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Knoevenagel condensation reaction between aromatic aldehyde, malononitrile or ethyl cyanoacetate is promoted by organocatalyst N-methylimidazole.

以1-甲基咪唑为有机小分子催化剂催化芳香醛与丙二腈或氰乙酸乙酯的Knoevenagel缩合反应,反应速度快,操作方便,产率高,后处理简单。

In this work, trially1 isocyanurate and trimethylolpropane trimethaerylate were used as a polyfunetional monomer of PP/PE blends, and the effects of radiation dosage, the kind and amount of polyfunetional monomer on the morphology and mechanical properties were studied.

本研究中采用三烯丙基异腈脲酸酯和三羟甲基丙烷三甲基丙烯酸酯为PP/PE共混体系的多官能团单体。研究了辐照剂量,多官能团单体种类和多官能团单体用量对共混物形态结构及力学性能的影响。

The main results and conclusions are as following:(1) By using the femtosecond time-resolved fluorescence up-conversion technique, we studied the ultrafast excited state photoisomerization process of 33TC dye molecule.

主要内容和结论如下:(1)利用飞秒时间分辨荧光上转换技术对3,3'-磺酸基丙基噻腈三乙胺盐(33TC)的超快激发态光异构过程进行了研究。

Within carboxylic groups, the coordination properties of carbonyl were studied and tn SEM graphs of picolinic acid, meta-methyl benzoic acid and 2-chloro-benzoic acid systems, a large amount of chains like structures probably caused by crystal growth have been firstly observed.

首次在杯[4]芳烃下沿羟基引进亲电性的三乙氧基硅基异腈酸丙酯,并且根据能量传递与匹配的机理合成了五种新型以改性超分子为功能片段的强键型杂化材料,其中与铽能量传递与发射情况最为优异。

It was reported that benzylidenemalononitrile did not react with 1-benzyl-1,4-dihydronicotinamide. However, similar reaction easily takes place under the same condition when the phenyl group is replaced by the pyridyl group.

本课题组之前报道了苯亚甲基丙二腈在室温下不能被BNAH所还原,本论文将反应底物中的苯基换成吡啶基之后,在同样的实验条件下,反应可以比较顺利的进行。

0Mol%. The catalytic system combining Pd 〓, imidazolium salt and pyridine has been employed in the cross-coupling of unactive aryl chlorides with malononitrile.

对大多数溴代芳烃而言,无论芳环上取代基是吸电子的,还是给电子取代基,均可高产率地制备得到相应的α—芳基丙二腈化合物(产率>85%)。

The combined extract was concentrated to dryness and redissolved in acetonitrile, then cleaned up by dispersive solid-phase extraction with sorbents of N-propyl ethylene diamine, graphited carbon black, and C18, and determined and confirmed by GC-NCI/MS.

样品经乙腈提取并浓缩后加入N-丙基乙二胺、石墨化碳黑和C183种填料进行分散固相萃取净化,气相色谱-负化学离子源质谱分时段选择离子监测技术测定与确证,外标法定量。

The polymer particles were prepared by copolymerization of phthalic aldehyde, allyl mercaptan and ethylene glycol dimethacrylate after heating. The fluorescence intensity of the polymer particles was very weak.

利用邻苯二甲醛与烯丙基硫醇、乙二醇二甲基丙烯酸酯在偶氮二异丁腈引发下热聚合制得了一种新型聚合物颗粒。

To improve the effect of CDCA on dissolving cholesterol gallstone, the water-soluble copolymers as polycarboxylic acid of comb-like copolymers and C_(60)-PCC were synthesized, which being used for modification of CDCA and strengthening effects of CDCA on dissolving the cholesterol gallstones by their entropy-repelled properties of comb-shaped side chains in buffers of phosphate and in model bile.The design theory of polymer was mainly employed to synthesis the conjugate of PCC-CDCA and C_(60)-PCC-CDCA by C_(60), polyoxyalkylene allylalkyldiether and maleic anhydride, which were copolymerized with AIBN as initiator, and then PCC or C_(60)-PCC were reacted with CDCA. The structures of the copolymers and the conjugates of PCC-CDCA and C_(60)-PCC-CDCA were confirmed with IR, TLC and TEM. The dissolving effects and the dissolution kinetics mechanism of cholesterol gallstone was inverstigated in PBS and in model bile of different cholesterol saturated index at pH7.4, including PCC-CDCA or C_(60)-PCC-CDCA.

利用高分子设计理论,以烯丙基聚氧乙烯基醚、顺丁烯二酸酐、C_(60)和CDCA为原料,以偶氮二异丁腈为引发剂,合成具有梳状侧链结构的梳状共聚物-CDCA结合物和C_(60)-梳状共聚物-CDCA结合物,以IR、TLC和TEM法表征共聚物的结构,并在pH7.4的PBS液和不同胆固醇饱和指数的模拟胆汁中进行溶石效果的研究,探讨在PBS液和不同CSI的模拟胆汁中结合物溶解胆固醇结石的效果和溶解动力学机制。

Company Profile Xiamen Fusite Rubber Co., Ltd., is a professional production of various kinds of rubber products and rubber metal combination of complementary services firms, mainly producing and processing rubber, silicone, nitrile rubber, ethylene-propylene rubber, SBR, natural rubber, fluoroelastomers such as temperature, oil, water, wear, sealing, shock absorption, anti-media, such as rubber.

厦门富士特橡塑有限公司,是一家专业生产各类橡胶制品及橡胶五金结合的配套服务厂商,主要生产加工橡胶、硅胶、丁腈胶、乙丙胶、丁苯胶、天然胶、氟橡胶等各类耐温、耐油、耐水,耐磨、密封、减震、耐介质等橡胶制品。

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By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候,里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色,卵在发育96h后卵基本全部孵化。

There was a conflict between plebs and patricians in ancient Rome in 494BC.

在公元前494年,罗马发生了一次平民反对贵族的斗争。