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By employing such a method, 5 series of elastomers, including natural rubbers, elastomeric polyester fibers and ethylene-octene, ethylene-methyl acrylate as well as SIS triblock copolymers, were investigated with the purpose of studying elongation induced phase structure and mobility changes of the samples. For NR samples, it was demonstrated that there exists a small amount of crystals at RT even for unelongated samples. For both NR and the soft segment of PEE, with the increase of elongation ratio, the elongation-induced crystallinity increases almost linearly in a certain region of R, in accord with the increase of the lamellar thickness of the crystals; The behavior of ethylene copolymers, in terms of elongation induced morphorpholgy changes, are quite different from NR and PEE. The crystals are found to be gradually destroyed with the increase of R, with accord with the decrease of the lamellar thickness; The motional behavior of the soft segment of SIS, changes from "liquid" to "solid", in terms of 13C NMR spin-lattice relaxation.For many of the aformented samples, the dependence of 13C spin-lattice relaxtion time T1 on R are different for different groups, indicating that the changes of mobility at MHz frequency region with elongation are different for different groups.

通过对天然橡胶、聚醚酯嵌段共聚物、乙烯-辛烯共聚物、乙烯-丙烯酸甲酯共聚物、SIS等高分子弹性体样品聚集态结构和分子运动的研究,获得了一些新的实验结果,如:给出了确切的实验证据,证明了室温下未拉伸的天然橡胶样品中存在着微量的结晶;发现随着拉伸比增加,天然橡胶及聚醚酯样品的软段部分会出现拉伸诱导的结晶,且结晶度在一定范围内呈现近似线性的增加,所形成晶片的厚度也随之逐渐增加;而乙烯共聚物随着拉伸比的增加,原有的结晶会被逐渐破坏,晶片厚度逐渐变薄,结晶中的缺陷逐渐增加;随着拉伸比的增加,SIS中PI软段部分的核磁共振弛豫行为会出现从液态到固态的转变等;在对上述多个体系的研究中,还发现不同基团的自旋-晶格弛豫时间随着拉伸比呈现不同的变化趋势,表明不同基团的高频运动随拉伸比增加有不同的变化规律。

With the increase in CO(NH2)2 concentration,the molecular weight significantly increased,and the best concentration scope of DMAEMA was 0.06%-0.10%.Inaddition,the agents for preventing cross-linking were used to prevent the cross-linking reaction and it content was not allowed too high,and the best concentration scope of sodium acetate(the regulator of molecula weight)was

在此中和度下,AMPS的适宜用量范围为AM的75%~16.25%;AA的适宜用量范围44%~55%;(NH4)2S2O8的适宜用量范围为AM/AA/AMPS总量的0.07%~0.12%;分子量随CO(NH2)2的增加而明显升高;甲基丙烯酸N,N-二甲氨基乙酯的适宜用量范围为0.06 %~0.10%;使用抗交联剂可以解决产品交联造成的难溶问题,但加入量不宜过多,否则分子量会下降;分子量调节剂醋酸钠的用量在1.24 %~1.54%范围内可以使产品的分子量达最佳值。

Business card printing and membership card making Ink viscosity in business card printing and membership card making faster, rollers and plates after the ink friction heats gets smaller, on the rising of the ambient temperature, the viscosity of ink will drift away, this time using the innovativeink, with the temperature increase, decrease viscosity is referred to as a viscosity index of added value, that is, the viscosity index is a viscosity index of temperature-dependent, for example, at a low temperature solvent oil sludge formation, if you join methylmetacrylate and transfromer monosomic of multi-fault copolymer exclude this.

制卡和会员卡制作油墨的粘度在随制卡和会员卡制作速度的加快时,因墨辊与印版摩擦后油墨温度升高而变小外,当环境温度的上升后,油墨的粘度也会逐渐变小,这种在使用油墨时,随着温度的上升,其粘度下降的行为被称为粘度指数增加值,即粘度指数是表示粘度随温度变化的指标,例如,溶剂油在低温下形成淤浆时,如果加入甲基丙烯酸酯和极性单体的共聚物排除此类故障的发生。

Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.

第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂,着重考察了CTSB—G—Hy的制备条件,并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件,结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4~6.5之间,吸附剂用量为5g/L,吸附时间为1h时pb~(2+)去除率高于94%,CTS—PA_4可在酸性条件下使用,在碱性条件下依然有效但处理效果较差;CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L,吸附时间为1h时处理效果极佳,pb~(2+)去除率高于96%;CTSB—G—Hy对pb~(2+)具有一定的吸附能力,吸附剂用量为3g/L,吸附时间为1.5h时处理效果最佳,Pb~(2+)去除率高于93%,而且CTSB—G—Hy的机械强度高,耐酸碱性强,可在较宽的pH范围内使用。

The research of polymer/layered silicate nanocomposite was introduced detailedly, including the classify, property and the latest research advance. On the basis of consulting the document and the exploratory experiment, the experimental method which first creative preparing poly (acrylonitrile-vinyl acetate)/raontmorillonite nanocomposite by emulsion intercalation copolymerization was established; the structure and property of polyacrylonitrle different molecule weight with inorganic mineral super fine nanocomposite was reseached. The reaction principle of PMMA by photo-initution was explored. The mixture principle with productor condition, property of PE/Clay nanocomposite milt insert was seal prived. By PS/Clay nanocomposite munufacture, the monomer ins-polymerization and polymerial solution was proved.

在查阅文献和探索性实验的基础上,确定采用乳液原位插层聚合方法首先创制了聚/蒙脱土纳米复合材料,利用正交实验得出了最佳实验条件,通过X射线衍射和红外光谱对纳米复合材料的结构进行表征,研究了复合材料的溶解性能,并测定了其溶液的绝对粘度;研究了不同相对分子质量的聚丙烯腈与不同的无机矿物超细粉复合材料的结构与性能;探讨了在蒙脱土中光引发聚甲基丙烯酸甲酯的反应机理;通过聚乙烯与粘土的纳米复合材料制备,探讨了热塑性树脂熔融插层复合机理与最佳工艺条件和复合材料性能关系;通过聚苯乙烯与蒙脱土纳米复合材料制备,验证了单体原位聚合插层和聚合物溶液插层机理。

The results from the experiment are: the amount of all micro-powders that grain sizes are less 0.044 mm should be less than 35% in weight, and the value of coarse q and attenuate q should be respectively 0.23 and 0.32, and the additive amount of active a-alumina and calcium alumina cement should be respectively 7% and 4% in weight, meanwhile, the best dispersant is PMAA-NH4 in the non-microsilica system; while the value of two q should be respectively 0.21 and 0.29, the amount of active a-alumina, microsilica and calcium alumina cement should be respectively 6%, 2% and 4% in weight, the best dispersants are sodium hexamer taphosphate and Na2P3Oio in the microsilica system.

依照上述实验方法得出刚玉自流浇注料所必备的条件:刚玉自流浇注料中的细粉(-0.044mm)总量应小于35%;在无硅微粉系统中的Andreassen公式的粗端q值和细端q值分别为0.23和0.32,氧化铝微粉、水泥的最佳加入量是7%、4%,且所使用的分散剂为改性聚丙烯酸钠最好,而在含硅微粉系统中的Andreassen公式的粗端q值和细端q值分别为0.21和0.29,氧化铝微粉、硅微粉和水泥的最佳加入量为6%、2%和4%,最好合用三聚磷酸钠和六偏磷酸钠作为分散剂。

The results showed that the adhesion characteristic between PC and acrylate adhesive was significantly improved after modification because of ion beam bombardment resulted in excellent hydrophilicity, increasing of the polarity, denuding of the weak boundary and engendering of crosslinked boundary.

结果表明:改性后的PC与丙烯酸酯胶黏剂的压剪强度得到了明显的改善。经分析,粘接性能的改善是由于低能离子束表面改性后的PC表面润湿性能的改善、表面活性的提高、表面弱电层的剥蚀和表面微交联层的生成引起的。

Emulsification is the mainly reason to influence on the reaction, the influences of emulsifiers such as the concentration of emulsifies, the ratio of anionic to nonionic emulsifier on the polymerization stability were researched;The influences of concentration and feeding method of initiators on the reaction stability and the mechanical properties of coating film of acrylate polymerization stability were researched;The influences of reaction temperature, stirring speed and pH buffer agent on the polymerization stability and pH regulator on the storage stability of Acrylate emulsions were also researched.

乳化剂是影响乳液稳定性的主要因素,因此对乳化剂进行了全面的探讨,包括乳化剂的种类和用量、阴离子型与非离子型乳化剂的比例对乳液稳定性的影响;文中还研究了引发剂的用量、加入方式对聚合稳定性的影响,以及引发剂用量对聚丙烯酸酯涂膜力学性能的影响;此外,讨论了反应温度、搅拌速率、pH值缓冲剂对乳液聚合过程稳定性的影响及pH调节剂对乳液贮存稳定性的影响。

AbstractObjectives1 Correlate bone mineral densityto vertebral compressive strengths.2 Consummate the technique for percutaneous polymethylmethacrylate vertebroplasty and observe the pattern of PMMA imaging distribution.3 Determine the strength and stiffness of osteoporotic with or without vertebroplasty with PMMA bone cement.4 Correlation of BMD,insertion torque and pull-out strengths of pedicle screws.5 Ascertain whether augmentation with PMMA bone cement can enhance pedicle screw fixation in the osteoporotic spine.6 Ascertain whether augmentation pedicle screw fixation with PMMA bone cement can enhance the stability of unstable thoracolurner burst fractures of osteoporotic spine.

目 的1、测试椎体压缩强度,分析强度与骨矿物质密度(bone mineral density,BMD)的相关关系。2、观察经皮椎体成形术后聚甲基丙烯酸甲脂(polymethylme- thacrylate,PMMA)骨水泥在椎体内的形态学分布及影像学表现。3、比较PMMA骨水泥骨质疏松椎体成形术前/后椎体最大抗压力和压缩刚度的变化。4、分析椎体BMD、螺钉最大旅入力矩和最大拔出力三者之间的关系。5、分析PMMA骨水泥强化骨质疏松椎弓根螺钉后的螺钉的最大轴向拔出力和拔出刚度的变化。6、评价PMMA骨水泥强化骨质疏松椎弓根螺钉脊柱内固定对不稳定型胸腰椎损伤的即刻稳定性和反复载荷后的稳定性。

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But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊!不用提了。提到肉,真是糟透了。

Tristan, I have nowhere to send this letter and no reason to believe you wish to receive it.

Tristan ,我不知道把这信寄到哪里,也不知道你是否想收到它。