丙烯酸的

Main component of composition of the negative type photoresistive agent is polyimide, which possesses pendent -COOH. Reaction between partial carboxylic acid group and monomer with glycidyl acrylate generates bond junction. Rudimental other part of carboxylic acid group and additional additive component with third amino group and monomer of C=C double bond forms ionic bond junction.

本发明的负型光阻剂组合物的一主要成份为聚亚酰胺其具有悬垂的-COOH且部分的羧酸基与带有环氧基团的丙烯酸酯单体glycidyl(methacrylate反应形成键结，而残留的另一部分羧酸基与另外添加的成份带有第三胺基及C＝C双键的单体形成离子键结。

The results are listed as following :㏕he best anti-erosion proportion of resin present is 25wt% in the condition of silicon carbide reinforced SMCC, while the alumina reinforced SMCC is 40wt%.(2) The better anti-erosion results was achieved with the ratio of silicone resin to acrylic resin containing hydroxy being 3: 1.㏕he composites coating tends to be more brittle when added in alundum particles. It also means that the maximum erosion peak of alundum reinforced SMCC tends to normal angle.甌he change of erosion rate of SMCC can be divided into two stages with the increment erodent velocity: the slow erosion stage of the beginning and the stable erosion stage.

首次发现：①SiC增强的复合涂料涂层，树脂含量为25wt％时，具有最佳耐冲蚀性能：Al_2O_3增强的复合涂料涂层，树脂含量为40wt％时，具有最佳耐冲蚀性能；②SiC增强的涂料，有机硅树脂与丙烯酸树脂的比例为3：1时的耐冲蚀性能好于1：1的复合涂料涂层；③Al_2O_3增强体使涂层变脆的倾向大于以SiC为增强体的涂层，即SiC增强的复合涂料涂层的最大冲蚀率出现在30°，Al_2O_3增强的复合涂料涂层的最大冲蚀率出现在75°～90°之间；④低速冲蚀磨损机理主要是弹性变形与疲劳；高速冲蚀磨损机理主要是显微切削和显微犁耕。

The molecular weight dependence of the distribfition of polymer molecules between the coacervate and the dilute phases on the phase separation of polymethylmethacrylate-acetone-methanol system has been proved to follow the relation first derived by Flory for binary systems: f"_j/f′_j = Qe~_j where f"_j and f′_j are the weight fractions of the polymer molecules of molecular weight M_j in the coacervate and in the dilute phases respectively, while Q and σ are parameters.

1。聚甲基丙烯酸甲酯-丙酮-甲醇体系的两次分相实验用θ-溶剂中的沉降速度法测定分相前试样和浓相的分子量分布曲线，得到高分子在浓稀相重量分配的分子量依赖关系 f_j=Qe~证实Flory的溶度函数形式与实际相符，并适用于三元体系的相分离，但Q值与两相体积比R值并不相同。 2。再分级使级分的分子量分布宽度随再分级次数的增加而减小，通常认为到第三次再分级其效果已不显著并不确实。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示：复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素，它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性，还有乳液涂膜的接触角等造成不同程度的影响；引发剂主要影响反应速率和凝胶率；丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度，有机硅单体主要影响涂膜的吸水率等；聚合反应温度主要影响乳液的反应速率和转化率等；搅拌强度主要是影响到聚合过程的凝胶率。

More levels of nano-SiO〓 lead to larger particle size. An increase in polymerization reaction temperature causes the decrease in coagulum and increase in viscosity and particle size, and the nano-SiO〓 has same effects at certain temperature. When the levels of hydrophilic monomer acrylic acid and hydroxylethyl methacrylate in core composite are increased, the particle size of emulsifier-free emulsion decreases, in spite of the presence of nano-SiO〓.

无皂乳液具有单分散性好、表面洁净、成本低廉、不影响产品性能的特点，首次研究了含或不含纳米粒子的含羟基和羧基的丙烯酸无皂乳液聚合，发现含或不含纳米粒子的无皂乳液聚合后的粒子粒径较大，具有单分散性；较多的纳米粒子导致较大的乳液粒径；反应温度升高，凝聚物含量下降，而乳液粘度和乳胶粒粒径增加，在相同的反应温度下，纳米粒子降低了聚合过程中的凝聚物含量，增加了乳液聚合物的粘度和粒径；不论纳米粒子是否存在，当无皂乳液核组成中亲水单体AA和HEMA用量增加时，乳胶粒粒径均减少。

The crystallizability and solution properties of polyacrylate depressants and their depressive effects on two waxy oils were studied. It was found that the crystallizability of PA depended on the length of its side chain and molecular weight. Gel was observed in the concentrated solution, The temperature of gelation, which was a measure of the crystallizability of PA in solution, was higher for the PA itself with stronger crystallizability.

对聚丙烯酸长链酯的结晶能力和溶液性质及其对两种含蜡油的降凝效果进行了研究，发现PA的结晶能力取决于PA侧链长度和相对分子质量，而其在溶液中形成冻胶或沉淀的温度（反映PA在溶液中的结晶能力）与PA本体的结晶能力有关，而PA对含蜡油的降凝效果则与PA在油中的结晶能力有关。

The fabrication of fibers was attempted. The copolymers, the copolymers containing MOCT and the copolymer films containing MOCT were characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy, Differential Scanning Calorimetry, Thermogravimetric Analyzer and X-ray Diffraction etc. The conclusions were summarized as following,1. The AN/MMA copolymers were testified that copolymerization of most AN and MMA occurred and the ratio of AN and MMA in copolymer was less than the ratio of monomers. With the increase of the contents of MMA, the viscosity of copolymer solution, molecular weight and decomposition temperature of copolymers increase.

通过傅立叶变换红外光谱、扫描电子显微镜、差示扫描量热分析、热重分析、X-射线衍射分析等测试方法对得到的AN／MMA共聚物、含有正十八烷微胶囊的共聚物以及共聚物膜等进行了测试和分析，得到如下的研究结论： 1、丙烯腈—甲基丙烯酸甲酯之间发生了聚合反应，共聚物的组成比略小于投料比；共聚物的粘度和分子量随着第二单体MMA加入量的增加有增大的趋势；第二单体加入量的增大使得共聚物的分解温度升高，通过热重分析证实当AN／MMA摩尔比为85／15时，共聚物的耐热稳定性较高。

The main contents are as follows:(1) The acrylic adhesive was synthesized by the method of semicontinuous emulsion polymerization. The effect of the weight ratio of monomer, type and quantity of functional monomer, the amount of emulsifier, reaction time and temperature on the properties of adhesive was discussed. And the molecular structure of the acrylate adhesive was characterized by FT-IR. Finally, the better production process of acrylic adhesive was determined.

具体内容如下： 1、采用半连续种子聚合的方法合成丙烯酸酯型胶粘剂，探讨了合成胶粘剂的软硬单体的配比、功能性单体的种类、用量及工艺条件(乳化剂的用量、反应时间和温度)对胶粘剂各项性能的影响，通过红外光谱对胶粘剂的微观结构进行表征，并最终确定较好的工艺配方。

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用，在机理研究的基础上，本论文选择五种不同结构的甲基丙烯酸酯类单体：lauryl methacrylate，(N，N-dimethylamino)ethyl methacrylate，polymethyl ether methacrylate，4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate，用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物，详细而深入地研究了它们的均聚、共聚动力学，发现了双硫酯并非在聚合反应初期就全部转化，而是随着反应进行逐步消耗，这与理想的活性聚合体系有很大差别。

E. OCB mode LCD elements . Then,we added bi-functional powder and LC E7 in the bulk copolymer of Poly Acrylic Acid and EOPO,then poured the LC solution,and exposed it with 5V voltages under ultraviolet radiation. Finally,we observed the changing phenomena of the planar display of OCB cell with additional external voltage under polarized microscopy . It can be observe obviously the polymer wall in OCB cell when NO.4 LC solution having concentration of 3％ wt . At the same time,the polymer which didn't sheltered by mask will polymerize,then,lead LC into high inclined angle alignment. And it formed discontinuous structure along mask affected LC which surrounded the wall. The results measured by photoelectric instruments showed the discontinuous structure not only keeps the inner LC structure at twist mode,but also promotes the originated respond-velocity of OCB.

然后利用聚丙烯酸与EOPO之团聚共聚合物，添加双官能基粉体及液晶E7，制备成液晶溶液再注入液晶盒里，放置光罩并给予固定外加5V电压在UV下进行曝光，然后在偏光显微镜下外加电压观察液晶盒的平面显示变化现象，发现四号高分子的液晶溶液在3%时，可以明显观察未被光罩遮蔽的高分子将会聚合形成高分子格子结构，并造成液晶成高倾角排列，顺著光罩形成不连续的结构藉以影响墙周围的液晶，从光电量测结果显示，利用此种不连续结构不仅可将内部液晶结构维持在twist的状态，也成功提升OCB原有的响应速度。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新