丙腈

For the reaction of benzaldehyde, malononitrile and α-naphthol, the ionic liquid can be recycled at least 3 times without the significant loss of activity.

以对氯苯甲醛、丙二腈和α-萘酚为模板反应，离子液体可重复使用3次，其催化活性没有明显降低，同时还探讨了该反应体系下的可能反应机理。

Study on Surface Enhanced Raman Scattering of Piperidine;2. Using piperidine as catalyst and ethanol as solvent, a series of new 2-amino-3-cyano-4-aryl-6-methoxy-1,4,9,10-tetrahydronaphtho[2,1-b]pyran derivatives were synthesized by one-pot reaction of aromatic aldehydes, malononitrile and 7-methoxy-1,2,3,4-tetrahydronaphthalen-2-one at room temperature in good yields.

以芳醛、丙二腈和 7 甲氧基 1，2 ，3 ，4 四氢萘 2 酮为原料，在六氢吡啶催化下以乙醇为溶剂，在室温合成了一系列新的 2 氨基 3 氰基 4 芳基 6 甲氧基 1，4，9，10 四氢萘并 [2 ，1 b]吡喃衍生物，反应条件温和，产率较高，并通过IR ，1HNMR和元素分析表征产物的结构，还通过单晶X射线衍射分析确证产物的构

Liquid-phase epoxidation of allyl chloride with hydrogen peroxide was carried out over Ti-MWW, a novel titanosilicate with the MWW structure, to synthesize epichiorohydrin selectively and effectively. Ti-MWW proved to be superior to the conventional TS-1 catalyst in both catalytic activity and product selectivity. Ti-MWW prefers aprotic solvents of acetone and acetonitrile, both of which can restrain the solvolysis of epichiorohydrin, whereas TS-1 favors a protic solvent of methanol.

研究了具有MWW结构的新一代钛硅分子筛Ti-MWW催化剂对烯丙基氯液相环氧化高效合成环氧氯丙烷的催化性能结果表明，Ti-MWW的催化活性以及产物选择性均优于传统的钛硅分子筛TS-1，对于Ti-MWW，合适的溶剂为非质子性溶剂丙酮和乙腈，在该溶剂中环氧化物不易发生溶剂化开环反应；而对于TS-1，合适的溶剂是质子性溶剂甲醇，但甲醇可导致醇醚副产物的生成。

Three methods are used to prepare molecular imprinted polymers,which include conventional bulk technique or polymerization with ultraviolet initiated in low temperature and polymerization with silica-gel as sacrificial materials. In the polymerization procedure , Sulfamethazine(SM2)and Sulfisoxazole were used as target template molecules, methacrylic acid and 4-vinylpyridine(4-VP) and acrylamide were selected as functional monomers, ethylene glycol dimethacrylate as crosslinker, azobisisobutyronitrile was used as initator.

主要工作如下：首先，以磺胺异噁唑和磺胺二甲嘧啶为模板，分别以4-乙烯基吡啶，甲基丙烯酸，丙烯酰胺为功能单体，以二甲基丙烯酸乙二醇酯为交联剂，偶氮二异丁腈为引发剂，采用了传统方法(60℃恒温水浴)、牺牲硅胶法及低温紫外光聚合法等三种方法合成了一系列的磺胺类药物印迹聚合物。

Using N, N-dimethyl-ethylenediamine as cationic substitute and 2-hydroxyethyl methacrylate or allylamine as co-substitute, a kind of pH-sensitive polyorganophosphazenes bearing unsaturated side group was prepared.

以N，N-二甲基乙二胺为阳离子型取代基，甲基丙烯酸羟乙酯或烯丙胺为共取代基，制备了同时带有pH响应性侧基和不饱和双键侧基的聚膦腈。

Although these inhibitors including 19 compounds of benzylidene malononitrile family and 13 compounds of 3-substituted indolin-2-ones family, possess quite different structures,a common pharmacophore model with very good stratistical results was determined.

尽管亚苄基丙二腈化合物和3-取代吲哚啉-2-酮系列化合物具有完全不同的骨架结构，但得到的药效团却具有共同的特性，这表明当这两类抑制剂和受体发生相互作用时，采用了相似的结合模式。

The controlled/living radical polymerization of methacrylates containing carbazolyl or 1,3,4-oxadiazolyl groups via RAFT polymerization was successfully demonstrated. Functional polymers poly, poly, poly, and poly with hole- or electron-transfer ability were synthesized with cumyl dithiobenzoate as a chain transfer agent and AIBN as an initiator in a benzene solution.

以合成的二硫代苯甲酸酯异丙苯酯为链转移剂、偶氮二异丁腈为引发剂，通过RAFT可控／活性自由基聚合方法成功地合成了侧链上悬垂空穴传输基团或电子传输基团(1，3，4-噁二唑基团)的光电功能聚合物：poly、poly和poly、poly。

In addition, the catalytic coupling of iodobenzene with cyanoacetate has been studied.

本方法具有催化效率高，反应条件温和的特点，可顺利地制备得到α—芳基丙二腈化合物。

In contrast to the previous work in which the ILs were used as solvents,[14,15,21] we observed that when this IL was used in a catalytic amount, the Knoevenagel condensation between ethyl cyanoacetate or malononitrile and carbonyl compounds (Scheme 1) could be performed with high efficiency.

和之前离子液体被用作溶剂的工作作为对比，[14，15，21]我们发现使用催化剂量的这种离子液体时，氰基乙酸乙酯或丙二腈和羰基化合物之间的Knoevenagel缩合(图示1)可以体现出高效率。

The propanedinitrile is synthesised from ethyl cyanoacetate by amination and elimination reaction.

由氰乙酸乙酯与氨反应生成氰乙酰胺，再经过消除反应制得丙二腈。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。