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PEVOH-SO3 Na is prepared by sulfonification of PEVOH with 1,3-propane sultone and characterized by IR, H1 NMR.

采用PEVOH和1,3-丙烷磺酸内酯合成了PEVOH磺酸钠,并对其结构进行了红外和核磁表征。

To economize cost of S03H-functionalized ionic liquids,extend their range of application in chemistry reaction,fifteen of ionic liquids have been synthesized by using methylimidazole,tri-alkylamine,pyridine with industrial materials 1,4-butane-sultone and 1,3-propane sultone as source in this paper.The ionic liquids were synthesized by tri-alkylamine have not been reported and yields are higher than 98%.

为了降低SO_3H-功能化离子液体的成本,使其应用范围更加广泛,本论文利用N-甲基咪唑、三烷基胺、吡啶和廉价工业级原料1,3-丙烷磺内酯、1,4-丁烷磺内酯为原料来源,合成十五种SO_3H-功能化离子液体,三甲胺为原料合成的SO_3H-功能化离子液体还未见文献报道,收率大于98%。

A series of ABEPS were synthesized from long chain fatty acids, benzene, polyglycol and 1, 3-propane sultone by the procedure of Friedel-Crafts acylation, Huang-Minlon reduction, Williamson and sulfonation reaction, and these compounds had never been reported in the past time.

以长链羧酸、苯、多缩乙二醇和丙烷磺内酯为初始原料,依次经Friedel-Crafts酰基化反应、Huang-Minlon还原、Blank反应、Williamson成醚以及磺化反应等过程,合成了系列未见报道的ABEPS。

The p-tert-butyl calix arene (n=4,6,8) were synthesized by p-tert-butyl phenol, formaldehyde aqueous solution as raw materials. Six kinds of calixarene oligomeric surfactants were prepared by etherification of the calix arene with 1,3-propane sultone and 1,4-butane sultone.

以对叔丁基苯酚、甲醛为主要原料合成杯芳烃母体对叔丁基杯芳烃(n=4,6,8);以1,3-丙烷磺内酯、1,4-丁烷磺内酯为醚化试剂,经Williamson醚化反应,合成出6种杯芳烃基低聚表面活性剂。

Main products are Perfluorosulfonated acid resin, PFSA aqueous dispersion, and on the basic of them, HFPO,TFE sultone,PSVE,PPVE,MTPME etc fluorinated fine chemicals,and FEP,FKM,PVDF etc fluorpolymers.

公司主导产品有全氟磺酸离子交换树脂、全氟磺酸离子交换树脂溶液,同时以此为依托,配套生产六氟环氧丙烷、四氟磺内酯、PSVE、PPVE、甲氧基四氟丙酸甲酯等含氟精细化学品,聚全氟乙丙烯树脂(FEP,F46)及分散液、氟橡胶、聚偏氟乙烯等含氟高分子材料。

In this paper,the toluene -2,4-diisocyanate and trimethylol-propane are usedto synthetize curing agent for polyurethan.

本文用2,4-甲苯二异氰酸酯和三羟甲基丙烷为原料合成聚氨酯固化剂,用该固化剂固化含羟基的树脂。

It is found that the stereochemistry of the reactions of telluronium allylide,crotonylide and trimethylsilyallylide with α,β-unsaturated esters and amides can be tuned by thechoice of reaction conditions.

利用反应条件的变化首次实现了烯丙基、巴豆基、含硅烯丙基碲叶立德与α,β-不饱和酯、酰胺进行环丙烷反应的立体化学调控,能高立体选择性地、高效率地合成两种不同几何异构体中的一个。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α,β-不饱和酮反应的立体化学完全不同,得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

Part Ⅱ: The evelopropanation reactions of both semi-stabilized telluronium and arsoniumylides with α,β--unsaturated ketones proceed smoothly.

第二部分:烯丙基、巴豆基、三甲基硅基烯丙基、肉桂基、苄基碲、胂两种叶立德与α,β-不饱和酮均可以成功地进行环丙烷化反应,并且表现出不同的立体选择性。

The telomerization reaction kinetics of 1,1,1,3-tetrachloropropane synthesis using tetrachloromethane and ethylene as raw materials was studied.

研究了以四氯化碳和乙烯为原料合成1,1,1,3-四氯丙烷的调聚反应动力学。

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