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丙酮二酰

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Acridine and body is acetone of synthetic pyridine, acetyl, right among its amino phenol, adjacent benzene the product such as 2 phenol, will be " 95 " the market develops a stress.

医药原料及其中间体合成吡啶、乙酰丙酮、对氨基苯酚,邻苯二酚等产品,将是"九五"市场开发重点。

The main contents are:(1) The polarized laser Raman spectra of acetone, methyl alcohol, alcohol, ethylene glycol, formamide, acetonitrile, acetic acid, Chloroform, Methylene chloride, and Bromoform are measured in the experiment.(2) The depolarization ratio of Raman shift in the measured spectrum are

主要的结果有:得到了丙酮分子9条喇曼谱线、甲醇分子5条喇曼谱线、乙醇分子9条喇曼谱线、乙二醇分子7条喇曼谱线、甲酰胺分子8条喇曼谱线、乙腈分子8条喇曼谱线、乙酸分子8条喇曼谱线

It crystallizes in the monoclinic space group C2/c, with a=1.6953(3)nm, b=1.9241(4)nm, c=1.7760(4)nm,β=94.75(3)°. Each Gd ion is coordinated by two oxygen atoms from two different radicals NITPh(OCH3)3 and six oxygen atoms from three hfac molecules to form eight-coordinated dodecahedron geometry.

Gd离子采取八配位的模式,两个氮氧自由基作为单齿端基配体分别以氮氧基团的氧原子与Gd离子配位,三个六氟乙酰丙酮阴离子分别以两个氧原子与Gd离子配位,构成十二面体。

The effect of different second ligand on the flourescent properties of polymers were studied. Then AxByEu/HTTA/PMMA was prepared using the best second ligand HTTA.

考察了不同的第二配体(咔唑、二甲基-联吡啶、邻菲罗啉、噻吩甲酰三氟丙酮HTTA)对脂肪酸铕聚合物发光性能的影响,选择出合适的第二配体HTTA,进而合成了A3Eu/HTTA/PMMA聚合物。

Cephalotaxine ester of 2-oxo-6-methylheptanoic acid was treated with lithium diisopropylamide and Me O-(1-methoxyisopropyl)glycolate to give a mixture of homoisoharringtonine and its stereoisomers with 56% yield. The four stereoisomers separated by TLC showed identical mass spectra and almost superimposed IR but with different 1H NMR spectra. The configuration of the 2'-C and 3'-C of the four isomers were postulated based upon their 1H NMR spectra as compared with the 1H NMR spectra of isoharringtonine and its stereoisomers.

2-氧代-6-甲基庚酰基三尖杉碱(3)与0-(1-甲氧基异丙基)羟基乙酸甲酯(4)在强碱性试剂二异丙胺锂存在下,起亲核加成反应,反应中间体5在室温用酸性丙酮水解,得到一种新的三尖杉酯类生物碱一一高异三尖杉酯碱(6c)及其立体异构体(6a、6b、6d)的混合物,产率56%、通过制备薄层层析分得这四个立体异构体,它们的1H NMR和异三尖杉酯碱及其立体异构体的1H NMR类似,推定了它们的绝对构型。

Due to their applications in magnetic, optical, electronic and catalyst, polynuclear lanthanide clusters are of importance. In this part, a series of nanowheel-shaped nonanuclear lanthanide clusters,〓〓(Ln=Sm~Tm; BA=benzoylacetone), were prepared and characterized. Each complex can exist in three phases, i. e., cubic, tetragonal and triclinic.

本论文第二部分在醇溶液中以三乙胺调变溶液pH,利用β-二酮配位方式的灵活性成功地构筑了一系列结构稳定、纳米尺度轮状的九核稀土配合物〓〓(Ln=Sm~Tm;BA=苯甲酰丙酮),并在不同溶剂中重结晶分别得到了三斜、四方以及立方三种晶型的晶体。

A novel route for synthesis of methyl acetoacetate from acetone and dimethyl carbonate over solid base catalysts was proposed.

以碳酸二甲酯与丙酮为原料,在固体碱上合成乙酰乙酸甲酯,并考察了反应温度、反应时间、催化剂用量和原料摩尔比等因素对反应结果的影响。

A run flat tire wheel assembly having a run flat support member formed by a ring-shaped metal shell and rubbery elastic members in an inside cavity of a tire/rim, wherein the rubbery elastic member comprises a rubber composition including 100 parts by weight of a diene-based rubber and 0.1 to 5 parts by weight of cobalt acetyl acetonate and/or, as a reinforcing filler, 40 to 90 parts by weight of carbon black/silica in a ratio of 10/1 to 1/2 and 1 to 20% by weight based upon the weight of the silica, of a silane coupling agent, whereby the bondability between the ring-shaped metal shell and rubbery elastic members is improved.

一种轮胎车轮组装体,它是在轮胎/轮辋的内空洞部具有由环状金属壳和橡胶状弹性体形成的漏气保用支撑体的漏气保用轮胎车轮组装体,其中通过由下述的橡胶组合物来构成上述橡胶状弹性体,改良环状金属壳与橡胶状弹性体的粘结性,所述橡胶组合物含有:100重量份的二烯烃类橡胶;以及0.1~5重量份的乙酰基丙酮酸钴、及/或作为增强性填充剂,40~90重量份的以10/1~1/2的比例配合的炭黑/硅石,和相对于上述的硅石重量,1~20重量%的硅烷偶联剂。

The producing of tetrapod-like CuCl was found to be the result of co-effect of acetylacetone and ethylene glycol.

通过对溶剂所起的作用的研究,发现四足形CuCl晶体的形成是乙二醇和乙酰丙酮协同作用的结果。

Diethanolamine and acetylacetone were selected as addition agents.

本文选择二乙醇胺和乙酰丙酮作为添加剂。

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