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丙硅烷

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The catalyst includes: supported Ziegler-Natta catalyst of titanium halide compound and organic electron donor compound supported with MgCl2 alcoholate carrier; aluminoxane prepared with trialkyl aluminum and water; and one kind of organic electron donor, such as organosilicon compound R2Si(OCH3)2, where R is phenyl, isopropyl, isobutyl or cyclopentyl.

该催化剂包括,a一种负载型的Ziegler-Natta催化剂,即将卤钛化合物和有机给电子体化合物负载在氯化镁醇合物载体上得到的固体催化剂,b一种通过三烷基铝与水反应而制备得到的铝氧烷和c一种有机电子给体,如有机硅化合物R 2 Si(OCH 3 ) 2 ,其中R为苯基、异丙基、异丁基或环戊基。

Objective: To sexplore the anti-tumor activity to Hela, SW480 and A549 and the growth regulative activitiy to radishes of amphibrya besides corns of dicotyledon of the target compound γ-(N-p-methylphenylsulfonyl) aminopropyl-3, 7, 10-trimethyl-2, 8, 9-trioxa-5-aza1-1-silicontricyclo [3, 3, 3, 0(superscript 1,5)] Undecanes.

目的:探讨目标化合物γ-丙基-3,7,10-三甲基-2,8,9-三氧杂-5-氮杂-1-硅杂三环[3,3,3,0(上标 1,5)]十一碳烷对人宫颈癌细胞、人结肠癌细胞(SW480)和人肺腺癌细胞(A549)的抗肿瘤效应以及对单子叶植物玉米、双子叶植物萝卜的生长调节作用。

A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.

一种用于丙烯聚合的催化剂组合物,所述催化剂组合物包括:一种或多种齐格勒-纳塔主催化剂组合物,该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体;一种或多种包含铝的助催化剂;选择性控制剂,该选择性控制剂包括至少一种包含硅的化合物,该化合物包括至少一种与硅原子连接的C 1-10 烷氧基;和一种或多种活性限制剂化合物,该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。

Water,dimethicone,propylene glycol,glycerin,cyclomethicone,ppg-15 stearyl ether,sorbitan oleate,stearic acid,cetyl alcohol,glyceryl stearate,ethylhexyl methoxycinnamate,peg-100 stearate,panthenol,phenoxyethanol,phospholipids,triethanolamine,methylparaben,oenothera biennis oil,imidazolidinyl urea,carbomer,c12-13 alkyl lactate,glycyrrhetinic acid,citrus aurantium dulcisoil,propylparaben,tocopheryl acetate,benzophenone-3,triclosan,disodium edta,ethylparaben,pentadecalactone,iris germanica root extract,retinyl palmitate,bisabolol,butylparaben,sodium hyaluronate,aesculus hippocastanumseed extract,ruscus aculeatus root extract,chlorhexidine digluconate,biosaccharide gum-1,citrus aurantium amaraoil,tocopherol,lecithin,ascorbyl palmitate,glyceryl oleate,BHT,citric acid,limonene,linalool

水, 地美司康,丙二醇,甘油,环甲硅脂, PPG-15 硬脂基醚,油酸己六酯,硬脂酸,十六醇,甘油硬脂酸, 4-甲氧基肉桂酸-2-乙基己基酯,聚乙二醇硬脂酸酯,维生素B5,苯氧乙醇,磷脂质,三乙醇胺,羟苯甲酯,月见草油,尿素醛,卡波姆, c12-13烷醇乳酸酯,甘草亭酸,甜橙油,羟苯丙酯,醋酸盐维他命E,二苯酮-3,玉洁新,乙酸乙二胺二钠,羟苯乙酯,环十五内酯,鸢尾花根萃取,维他命A酯,没药醇,羟苯丁酯,透明质酸钠,欧洲七叶树籽萃取,假叶树根萃取,洗必泰葡萄糖酸盐,多醣物质,苦橙油,维生素E,卵燐脂,抗坏血酸棕榈酸酯,甘油油酸酯,二丁基羟基甲苯,柠檬酸,柠檬精油,芳樟醇水:几乎所有护肤品成分第一位都是水。地美司康:即silicon,矽灵,一般添加于霜剂中,使用后皮肤手感光滑。该成分不可吸收。

In order to check the corresponding compound at 31P NMR –45.4 ppm, stable pentacoordinate spirobicyclic 2-phenoxy-1,3-phenylene-dioxo-1,3,2-iminoacetoxyphosphoranes were synthesized through a new and efficient method whereby phosphorus pentachloride was displaced stepwise by catechol, N,O-bisamino acid and phenol, or catechol, phenol and N,O-bisamino acid, their 31P NMR chemical shifts are at about 31P NMR –45.0 ppm, the results showed that the compound 4 at 31P NMR –45.4 ppm was pentacoordinate phosphorane containing amino acid residue.

采用磷谱跟踪来研究上述成肽反应机理。例如在氮气保护下,0.1mmol O,O-亚苯基磷酰氯(1)和0.15mmol N,O-二苯丙氨酸(2)苯溶液加入0.6ml核磁管中,混合均匀,反应过程用磷谱检测。反应1分钟后,起始原料1(δp=19ppm)很快转变成N-磷酰苯丙氨酸的三甲基硅基酯(3)(δp=19.8ppm),在8分钟内,3完全转变成苯丙氨酸磷烷4(δp =-45.4ppm),同时出现环磷三酯(6)(δp=3.5ppm)。随着反应的进行,对应于化合物4的峰逐渐变小,而6逐渐变大。

Thirty-one new chiral phosphorus compounds have been synthesized starting from D-camphor,-alpha-phenylethylamine,-Betti base,-1-(4-nitrophenyl)-2-amino- propane-1,3-diol, L-amino acids (such as serine, phenylalanine, proline etc.) and their application as organocatalysts in asymmetric trimethylsilylcyanation of aldehydes and asymmetric borane reduction of prochiral ketones and ketimines were investigated.

该项目从D-樟脑、-alpha-苯乙胺、-Betti碱、-氯酶胺、L-氨基酸(如丝氨酸、苯丙氨酸、脯氨酸等)出发合成了31个新的手性磷化合物,研究了它们作为有机催化剂在醛的不对称硅氰化反应、潜手性酮的不对称硼烷还原反应以及亚胺的不对称硼烷还原反应中的催化效果。

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