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The repellent action and contact action of the extracts of 21 species of plants to adult maize weevil, Sitophilus zeamais Motschulsky were studied.

为了筛选对粮库安全的植物源杀虫剂,研究了21种植物的4种溶剂(无水乙醇、丙酮、乙酸乙酯和石油醚)提取物对玉米象Sitophilus zeamais Motschulsky的驱避和触杀作用。

However, when trans-4-aryl-3-buten-2-ones were taken as the substrates, the electron-rich but less sterically hindered ligand 9c gives the best results (up to 96.4 % ee) with highly catalytic activity.

而富电子但空间位阻小的配体9c对亚节基丙酮类底物获得最好的结果(%。4%ee),同时还表现了最好的化学活性。

By GAS recrystallization HMX(1,3,5,7 tetranitro 1,3,5,7 tetraazacyclooctane),we can obtain microparticle β HMX with different particle size and distribution.The effect of temperature on morphology of HMX in the processes of supercritical carbon dioxide antisolvent recrystallization in acetone solution was studied.

研究了以丙酮为溶剂的超临界 CO2 - GAS重结晶制细过程温度对 HMX晶型的影响,结果表明:超临界 CO2 - GAS重结晶 HMX过程与常规的重结晶过程相似,温度对 HMX晶型起控制作用,而对颗粒尺寸影响不大;当局部操作温度大于 5 0℃时,结晶颗粒中会有α型 HMX生成;当整体温度大于 6 0℃时,产品中α型 HMX占主要部分。

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮,1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2,2-联吡啶,邻菲啰啉,三苯基氧膦)合成了16个稀土红外配合物(Ln=Er,Nd,Yb),获得了其中三个配合物的单晶结构,研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

Unoxidated and oxidized wheat stalks were extracted sequentially with CS2, benzene, methanol, acetone and THF, and the extraction solutions were analyzed with GC/MS. The relative contents and compositions of fractional extracts of un-oxidized and oxidized wheat stalks were compared.

采用二硫化碳、苯、甲醇、丙酮和四氢呋喃对未氧化和氧化的麦秆进行分级萃取,比较麦秆各级萃取物的相对含量和组成差异,并对各级萃取物的组成进行GC/MS分析。

The similar nicotinoyltrifluoroacetones are synthesized from acetylpyridine and ethyl trifluoroacetate through Claisen reaction.The influnences of alcoholic natrium,reaction temperature and solvent on reaction yield is studied.The subliming method is improved.

本文以乙酰吡啶和三氟乙酸乙酯为主要原料,利用克莱森酯缩合反应,合成了三种相似结构的吡啶甲酰三氟丙酮化合物,考察了碱性试剂醇钠、反应温度和溶剂等因素对反应产率的影响,改进了纯化产物的方法。

The pathogenicity of pathogen was enhanced by washing leaf surface with acetone and 700% alcohol and by exposing the seedlings out of green-house.

在侵染试验中,用丙酮和70%酒精清洗的幼苗叶片发病加重;露天放置的烟苗较生长在温室内的烟苗发病重。

The solvent effects of C24H30O8 have also been investigated based on Onsager self-consistent reaction field model in chloroform, acetone,DMSO and water.

采用密度泛函理论方法,在B3LLYP/6-31G*水平下全优化得到了该化合物的分子几何构型和电子结构;依据Onsager自恰反应场模型考察了其在氯仿、丙酮、二甲亚砜及水等溶剂中的溶剂化作用;基于气相优化结构进行了B3LYP/6-31G*振动分析,用0.9613校正后的主要红外光谱与实验符合得很好。

The solvent effects of C24H30O8 have also been investigated based on Onsadger self-consistent reaction field model in chloroform, acetone, DMSO and water.

采用密 度泛函理论方法,在B3LYP/6-31G*水平下全优化得到了该化合物的分子几何构型和电子结构;依据Onsager自恰反应场模型考察了其在氯仿、丙酮、二甲亚砜及水等溶剂中的溶剂化作用;基于气相优化结构进行了B3LYP/6-31G*振动分析,用0.9613校正后的主要红外光谱与实验符合得很好。

In this work,a full optimal calculation on the molecular geometry and electronic structure of C24H30O8 has been performed using density functional theory methods at B3LYP/6-31G* level.The solvent effects of C24H30O8 have also been investigated based on Onsager self-consistent reaction field model in chloroform,acetone,DMSO and water.

采用密度泛函理论方法,在B3LYP/6-31G*水平下全优化得到了该化合物的分子几何构型和电子结构;依据Onsager自恰反应场模型考察了其在氯仿、丙酮、二甲亚砜及水等溶剂中的溶剂化作用;基于气相优化结构进行了B3LYP/6-31G*振动分析,用0.9613校正后的主要红外光谱与实验符合得很好。

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