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Polyethylene glycol dimethacrylate, one of the fine chemical intermediates is the main ingredient of anaerobe. With the development of adhesives, the domestic production of polyethylene dimethacrylate has been challenged from many aspects, therefore, to improve the production technics and yields has been the key problem to resolve at present.

缩乙二醇双甲基丙烯酸酯——精细化学品中间体之一,作为胶粘剂中厌氧胶的主剂,在胶粘剂日益发展的今天,国内的缩乙二醇双甲基丙烯酸酯生产受到了很多方面的挑战,因此,改进生产工艺,提高产率是目前缩乙二醇双甲基丙烯酸酯生产首要解决的问题。

An acrylic cathodic electrodeposition paint based on the solution polymerization of glycidyl methacry-late and normal acrylic monomers has been developed, which has overcome the shortcomings of epoxy - polyurethane CED paint and featured by its good colorability, decoration and weatherability.

介绍了采用甲基丙烯酸缩水甘油酯与常用的丙烯酸单体通过溶液聚合,制备丙烯酸阴极电泳漆的简单可行方法。研制的电泳漆克服了环氧-聚氨酯阴极电泳漆的缺点,具有可着色性、高装饰性、高耐候性等特点。

Polymer A is a acrylic copolymer containing 70% by weight of methacrylic acid and 30% by weight of methyl methacrylate prepared by a catalytic chain transfer method to give a polymer having a number averaged molecular weight of approximately 600 as measured by GPC.

聚合物A是丙烯酸共聚物其含有甲基丙烯酸重量70%,按重量的30%甲基丙烯酸甲酯的催化链转移的方法准备给予聚合物具有的平均人数约600分子量为由GPC测定。

Thus, in industry it is easy to determine the BA level in vaporized solvent through saponif ication and calculate the BA level in resins with the regression equation. Finally to obtain the residual monomer level simply through reduction formula.

这样,在工业生产中就可通过皂化法方便地测得蒸出少量溶剂中的丙烯酸丁酯的含量,再利用回归方程算得树脂中的丙烯酸丁酯含量,最后简单换算出丙烯酸-氨基漆中残余单体的含量。

Hrough copolymerization of styrene with few quantity of methacrylic acid, maleic anhydrate or 4-vinyl pyridine respectively and of butyl methacrylate with maleic anhydrate, the functional groups carboxyl, simple anhydride and pyridyl have been introduced respectively to the chain of PS or PBma.

通过苯乙烯与少量的甲基丙烯酸、马来酸酐或4—乙烯基吡啶的共聚及甲基丙烯酸正丁酯与马来酸酐的共聚,可在聚苯乙烯及聚甲基丙烯酸丁酯链上分别引入功能基因羧基、酸酐基和吡啶基对共聚物进行了红外光谱、酸碱滴定、元素分析、玻璃化转变温度、粘度及紫外光谱的测定。

By the testing means of electron-spectroscopy for chemical analysis , thermogravimetric analysis , differential scanning calorimetry , transmission electronmicroscopy , the results have shown that the emulsion polymerization in situ in the presence of nano-particle of calcium carbonate can happen smoothly and successfully and the surface of nano-particle of calcium carbonate have been capsulated by polymer of acrylates, which prevent from the agglomerating of nano-particles of calcium carbonate. Because the copolymer of acrylate has good compatibility with some plastics such as PVC, ABS, AS and so on, so the dispersion of nano-scale calcium carbonate as nanometer size in these plastics can be reached more easily and the effects of nanometer can happen.

通过X射线光电子能谱、热失重分析、动态扫描量热分析、透射电子显微镜等手段,证实在纳米碳酸钙原生粒子存在下,可以进行丙烯酸酯类的原位乳液聚合,乳液聚合顺利,纳米碳酸钙表面被丙烯酸酯类聚合物所包覆,使纳米碳酸钙粒子间的团聚不易发生,同时由于丙烯酸酯类聚合物与PVC、ABS、AS等极性聚合物具有较好的相容性,从而使纳米碳酸钙在聚合物基体中能达到纳米状态分散,从而发挥纳米效应。

APUHD was prepared with PEPUD acted as emulsor and reactive seeded emulsion in polymerization of acrylate monomer.

利用可聚合自乳化聚氨酯水分散体作为乳化剂和反应性的种子乳液与丙烯酸酯等单体共聚,其优点在于能调节聚氨酯水分散体侧链上参与共聚的双键数目,使聚氨酯和丙烯酸酯两相聚合物体系间直接化学键合增强,相容性提高,增加体系内部交联密度,合成得到具有核壳间互穿网络结构的丙烯酸聚氨酯杂合水分散体。

In this thesis,three copolymerization systems have been investigated in detail.They are α-ethylacrylic acid/maleimide,α- acrylic acid/maleimide and monomethyl itaconate/maleimide,respectively.

本文对α-乙基丙烯酸/马来酰亚胺、α-正丙基丙烯酸/马来酰亚胺和衣康酸单甲酯/马来酰亚胺三种新的共聚体系进行了详细地研究,并对合成共聚物的生理活性进行了初步探讨,实现了α-正丙基丙烯酸乙酯/马来酰亚胺体系的可控共聚反应。

A novel method combining a conventional free-radical solution polymerization with a chemical saponification was used to synthesize a, cu-dicarboxyl terminated oligo s with molecular weight below 1500. Here, cn-carboxyl terminated oligo s were firstly synthesized by the free-radical polymerization in THF, where 4,4'-azobis(4-cyanovaleric acid) was used as initiator, thioglycolic acid as chain transfer agent, then CTBMA were transformed into di-CTBMA via saponifying CTBMA in dioxane/H_2O/KOH solution.

利用传统自由基聚合法,在四氢呋喃溶液中自由基引发聚合甲基丙烯酸丁酯单体而得到w-羧基-甲基丙烯酸丁酯低聚物(分子量在1500左右);利用CTBMA 末端酯基的反应特性,在二氧六环/水/KOH混合溶液中皂化CTBMA,使之转化为a ,w-羧基甲基丙烯酸丁酯低聚物;研究了溶剂的类别、反应时间等反应条件对皂化产物结构的影响;利用MALDI-TOF-MS及LSIMS对皂化各阶段产物进行了分析监测。

The time from saturated soil moisture content to wilting percentage of Aeolian sandy soil, Loessial soil and Lou soil was extended by 244.72%,251.11% and 36.31% respectively when Sodium Polyacrylate was applied at the suggested dosage.

风砂土、黄绵土与塿土的蒸发强度随着高分子化合物聚丙烯酸钠用量增加而降低,聚丙烯酸钠用量为0.5%时,砂土、黄绵土与塿土10天累积蒸发量分别较对照降低了59.89%、48.92%与55.81%;综合考虑对土壤蓄水与蒸发能力的影响,聚丙烯酸钠用量为风砂土、黄绵土应控制在0.08%~0.2%,塿土中用量必须严格控制在0.2%左右;在上述用量条件下,风砂土、黄绵土、塿土从饱和含水量蒸发失水至凋萎含水量的时间分别被延长了244.72%、251.11%与36.31%左右。

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