丙酮基

This paper uses orthogonal experiment to research on the synthesis technique of pseudo-ally lionone from citral and allylacetone. The product structure had analysed by IR.

利用正交试验法对柠檬醛和烯丙基丙酮合成假性烯丙基紫罗兰酮的工艺进行了研究，并用红外光谱对产品进行了结构分析和鉴定。

It crystallizes in the monoclinic space group C2/c, with a=1.6953(3)nm, b=1.9241(4)nm, c=1.7760(4)nm,β=94.75(3)°. Each Gd ion is coordinated by two oxygen atoms from two different radicals NITPh(OCH3)3 and six oxygen atoms from three hfac molecules to form eight-coordinated dodecahedron geometry.

Gd离子采取八配位的模式，两个氮氧自由基作为单齿端基配体分别以氮氧基团的氧原子与Gd离子配位，三个六氟乙酰丙酮阴离子分别以两个氧原子与Gd离子配位，构成十二面体。

At lower temperature, the interaction between the Ir particles and the adsorbed ethoxyl species is not strong enough to abstract H atom from the nearby CH3 group, and thus acetaldehyde acts as the key intermediate. Acetaldehyde can decompose to methane and CO and/or convert to acetone through decarbonylation.

低温时Ir粒子与吸附的乙氧基的相互作用的强度不足以从-CH3基团中提取H原子，此时乙醛是关键的反应中间物，乙醛可以裂解生成甲烷和一氧化碳或脱羰基生成丙酮。

A novel carbonyl transposition led by anilines'nucleophilic addition to methyl 2-keto α-D-glucopyranoside was discovered. And the mechanism of the reaction concerned to an enol rearrangment was provided through tracing the change of 〓H-NMR and 〓C-NMR of a hemiacetal intermediate which was obtained in the reaction of o-phenylene diamine with 2-keto glycoside. Both the intermediate and the converting product were identified by 〓H-NMR,〓C-NMR,〓H-〓H COSY and HMQC.

一、发现了2-位氧化α-甲基D-葡萄糖苷的芳胺亲核加成引起羰基转位的新方法，利用核磁共振氢谱及碳谱对邻苯二胺与2-位氧化α-甲基D-葡萄糖苷加成生成的稳定中间体半缩酮化合物在氘代丙酮中的变化进行跟踪，结合对转化产物的氢氢相关谱和HMQC结构确证，提出了该反应中2-位羰基通过烯醇化互变而转至3-位的机理并得到了验证。

This sequence was cloned into eukaryotic expression vector and then expressed in pichia pastoris to overproduce post-translationally modified protein of interest.

在通过甲醇诱导表达后，分别得到了水稻丙酮酸脱羧酶的a亚基和β亚基

Our use Co2 as a catalyst in this work, exploring new way to produce nitrobenzoic acid from nitrotoluene under the prue oxygen in basic medium.

本文探讨了以乙酰丙酮钴为催化剂，分子氧为氧源，在NaOH-CH_3OH的反应环境下，氧化硝基甲苯制备硝基苯甲酸的新方法。

Synthesis of pyruvic acid from lactic acid by catalytic oxidation with oxygen was studied. The effect of catalyst composition, amount of catalyst and oxygen, reaction temperature and time on product yield was investigated and the optimum conditions were found.

由于丙酮酸的分子中同时具有羰基和羧基两个官能团，因而反应中心多而显出比一般化合物更为重要和特殊的化学性质，已引起越来越多的化学工作者的重视。

The homology is extensive throughout the protein and all amino acid residues of Pdc that have been shown to be involved in ThDP binding, both of the thiazole and phosphate moieties, are precisely conserved in Thi3p.

整个蛋白具有广泛的同源性，并且丙酮酸脱羧酶的氨基酸残基，已被证明参与了ThDP结合，双方的噻唑和磷酸基，都精确的保存在Thi3p中。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

The graft copolymerization of vinyl monomer onto carbon black with,respectively,ceric ions, n butylithium,acetylacetonate copper complex and manganic pyrophosphate complex as initiator were studied.

讨论了分别在铈离子体系，正丁基锂体系，过渡金属离子乙酰丙酮铜以及焦磷酸络锰体系的作用下，炭黑与乙烯基单体的接枝聚合。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。