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丙酮基

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Its zinc complex was applied in asymmetric direct aldol reaction of acetone and p-nitrobenzal...

设计合成了一种NOBIN衍生的手性配体,初步研究了该手性配体的双核锌配合物在对硝基苯甲醛和丙酮的不对称直接醇醛缩合反应中的催化应用,20℃和20mol%催化剂量下,获得了32.5%ee和72%收率的产物。

Methods The immobilizing conditions of neutrophil alkaline phosphatase staining were detected by the stationary liquid of 40%, 60% and 80% acetone-citric acid, and at the same time, the staining conditions were detected at 10, 15 and 20 minutes in the matrix liquid prepared respectively with 2-amino-2-methyl-1.3-propylene glycol (PH9.4-9.6) buffer, barbital (PH9.2) buffer and Tris (PH9.2) buffer.

用40%、60%、80%的丙酮-枸缘酸固定液对中性粒细胞碱性磷酸酶染色固定条件进行测定。同时用2-氨基-2-甲基-1.3-丙二醇(pH9.4-9.6)缓冲液、巴比妥(pH9.2)缓冲液、Tris(pH9.2)缓冲液配制的基质液分别在10、15、20分钟的染色条件进行测定。

The results showed that the first canonical correlation coefficient between aldehydes, ketones, esters and the total quantity of each kind of ingredient and smoking quality achieved 5 % or 1 % remarkable level. And their correlation depended mainly in the correlation between phenylacetaldehyde, furfural, megastigmatrienone-1, megastigmatrienone-3, geranylacetone,β-damascenone, keto-isophorone, dihydroactinidiolide and smoking quality.

结果表明:醛类成分、酮类成分、酯类成分与香气质、香气量的第一典型相关系数达到5%或1%显著水平,各类成分总量与香气质、香气量的第一典型相关系数达到1%极显著水平,其相关关系主要表现在苯乙醛、糠醛、巨豆三烯酮1、巨豆三烯酮3、香叶基丙酮、β-大马酮、氧化异佛尔酮、二氢猕猴桃内酯等成分与香气质、香气量的相关上。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K,压力为1.01×10^5Pa空气,O3过量的条件下,异戊二烯很快反应完全,反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛;产物中还包括甲酸、一氧化碳和二氧化碳。

Catalytic oxidation ; p nitrotoluene ; p nitrobenzoic acid ; Co 2

催化氧化;对硝基甲苯;对硝基苯甲酸;乙酰丙酮钴

As for the mesh screen type, its volume multiplied by 100% its porosity was the desirable filling amount. Having considered the forgoing findings, the researchers add up the amounts of the above two types as the filling amount of the composite micro structure, with the filling fluid being acetone. In fabricating the heat spreader, a copper pipe is added to serve the filling purpose. What is more, because the manufacturing process is not carried out in a totally clean environment, there is some noncondensible gas left, which will have a negative effect on the performance of the heat spreader. Consequently, the copper pipe has to be reserved so that the exhaust gases can be evacuated after the filling is done.

Kempers 文中可知,沟槽结构之填充量以微结构体积之80%为最佳,网格结构则是以网格体积乘上孔隙率(porosity,φ)之100%为最佳,故本研究便以两者之加总做为复合式微结构之填充量,填充液为丙酮;在均温基板之制造程序中,会加装一铜管做充填之用,且而由于制造过程并非于一完全干净之环境下完成,故板内会有一些不利于均温基板作用之非凝结性气体noncondensible gas (NCG残留,因此铜管需保留一定的长度,以方便充填完成后将废气排出之用。

However, there were no significantly differences on serum glutamic oxaloacetic transaminase and serum glutamic pyruvic transaminase between these four groups.

然而在肝功能方面,不论是血清麸草酸转胺基酶或血清麸丙酮酸转胺基酶,四组都没有显著性的差异。

Aiming at the shortcomings of high formaldehyde content and low soaping and crocking fastnesses of currently used pigment printing binder,by60Co-γ radiation polymerization process,the waterborne polyacrylate emulsion containing active keto groups was synthesized from acrylate monomers and diacetone acrylamide.

针对目前所用涂料印花黏合剂存在的色牢度低和甲醛含量高的缺陷,采用钴60-γ辐射法聚合工艺,利用丙烯酸酯单体、双丙酮丙烯酰胺合成出含活性酮羰基的丙烯酸酯乳液;然后同含端酰肼基聚氨酯乳液按一定的比例混合,制备出酮肼交联型丙烯酸酯聚氨酯复合乳液。

The results showed that Kaidimycin was chemically neutral, macrocylic polylactones, stable and liable to dissolve into water and pyridine, slight to dissolve into methanol, ethanol and N-butanol, difficult to dissolve into ethyl acetate, acetone, benzene and chloroform. Chemical reaction of functional group of Kaidimycin showed that it had glycoside, amino acid and aldehyde, no reducing sugar, polypeptide and phenol.

凯地菌素属中等极性的、中性抗生素,极性纸层析结果与多烯类抗生素的纸层析结果相似:易溶于水、吡啶,微溶于甲醇、乙醇、正丁醇,不溶于乙酸乙酯、丙酮、苯、三氯化碳;对高温、光照和紫外处理有很好的稳定性;官能团反应试验结果发现,凯地菌素可能含有糖苷键、氨基酸伯氨基和醛基,不含有还原糖、多肽和酚基,高锰酸钾、浓硫酸反应与多烯大环内酯类抗生素的特性相似;并且依据纯品,采用生物法和分光光度法对摇床发酵液进行了效价的测定。

Using acetone as a photosensitizer,and N3· as an oxidant by pulse radiolysis method,the induced oxidation of cyclic-Phe-His in aqueous solution has been also reported in this paper,results similar to the photoionization of cyclic-Phe-His have been found.

而具有亲电子性的丙酮能在该环肽的苯丙氨酸残基的苯环上抽取电子,形成320nm和410nm的特征吸收峰,求出了自由基的有关动力学参数,并用脉冲辐解动态吸收光谱法印证了上述结果。

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