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The developed catalysts demonstrated good activities towards the Heck reaction of iodobenzene and methyl acrylate with about 90% yield, easy separation after reaction and reusability. The metal leaching was not apparent after four runs.

以碘代苯与丙烯酸甲酯的Heck反应为例,考察双腈基固载Pd的催化性能,肉桂酸甲酯的收率近90%,四次循环使用后催化活性没有明显的降低,Pd的析出并不严重,该催化剂易回收使用。

The first synthetic route uses 1,2,4-trimethoxybenzene and chloroacetonitrile in forming 2,4,5-trimethoxy-a-chlor-acetophenone under the anhydrous condition, then the intermediate condensates with papaverine forming the core pyrro[2,l-a]isoquinoline, followed by formation and lactonization to form the lactone ring. The second synthetic route uses prepared aldehyde with prepared ethyl nitroacetate by Knoevenagel condensation to obtain 2-Nitro-3-(2,4,5-tris-methoxy-phenyl)-acrylic acid ethyl ester and 2-Nitro-3-(2,4,5-tris-benzyloxy -phenyl)-acrylic acid ethyl ester etal intermediates. The lamellarin skeleton could arise from condensation of the papaverine and these intermediates by Michael reaction, the ester group is provided for subsequent lactonization. The third synthetic route uses coumarin or indan-l,3-dione derivatives and papaverine to form lamellarin under basic conditions.

第一条路线首先从1,2,4-三甲氧基苯出发与卤乙腈作用合成卤代芳酮中间体,然后与罂粟碱反应合成开链片螺素,最后经乙酰化、去保护、成内酯环得到片螺素;第二条路线由制备的芳醛和制备的硝基乙酸乙酯经缩合得到2-硝基-3-芳基丙烯酸乙酯,然后由该中间体与罂粟碱反应,在完成关环的同时也引入酯基,最后去保护、成内酯环得到片螺素;第三条路线是由香豆素或茚二酮出发,经溴代后的中间体与罂粟碱反应,得到片螺素的基本框架。

Most of the substances in the deposit were the nonsticky calcium carbonate and fines that could adhere to the sticky contaminants and deposit together, resulting in a great deal of the deposit.

对福建南平纸厂网前压力筛处的胶粘物进行分离和分析发现,以聚醋酸乙烯酯和聚丙烯酸酯为代表的人工合成聚合物以及机械浆中的木材树脂是产生胶粘物的根本来源,但它们在胶粘物沉积中的含量只有5%左右。

The semiconductor nanocrystalline surface is modified by using organic overlay method. As an organic overlay,-methacrylic restrains the reuniter between the grains in the latter process. Furthermore, it can combine with empty bond of atom at grain surface state and eliminate the surface state.

应用有机包覆的方法对纳米颗粒进行了表面修饰,作为包覆剂的α-甲基丙烯酸有效抑制了后处理工艺中纳米颗粒间的团聚现象,在纳米颗粒表面形成帽层,并与粒子表面态的原子悬键进行配位,这对消除表面态是非常有益的。

Two multifunctional agent, glycidyl methacrylate and refined ricinoleic acid , were adopted to modify EPDM in situ during compounding and vulcanization process. The effects of the modifiers on vulcanization behavior, processiability, different properties of the vulcanizates were investigated.

为此,选择了含有极性基团的多官能团小分子改性剂甲基丙烯酸缩水甘油酯和精制蓖麻油酸,在橡胶混炼和硫化过程中对EPDM进行原位改性,研究了原位反应技术对过氧化物硫化EPDM橡胶的反应特性、加工性能、力学性能、热性能、耐老化性能、耐屈挠疲劳性能及与金属的粘合强度等性能的影响,并探讨了其改性的机理。

In this article, the factors that affect molecular weight and solubility of polyacrylamide are studied and suitable initiator system is selected. The optimum parameters of copolymerizing process are obtained as follows: the molar proportion of acrylamide and sodium acrylate is 7:3, the monomer concentration is 30%, pH value of solution is 12, the oxidizer (K2S2O8) concentration is 0.1%, the reducing agent (NH2CONH2) concentration is 1%, the chain-transfer agent concentration is 0.4%. The initial reaction temperature is 35℃.

讨论了影响聚丙烯酰胺分子量和溶解性能的因素,选取了合适的氧化-还原引发体系,确定了制备超高分子量速溶型部分水解聚丙烯酰胺的优化聚合工艺参数:起始共聚合反应温度为35℃,保持在密闭条件下的共聚合反应2.5h后,再将聚合反应温度升高到55℃,继续反应2h,反应结束;反应溶液单体总浓度:30%,共聚合反应溶液pH值:12,氧化剂K_2S_2O_8:0.1%,还原剂NH_2CONH_2:1%,共聚合反应中两种单体的投料比:丙烯酰胺:丙烯酸钠=7:3,异丙醇链转移剂:0.4%。

The results show that if we choose right surgical method (completely obturated technology), good lens (dealing with hydrophobicity acrylate and heparin) and special shape design, we can reduce or avoid the occurrence of capsular opacification to the greatest extent.

选择适宜的手术方法、优良的人工晶状体材质(疏水性丙烯酸酯和肝素处理)、特殊的形态设计就能最大程度的减少或避免后囊膜混浊的发生。

Two-component waterborne polyurethane paint composed of acrylic dispersion and hydrophilically-modified polyisocyanate has fast dry time, good adhesion, flexibility, impact resistance, but poor water and chemical-resistance. The dry time becomes shorter with the increase of glass transition temperature and the decrease of acid value; the gloss of the film decreases with the increases of hydroxyl value, acid value and Tg of emulsion polymer; higher Tg polymer leads to harder film.

将制得的丙烯酸分散体与亲水改性多异氰酸酯组分配制水性双组分聚氨酯涂料,发现漆膜表干和实干比较快,干燥时间随玻璃化温度升高而缩短,随酸值的增加而增加;附着力、柔韧性和冲击强度比较好;光泽随分散体羟值、酸值的增加和玻璃化温度升高而降低;硬度随玻璃化温度升高而升高;较高的酸值使涂料的耐化学品性和耐水性较差,羟值在100mgKOH/g时较好,而酸值应尽可能低。

Results indicated that fluorinated chain block is incorporated into the macro molecule chain of the polymer successfully. The composite emulsion has a stable core-shell structure. The interface composed of fluorinated acrylate chain blocks are formed on the film surface and the incorporation of FA blocks increase the contact angle between PUA film and water from 65° to 98°.

结果表明,含氟链段成功接入了大分子链中,乳液形成稳定的核-壳结构,在膜材料表面形成了主要由含氟丙烯酸酯链段组成的界面, FA 的引入可使复合乳液胶膜与水的接触角( PUA 膜与水的接触角)由65°提高至98°。

Objective:To investigate the dynamic changes of immune function indexes of erythrocyte in the dialysis process of patients subject to blood dialysis, and to study the contribution of dialysers with different biocompatibilities to the changes.

目的:了解血液透析病人透析过程中红细胞免疫功能指标的动态改变及不同生物相容性的透析膜对其变化的影响。方法:分别采用铜仿膜、聚砜膜、聚甲基丙烯酸甲酯膜,观察了透析过程中不同时相的红细胞免疫功能指标RBC-C3b和RBC-IC的变化。

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