮在氧化铝表面的醛醇缩合机理。

Some technologies,including olefines from methanol,oxalates and ethylene glycol from carbon monoxide,carbon dioxide-based polymers,chemicals from the syngas prepared by biomass gasification,acetone and butanol by fermentation,and chemicals from acetylene,ethanol,glycerol,furfural,hydroxymethyl furfural and starch,were reviewed.

包括甲醇制烯烃,一氧化碳制草酸酯和乙二醇,乙炔化学品,二氧化碳聚合物,生物质气化合成化工产品,发酵法生产丙酮、丁醇,乙醇衍生化工产品,甘油合成化工产品,糠醛和羟甲基糠醛合成化工产品,淀粉合成化工产品等重要的石油替代化学品生产技术被介绍。

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