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The samples were extracted with acetone by blending and the extract was partitioned with methenyl chloride. The extracts were cleaned up by a column of silica gel.

样品以丙酮提取,三氯甲烷萃取,硅胶柱净化,液相色谱测定,最小检出量为0 5×10-9g。

So the catalysts for producing methylglyoxal from 1,2-propane glycol were studied in this thesis.

因此本文对丙二醇氧化制备丙酮醛的催化剂进行了研究。

The technology of producing methylglyoxal in our country was developed in recent years, but its capacity is small, and the catalyst is very expensive too.

国内丙酮醛的生产起步晚,规模较小,并且所需催化剂比较昂贵。

The ozonolysis of isoprene has a significant contribution to atmospheric carbonyls, especially to formaldehyde and methylglyoxal.

异戊二烯臭氧氧化反应对大气羰基化合物特别是甲醛和丙酮醛具有重要贡献。

Firstly, the molybdenum based catalysts modified by silver, phosphorus, vanadium using aluminum oxide as carrier were studied. The results showed that its catalytic performance for 1,2-propane glycol oxidation to methylglyoxal is good.

论文首先对以氧化铝为载体,在银、磷、钒修饰下的钼系催化剂进行了研究,通过实验发现该催化剂对丙二醇氧化制备丙酮醛具有高的催化活性和较好的选择性。

As for acetalation, we research the effects of acid kinds, acid quantity, temperature solvents on it and get the conclusions that the optimized acid is sulfuric acid, the optimized temperature is 65 °C, the reaction time is five hours, and the material ratio of sulfuric acid to methylglyoxal to methanol is 0.028:1:6.837.

在醛保护一步中,研究了酸种类、酸用量、温度及其溶剂的影响,得到了本反应的较好条件是:酸为浓硫酸,反应温度为65℃,反应时间为5小时,浓硫酸:丙酮醛:甲醇的配比为0.028:1:6.837,反应收率可达81%。

Using the chemical reaction route selection method proposed by the authors, a reaction route of using commercial methylglyoxal as the starting material to produce Furaneol was chosen.

今采用作者提出的化学反应路径选择因子对呋喃酮的合成方法进行计算比较,确定了以丙酮醛为原料,通过偶联反应合成中间体苏式3,4-二羟基-2,5-己二酮,再由成环反应制备产物呋喃酮的合成路线。

The results indicated isoprene was soon consumed under the condition of excess ozone. During the reaction, the major carbonyl products formed were methyl vinyl ketone, methacrolein, methylglyoxal, and formaldehyde. Formic acid, CO and CO2 were also among the products.

在反应温度(294±2)K,压力为1.01×10^5Pa空气,O3过量的条件下,异戊二烯很快反应完全,反应中生成的羰基产物主要包括甲基丙烯醛、甲基乙烯基酮、丙酮醛和甲醛;产物中还包括甲酸、一氧化碳和二氧化碳。

We ever reported cellulose is in propyl of Xi of ionic liquid 1-- chloric salt of Zun of 3- methylic Mi (the homogeneous phase acetyl in Am ImC L) converts reaction, falling without activator condition, one pace gets the CA of different DS, get acetone but the CDA[12] of dissolve.

我们曾报道了纤维素在离子液体1-烯丙基-3-甲基咪唑氯盐中的均相乙酰化反应,在无催化剂条件下,一步得到不同DS的CA,并得到丙酮可溶的CDA[12]。

The method uses carboxyl methylic cellulose sodium spreads out an agent to be chloroform as bind agent;- acetone (7:3); Chan Bo grows linear scanning law to determine,λ S=360 Nm.

方法采用羧甲基纤维素钠作为黏合剂;展开剂为氯仿-丙酮(7:3);单波长线性扫描法测定,λS=360 nm。

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