丙酮的

Tebufenpyrad, a new high effective pyrazoleamide acaricide , was synthesized from 1-methyl-3-ethyl-4-chloro-5-pyrazolecarbon acid and 4-t-butylbenzylamine, the raw material are propionyl pyruvic ethyl ester and 4-t-butyl benzylchloride.

吡螨胺是一种新型、高效的吡唑酰胺类杀螨剂，本文以中间体1-甲基-3-乙基-4-氯-5-吡唑甲酸和4-叔丁基苄胺合成，起始原料丙酰丙酮酸乙酯和4-叔丁基苄氯，总收率为61.23%。

The pyretic acid formed by GLYCOLYSIS is broken down into acetaldehyde and carbon dioxide.

糖酵解过程中产生的丙酮酸分解为乙醛和二氧化碳。

Acetone is widely used as an excellent organic solvent in industry.

丙酮是应用广泛、性能优良的有机溶剂之一。

Following are summary of our works:(1)The powders of LaCr_(0.9)Co_(0.1)O_3, LaCr_(0.9)Fe_(0.1)O_3, LaCr_(0.9)Ni_(0.1)O_3, LaCr_(0.95)Sn_(0.05)O_3 and LaCr_(1-x)Ti_xO_3(x=0.0-0.3) were single perovskite phase with orthorhombic structure. The gas-sensing properties of their thick film sensors were tested in the acetone, ethanol, normal propyl alcohol, carbinol and formaldehyde organic gases. The sensitivity of the sensors can not be enhanced effectively by doping Co、Fe、Ni、Sn elements in B-site of LaCrO_3. Ti dopant with proper concentration can greatly improve the gas-sensing properties, which make the sensor display higher sensitivity and quicker response-recovery characteristics.

所得结果摘要如下：(1)LaCr_(0.9)Co_(0.1)O_3、LaCr_(0.9)Fe_(0.1)O_3、LaCr_(0.9)Ni_(0.1)O_3、LaCr_(0.95)Sn_(0.05)O_3和LaCr_(1-x)Ti_xO(来源：ABfd1dC论文网www.abclunwen.com)_3(x=0.0-0.3)粉体为正交单相钙钛矿结构，其厚膜型气敏元件在350℃时对丙酮、乙醇、正丙醇、甲醇、甲醛等有机气体的气敏性能测试表明：0.1mol Co、Fe、Ni和0.05mol Sn元素在LaCrO_3的B位进行掺杂后，不能有效提高材料对以上测试气体的气敏性能；而Ti元素的适量掺杂可以极大地改善LaCrO_3的气敏性能，使之显示出对丙酮气体的高灵敏度和快速响应恢复能力。

Basing on above researches, we designed a series of ionic liquid supported acetylacetone metal catalysts and non ionic liquid supported acetylacetone metal catalysts. The catalytic abilities of these catalysts were evaluated by using them to catalyze the methane oxidation reaction.

在以上研究的基础上，本论文设计了系列离子液体支载的乙酰丙酮金属催化剂及非离子液体支载的乙酰丙酮金属催化剂，并通过这些催化剂对甲烷氧化反应的催化效果来预测它们的活性。

The thicking of secondary cell wall may be one of the reason of ethanol accumulation. The activities peak value of CAT, PPO and POD were advanced and the activity of AAO gradually increased, the content of total phenol decreased sharply, the production rate of superoxide anion ,the content of MDA and H2O2 in flesh of 'brumal jujube' increased treated with ABA during storage, this showed ABA accelerated the scenescence of fruit, the effects of ABA on 'brumal jujube'fruit was contrary to GA.

点红冬枣贮藏过程中，各有机酸(柠檬酸、t-顺乌头酸、琥珀酸、延胡索酸)含量逐渐下降，苹果酸略有增加，丙酮酸含量逐渐增加，峰值出现后下降，说明丙酮酸的增加与进入三羧酸循环的有机酸流量的降低是导致果实乙醇发酵的机制之一；点红冬枣中蔗糖含量较高，贮藏期间，蔗糖含量下降，葡萄糖和果糖含量增加，气调贮藏可延缓果实蔗糖降解和葡萄糖和果糖含量的增加。

The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明，由丙烯脱氢生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处；基于此提出了较完整的丙烯氧化反应网络：丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H，生成烯丙基物种，该物种嵌氧生成σ-O络合物，脱氢得到丙烯醛前驱体，脱附生成丙烯醛；完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成；较低反应温度下丙烯氧化生成丙酮，通过烯醇式中间物种氧化生成丙酮前驱体得到。

Secondly, the silver based catalysts modified by phosphorus, zirconium, zinc, potassium and so on using molecular sieve as carrier, which were produced by ion-exchange method, had also good catalytic performance for 1,2-propane glycol oxidation to methylglyoxal. The conversion of 1,2-propane glycol and the selectivity of methylglyoxal were both high, and the impurity such as formaldehyde and acetaldehyde in the product is little. At the condition of the temperature 300 ℃, the molar ratio of oxygen to 1,2-propane glycol 1.7:1, the space velocity 6000h~(-1), and the concentration of 1,2-propane glycol 70wt%, the conversion of 1,2-propane glycol is 90% and the selectivity of methylglyoxal is 45% on the Ag-P catalyst.

其次对采用离子交换法制备的负载在分子筛上的银系催化剂进行了研究，发现此催化剂在助催化剂磷、锆、锌、钾等的作用下对丙二醇的低温氧化脱氢具有很高的活性，可以得到较好的丙酮醛的收率，并且产物中的甲醛、乙醛副产物的量比较低；经过对Ag-P催化剂上反应条件的考察，发现当温度为300℃、氧醇比1.7：1、空速6000h~(-1)、丙二醇浓度为70wt%时，丙二醇的转化率为90%，丙酮醛的选择性为45%。

From FT-IR we think that the hydrogen bond between the polar oxygenous group on the thin film surface treated with plasma and acetone molecules would enlarge the distance between the carbon black particles, resulting in the addition of the electrical resistance, then the response behavior of the thin film to acetone was improved greatly.

我们通过FT-IR研究认为，等离子体处理后，薄膜表面引进的极性含氧基团与丙酮分子之间氢键的形成会增大炭黑粒子之间的距离，导致了薄膜电阻的极大增加，使薄膜对丙酮蒸气的响应得到很大改善。

Methods The ionization constant was determined with acid-basle titration in acetone/water solutions with different ratios, the pH at half neutralization point was regarded as pKa, the value to infinite diluted in pure water was explored and the lgP was determined with bottle-shaking method by HPLC.

方法采用酸碱滴定法测定各不同体积比的丙酮-水溶液中药物半中和点时的pH值作为药物在该体积比的丙酮-水溶液中的pKa值，再外推至纯水中药物浓度无限稀释时的pKa值；采用HPLC配合摇瓶法测定药物的分配系数。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。