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A series of UV curable waterborne hyperbranched polyester s with different acid/amine terminal rate,which contained -OH?-COOH and methacrylic chain end groups,and were partly neutralized with thertiary amine,were synthesized from trimellitic anhydride,epichlorohydrin,glycidyl methacrylate and triethylamine.

以偏苯三酸酐、环氧氯丙烷、甲基丙烯酸缩水甘油酯、三乙胺合成了末端羧基与氨基不同比例的一系列可UV固化的高支化聚酯,研究了末端官能团对合成产物水溶性、粘度以及凝胶转化率的影响。

Water-soluble air drying alkyd resin is formulated by flax oil acid,trimethylol propane,dimethyl isophthalate,benzoic acid,maleic anhydride and trimellitic anhydride.

以亚麻油酸、三羟甲基丙烷、间苯二甲酸、苯甲酸、顺丁烯二酸酐、偏苯三酸酐为原料合成水溶性醇酸树脂,中和后制得的涂料具有干性好、硬度高、耐水性和贮存稳定性优良等特性。

An expansion monomer 3, 9-dihydroxymethyl-di (6-methyl-5 -hydroxyl)-2- heptanone-1, 5, 7, 11tetraoxaspiro [5, 5] undecane was synthesized and its volume change during polymerization is about +3.04%. Its prepolymer was also synthesized by toluene 2, 4-diisocyanide with it.

由三经甲基丙烷合成了螺环原碳酸酯单体3'、9'-二羟甲基-3',9'-二乙基-1,5,7,11--四氧杂螺环[5、5]十一烷单体(体积膨胀率+3.04%)以及它的预聚物,并用其来改性环氧树脂B-63。

Markstein length increases with the increase of dilution ratio when equivalence ratio is less than 1.4, and the flame stability tends to increase with the increase of dilution ratio. The ratio of unstretched laminar burning velocity with and without diluent is only related to the dilution ratio and is little influenced by the equivalence ratio.

丙烷-空气-稀释气混合气随稀释系数的增加,火焰传播速率和层流燃烧速率降低,在当量比小于1.4时,随稀释系数的增加,马克斯坦长度值增加,火焰前锋面的稳定性趋势增加。

The average epoxy value and the average viscosity of such diluent were 0.502×10-2eq/g and 3.2 mPa.s(25 ℃) respectively. It was an ideal diluent and could be used instead of active diluent such as butyl epihydrin etc. and non-active diluent such as dibutyl phthalate etc. in epoxy resin industry. The preparation of the epoxy diluent by fusel oil could not only settle the problem of environmental pollution caused by fusel oil drainage, but also produce economic and social benefits.

结果表明,杂醇油制备的环氧树脂活性稀释剂环氧值平均为0.502×10-2eq/g,环氧值适中;粘度平均值为3.2 mPa.s(25 ℃),粘度较小,为比较理想的环氧树脂活性稀释剂;该环氧树脂活性稀释剂可望代替环氧丙烷丁基醚等活性稀释剂和邻苯二甲酸二丁酯等非活性稀释剂应用于环氧树脂工业;可解决酿酒企业和酒精厂下脚料杂醇油排放带来的环境污染问题。

At 275℃, with Al2(SO4)3/K2SO4 mixed catalyst, which the mass ratio was 15:85, the conversion ratio of propylene oxid could be as high as 97.60%, and the selectivity of propionaldehyde was 94.57

其中有如Al2(SO4)3/K2SO4(质量比15∶85)混合型催化剂在275℃时,环氧丙烷转化率达到97.60%,丙醛选择性达到94.57

Bezaldehyde was used as protective agent in first method.S-Epichloeohydrin was aminated and acidulated to give(2S)-1-Amino-3-chloro-propanol Salts.The acetylation of (2S)-1-Amino-3-chloro-propanol by acetic anhydride produced the intermediate-N-[2--3-chloropropyl]acetamide.And then at 20℃,in the presence of lithium tert-butoxide,benzyl 3-fluoro-4-morpholinophenyl carbamate react with-N-[2--3-chloropropyl]acetamide to give linezolid in total yield of 43.6%.

路线一采用苯甲醛作保护剂,使S-环氧氯丙烷氨解、酸化生成S-1-氨基-3-氯-2-丙醇盐酸盐,然后经乙酰化反应后,生成中间体-N-[2-乙酰氧基-3-氯丙基]乙酰胺,再用N-(3-氟-4-吗啉苯基)氨基甲酸苄酯和中间体在催化剂叔丁醇锂存在下25℃反应生成利奈唑酮,总产率达到43.6%。

Including high temperature for the pyrolysis of natural gas to produce carbon black and acetylene; steam reforming of natural gas or partial oxidation of natural gas, synthetic gas can be obtained; natural gas through chlorination, sulfide, nitrification, ammoniated oxide, oxidation can be obtained A N all kinds of derivatives; in the wet gas ethane, propane, butane and natural gas liquid condensate, and so on, the steam cracker or pyrolysis to produce ethylene, propylene and butadiene; dehydrogenation of butane oxidation or produce small Diene or acetic acid, methyl ethyl ketone, and maleic anhydride, and so on.

包括在高温下进行的天然气热裂解,主要生产乙炔和炭黑;天然气蒸汽转化或天然气的部分氧化,可制得合成气;天然气经过氯化、硫化、硝化、氨化氧化、氧化可制得甲烷的各种衍生物;湿性天然气中的乙烷、丙烷、丁烷和天然气凝析液等,经蒸汽裂解或热裂解可生产乙烯、丙烯和丁二烯;丁烷脱氢或氧化可生产丁二烯或醋酸、甲基乙基酮、顺丁烯二酸酐等。

The wastewater containing epichlorohydrin is high toxic and hard to be biodegraded, which is not fit for biological treatment. The oxidation process of Fenton reagent was put forward.

环氧氯丙烷废水毒性强、生物降解性差,不适合用一般的生物方法处理,提出Fenton试剂氧化处理的方法。

One-step synthesis of the high molecular weight bromated epoxy resins for flame retardants is studied with tetrabromobisphenol A and epichlorohydrin as raw materials in mixed solvent comprising 1,4-dioxan and water.

研究以四溴双酚A和环氧氯丙烷为原料在二氧六环和水混合溶剂中一步法合成了高分子量溴化环氧树脂阻燃剂。

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