丙酮基

Results: The good linear range of method was 10 to 1000μg/ml (T=0.9999) with the correlation coeffivient of 0.9999, and the limit concentration in air was 0.2 mg/m^3 with the average relative standard deviation less than 5%(n=6). The average sampling rate ranged from 96.6 to 100%, and the breakthrough capacity of l00mg activated charcoal was 4.7mg. The average desorption rate was 97.6%, and mesityl oxide absorped in activated charcoal tube was stable for 7 days and can be detected accurately with other gas coexisting in the air of workplace.

结果：异亚丙基丙酮浓度在10~1000μg/ml内呈良好线性关系，相关系数0.9999，最低检出浓度为0.2mg/立方公尺，相对标准偏差＜5%(n=6)；气体采样效率≥96.6%，100mg活性炭对异亚丙基丙酮的穿透容量为4.7mg，平均解吸效率97.6%；活性炭样品室温下可保存7天；丙酮、丁酮、异佛尔酮、苯、甲苯、二甲苯等共存物不干扰测定。

Formyl-3-acetyl-4-methyl-5-carbobenzoxypyrrole (6) was synthesized via the selective oxidation of 2,4-dimethyl-3-acetyl-5-carbobenzoxypyrrole (5), which was produced from acetylacetic benzylester (1) via nitrosation, reduction and addition-cyclization with acetylacetone. The total yield of the product was about 34%.

以乙酰乙酸苄酯(1)为原料，经过亚硝化、还原、与乙酰丙酮加成环化生成2， 4-二甲基－3-乙酰基－5-苄氧羰基吡咯(5)，通过选择性氧化反应制得目标化合物2-甲酰基－3-乙酰基－4-甲基－5-苄氧羰基吡咯(6)，反应的总收率约为34%。

Result Under the pretreatment conditions, the content of acetone extractives transformed. The hydroxyl and carboxyl, belonging to auxochromic groups, were oxidized into the carbonyl and ester groups. Also, there were plenty of auxochromic groups and chromophoric groups in the acetone extractives of silver chain.

结果］刺槐在预处理条件下，丙酮抽出物成分发生了变化，羟基、羧基等助色基团在预处理条件下氧化成羰基、酯基等发色基团，且丙酮抽出物的主要成分中含有大量发色基团和助色基团。

Chapter 4: Synthesis of 1,5-diary 1-1,4-pentadien-3-ones from acetone or benzalacetone with aromatic aldehydes results in 86-97% yield with potassium hydroxide as catalyst under ultrasound irradiation in 5-60min.

为合成氰基环己醇找到一条方便高效的合成方法。第四章：研究了超声辐射下，以氢氧化钾为催化剂，芳香醛与丙酮及亚苄基丙酮之间反应合成1，5-双苄基-1，4-戊二烯-3-酮。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

The paint includes liquid A, which consists of acrylic resin, mixed solvent of xylene, acetone and isophorone, organic silicone solution, superfine silica powder, titanium dioxide powder, methyl-(N-beta-amino ethyl gamma-amino propyl)-dimethoxy siloxane solution, gamma-methyl acrylyloxy propyl tromethoxy siloxane solution and fluorocarbon modified siloxane; and liquid B, which consists of hexamethylene diisocyanate, polydiisocyanate, xylene, and methoxy propyl acetate. When the paint is used, two components are mixed together.

由丙烯酸树脂、二甲苯和丙酮及异佛尔酮混合溶剂、有机硅酮溶液、超细二氧化硅粉、钛白粉、甲基(N-β-氨乙基γ-氨丙基)二甲氧基硅烷溶液、γ-甲基丙烯酰氧基丙基三甲氧基硅烷溶液、氟碳改性硅氧烷溶液组成A液，由六亚甲基二异氰酸酯聚异氰酸酯、二甲苯和甲氧基乙酸丙酯混合溶液组成B液，使用时将两组分混合。

The results of in situ DRIFTS on propylene oxidation show that the allyl species originated from α-H abstraction of propylene were located at the wavenumbers of 1454 cm~(-1) and 1427 cm~(-1). The rate-determining step is the abstraction of an α-H abstraction from a lattice oxygen linked to a bismuth ion to form a π-allyl intermediate coordinated to a molybdenum ion. The metal-oxo group then attacks the allyl intermediate forming a σ-bonded oxygen-allyl species, which is in a rapid equilibrium with the π- bonded species. The σ-bonded species then transforms to acrolein by further abstraction of α-H. Such species as formate, carboxylate, carbonate transform to deep oxidation products. The acetone was derived from propylene by an enolic species at lower temperatures.

丙烯氧化反应体系的原位漫反射红外光谱研究结果表明，由丙烯脱氢生成的烯丙基中间物种吸收峰在1454cm~(-1)和1427cm~(-1)处；基于此提出了较完整的丙烯氧化反应网络：丙烯选择氧化生成丙烯醛主要经历丙烯脱除甲基上的一个H，生成烯丙基物种，该物种嵌氧生成σ-O络合物，脱氢得到丙烯醛前驱体，脱附生成丙烯醛；完全氧化产物是由催化剂表面上生成甲酸盐、羧酸盐、碳酸盐等形式的中间物种转化而成；较低反应温度下丙烯氧化生成丙酮，通过烯醇式中间物种氧化生成丙酮前驱体得到。

Their structures were characterized by IR, 1H NMR, of which 4-chloro- 2-methyl-7-(2-bromoethoxy) isoflavone, 2, 4\'-dimethyl-7-(2-bromo-ethoxy)isoflavone and 2-methyl-7-(2-bromoethoxy) isoflavone are rarely reported so far.4\'-chloro-2-methyl-7-(3-bromopropoxy)isoflavone, 2, 4\'-dimethyl-7-(3-bromo- propoxy) isoflavone, 2-methyl-7-(3-bromopropoxy) isoflavone, 4\'-methoxy-2-methyl-7-(3-bromopropoxy) isoflavone and 4\'-hydroxy-2-methyl-7-(3-bromopropoxy) isoflavone were gained by reacting 7-hydroxy-2-methyl isoflavone derivatives with 1, 3-dibromo- propane, respectively.

第三章(来源：73ABC论文网www.abclunwen.com)在丙酮溶液中以K_2CO_3为碱，使溴乙氧基异黄酮和溴丙氧基异黄酮与咪唑偶合，以较高的产率合成出10种目标化合物：2-甲基-4′-氯-7-2-(1-咪唑基乙氧基异黄酮、2，4′-二甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-甲氧基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-羟基-7-2-(1-咪唑基乙氧基异黄酮、2-甲基-4′-氯-7-3-(1-咪唑基丙氧基异黄酮、2，4′-二甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-甲氧基-7-3-(1-咪唑基丙氧基异黄酮、2-甲基-4′-羟基-7-3-(1-咪唑基丙氧基异黄酮，经IR、~1H NMR、~(13)C NMR、元素分析等对其结构进行了表征，10种目标产物均未见文(来源：ABC论文cccccc网www.abclunwen.com)献报道。

The factors which mostly affect the quality and output of the product including molar proportion of reagents, reaction temperature, alkaline concentration and reaction time are analyzed. After orthogonal experiment, it is concluded that the optimized reaction condition is that acetone and furfural are charged with equal molar quantities at 40 with sodium hydroxide (0.10 mol/L) and the operation time 5 h.

通过对影响亚糠基丙酮质量和收率的主要因素原料配比、反应温度、碱浓度、反应时间等单因素实验，探索出合成亚糠基丙酮的优化反应条件为：原料配比n：n=1.0：1.0、反应温度40℃、氢氧化钠溶液浓度为0.01 mol/L、反应时间5h。

A new convenient synthesis of a series of 1-aryl-2-propanones using aromatic amine s as precursors, via diazo reaction and improved Meerwein arylation reaction under mild conditions, was achieved.

以芳香胺为原料，经重氮化和改进的Meerwein芳基取代反应，合成了一系列的1-芳基-2-丙酮，其中1-(3，5-二三氟甲基苯基)-2-丙酮是一个新化合物。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。