丙酮基

We found that when acetone was used as solvent, in the presence of TFA, cis-4-pyrrodin-1-yl-L-proline could catalyze the direct asymmetric aldol reaction between acetone and 4-nitrobenzaldehyde with 84% ee.

研究发现，该催化剂以丙酮为溶剂时，加入催化剂等当量的三氟乙酸可以较好的催化丙酮与对硝基苯甲醛之间的直接不对称Aldol反应，得到84%的ee值。

Three open chain crown ether s and triglycolyl isopropylidene hydrazide complexes of rare earth nitrate were synthesized for the first time with isoproylidene hydrazide as the terminal group and through IR, 1HNMR, MS, characterized their structures have been characterized.

首次合成了以丙酮酰腙为端基的3种双酰腙型开链冠醚及三甘双酰丙酮腙稀土硝酸盐配合物，并通过元素分析，IR，1HNMR，MS对分子结构进行了表征

In our country, the acetone is mainly used to produce solvent, acetone cyanide alcohol / methyl methacrylate, methyl isobutyl ketone, bisphenol A, medicines and rubber additives.

国内丙酮主要用于溶剂、丙酮氰醇/甲基丙烯酸甲酯、甲基异丁基酮、双酚A、医药以及橡胶助剂等。

The synthesis of l-(4-acetylaminophenyl)-2-bromo-1-propanone was discussed, and the mechanism and possible factors were analyzed. Hence the routine was determined, in which l-(4-acetylaminophenyl)- 1-propanone was reacted with Bromine dissolved in ethanol, so that the a -bromination can be carried on, resulted in the yield of up to 70.4%.

探讨了1-(4-乙酰胺基苯基)-2-溴代-1-丙酮的合成方法，分析了反应机理和影响因素，确定将1-(4-乙酰氨基苯基)-1-丙酮溶解在乙醇中以溴的乙醇溶液进行α-溴化的合成路线，产率可达70.4％。

In the paper, a series of metallorganic compounds have been studied by the quantum-chemical calculation with proper basis sets, including:1. a series of carbonyl complexes.2. dibenzene chromium and its derivatives3. ferrocene and its derivatives4. a series of metallic complexes with acetylacetoneWe optimized the geometric configurations of a series carbonyl complexes including Ni4 Fe5, Cr6 with density functional theory B3LYP method at the different levels and confirmed the stable geometry by vibrational analyses. Then we calculated the nuclear magnetic resonance spectra with GIAO method provided by GAUSSION98 program at the different levels.

本文用量子化学计算程序，用密度泛函B3LYP方法，在恰当基组水平上，用GAUSSIAN98程序提供的GIAO方法研究了系列金属有机化合物的核磁共振谱：一、羰基配合物系列：二、二苯铬及其衍生物系列：三、二茂铁及其衍生物系列：四、乙酰丙酮的配合物系列：我们用密度泛函B3LYP方法，在不同基组水平上对第一过渡系羰基化合物的系列配合物进行了结构优化，通过振动分析确定其稳定构型，然后再用密度泛函B3LYP方法在不同基组水平上，用GAUSSIAN98程序提供的GIAO方法计算其核磁共振谱。

In this paper, the structures of methylglyoxal and 1,1-dimethoxy-2-propanone are identified by GC-MS, NMR and the standard samples. The reaction conditions of catalyst oxidation and acetalation according to reaction mechanisms are discussed.

本文运用质谱、核磁和标样确定了中间体丙酮醛及其产物1，1-二甲氧基丙酮的结构，并结合反应机理对催化氧化和醛保护的反应工艺条件进行了探索。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl-2-acctonc, phenylacetic acid, 1-phenyl-2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、3，4-亚基二氧苯基-2-丙酮、苯乙酸、1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

A series of lanthanide complexes (Ln = Er, Nd, Yb) with infrared emission properties were designed and synthesized by using different anionic ligands [1 -phenyl-3-methyl-4-(4-tertbutylbenzoyl)-5-pyrazolone and l-phenyl-3-methyl-4--5-pyrazolone and 2-naphtoyl trifluoroacetone] and netural ligands (2,2-dipyridine, phenanthroline, triphenylphosphine oxide and water). Three crystal structures of these complexes were obtained and structure studied, and the properties of photoluminescence and fluorescent lifetime were studied in detail.

我们通过选用不同的第一配体[1-苯基-3-甲基-4-(4-异丁酰基)-5-吡唑酮，1-苯基-3-甲基-4-(4-叔丁基苯甲酰基)-5-吡唑酮和2-萘基三氟乙酰丙酮]和第二配体(2，2-联吡啶，邻菲啰啉，三苯基氧膦)合成了16个稀土红外配合物(Ln=Er，Nd，Yb)，获得了其中三个配合物的单晶结构，研究了这些稀土红外配合物的光致发光和荧光寿命等性质。

The Pd-supported catalyst on MCM-22 synthesized by static method shows a higher acetone conversion than that prepared by dynamic method in one-step synthesis of methyl isobutyl ketone from acetone.

在丙酮一步法合成甲基异丁基酮反应中，静态条件下合成的MCM-22为载体的催化剂的丙酮转化率较高，这是由于该分子筛的酸量较高所致。

4Production of chemical products from which narcotics are easily made ephedrine, 3, 4-idene dihydro phenyl -2-acctonc, phenyl acetic acid, 1- phenyl -2-acetone, heliotropin, safrole, isosafrole, acetic oxide

易制毒化学品生产（麻黄素、 3 ， 4-亚基二氧苯基-2-丙酮、苯乙酸、 1-苯基-2-丙酮、胡椒醛、黄樟脑、异黄樟脑、醋酸酐

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。