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The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应,用茚〓和1,1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物,发现可控制反应条件,使1,1'-联茚与〓反应,并高产率地得到具有新颖结构的单加成物,用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征,测得它的两个〓杂化的桥头碳的化学位移为〓ppm,证明生成的衍生物为6∶6闭式环加成,〓NMR谱中共给出38个信号,表明〓联茚衍生物分子具有〓对称性;在波长532nm,脉冲宽度8ns的激光下,〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近,由于〓联茚单加成衍生物熱稳定性好,在四氢呋喃,丙酮等极性溶剂中溶解性好,能分别均匀地掺入溶胶-凝胶中,已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能;使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究,通过等温压缩曲线测试,证明浓度为〓〓时,〓联茚衍生物能够形成单层膜。

A run flat tire wheel assembly having a run flat support member formed by a ring-shaped metal shell and rubbery elastic members in an inside cavity of a tire/rim, wherein the rubbery elastic member comprises a rubber composition including 100 parts by weight of a diene-based rubber and 0.1 to 5 parts by weight of cobalt acetyl acetonate and/or, as a reinforcing filler, 40 to 90 parts by weight of carbon black/silica in a ratio of 10/1 to 1/2 and 1 to 20% by weight based upon the weight of the silica, of a silane coupling agent, whereby the bondability between the ring-shaped metal shell and rubbery elastic members is improved.

一种轮胎车轮组装体,它是在轮胎/轮辋的内空洞部具有由环状金属壳和橡胶状弹性体形成的漏气保用支撑体的漏气保用轮胎车轮组装体,其中通过由下述的橡胶组合物来构成上述橡胶状弹性体,改良环状金属壳与橡胶状弹性体的粘结性,所述橡胶组合物含有:100重量份的二烯烃类橡胶;以及0.1~5重量份的乙酰基丙酮酸钴、及/或作为增强性填充剂,40~90重量份的以10/1~1/2的比例配合的炭黑/硅石,和相对于上述的硅石重量,1~20重量%的硅烷偶联剂。

The product has green-yellow fluorescence at excitation wavelength of 355 nm and emission wavelength of 478 nm, and the fluorescence intensity could be enhanced in the presence of acetone.

三、流动注射在线氧化荧光法测定氯普噻吨的的研究利用在硫酸介质中二氧化铅可使无天然荧光的氯普噻吨氧化而转变为在最大激发波长和最大发射波长分别为393nm和452nm的强荧光物质,而且丙酮对该荧光体系有强烈增敏作用的现象,建立了以醋酸纤维素固定化的二氧化铅作为固相反应器的流动注射在线氧化荧光法测定氯普噻吨的新方法。

The results show that though the strain is growing slower in the nitrogen-free medium than in the nitrogen-containing medium, the content of capsular polysaccharides produced by the strain in the nitrogen-free medium is higher than those in the nitrogen-containing medium, the content of capsular polysaccharides produced by the strain in the nitrogen-free medium is higher than those in the nitrogen-containing medium. The capsular polysaccharides produced by the strain in the culture which contains different mineral powders will reach the highest content on the third or the fourth day in its growing period. The strain's capability of releasing potassium from k-feldspar and biotite in the nitrogen-containing medium is higher than that in the nitrogen-free medium because in the nitrogen-free medium, the strain and its production of glucoprotein are less than those in the nitrogen-containing medium.

结果表明,尽管该菌在无氮培养条件下的菌体数量远小于有氮培养条件,但无氮培养条件下所提取的细菌多糖多于在有氮条件下培养所提取的细菌多糖;胶质芽孢杆菌在以添加钾长石粉或黑云母粉制作的无氮培养基中生长可形成大量多糖,采用丙酮法进行细菌培养液多糖提取,发现细菌培养的第3天所提多糖含量最高;胶质芽孢杆菌在以添加钾长石粉或黑云母粉制作的有氮培养基中生长亦可形成较多的多糖,且在细菌培养的第4天所提多糖含量最高;胶质芽孢杆菌在有氮条件下对含钾矿物的释钾率高于在无氮条件下的释钾率,这可能与该菌在有氮条件下生长更快、可产生较多菌体细胞有关。

A method for making Bisphenol A with a purity of more than 99.7% by reacting phenol and acetone using an acid catalyst, separating a BPA-phenol adduct by crystallisation and removing phenol from the adduct, in which involves continuous suspension crystallisation with a total dwell time of more than 4 hours in at least 3 crystallisers, by cooling first to 50-70 C in two parallel crystallisers and then to 40-50 C in a third crystalliser connected in series with the first two.; A method for the production of Bisphenol A with a purity of more than 99.7%, by reacting phenol with acetone in presence of an acid catalyst, separating a BPA-phenol adduct from the product mixture by crystallisation, filtration and washing, and removing the phenol from the adduct, in which stage involves continuous suspension crystallisation in at least three crystallisers connected in such a way that the mixture is first cooled to 50-70 C in two crystallisers in parallel and then cooled to 40-50 C in a third crystalliser in series with the first two, the total residence time of the mixture over all crystallisers being more than 4 hours.

描述用于生产纯度大于99.7%的双酚例如,双酚A(BPA的方法,这种方法包含苯酚和丙酮在有酸性催化剂参与的情况下反应形成一个包含双酚的产物混合物;通过结晶、过滤和洗涤从该产物混合物中以双酚/苯酚复合物的形式除去至少一部分双酚以提供双酚A/苯酚复合物晶体;并且从双酚/苯酚复合物晶体中除去至少一部分的苯酚以提供纯度大于99.7%的双酚;其中结晶过程包括连续的混悬液结晶,并且是在至少三个结晶装置中进行的,装置的排列使得产物混合物首先在结晶过程的第一阶段在第一个结晶装置和并联的第二个结晶装置中被冷却到50至70℃的温度,随后在结晶过程的第二阶段在与第一和第二个结晶装置下游串联的第三个结晶装置中被冷却到40至50℃的温度,并且其中产物混合物在结晶过程中的总驻留时间在4小时以上。

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