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Acrylate monomer ratio was computed by Fox equation which was used to design the glass temperature of acrylate resin.

通过Fox方程设计丙烯酸树脂的玻璃化温度以确定各类丙烯酸单体的配比,对所得到的丙烯酸树脂性能进行了讨论分析。

In the determination of methyl acrylate,butyl acrylate and methyl methacrylate in ambient air,the sample was absorbed with active carbon and resolved with carbon bisulfide,and then determined by GC.

测定环境空气中的丙烯酸甲酯、丙烯酸丁酯和甲基丙烯酸甲酯时,气样采用活性炭吸附,用二硫化碳解析,直接进气相色谱仪检测,根据保留时间定性,外标法定量,能获得良好的线性和较低的方法检出限,不仅精密度、灵敏度和重复性良好,而且可操作性强,易于在环境监测系统中推广。

In the determination of methyl acrylate,butyl acrylate and methyl methacrylate in ambient air,the sample was absorbed with active carbon and resolved with carbon bisulfide,and then determined by GC.After the qulitation by retention time and quantitation by external standard method,the good linearity and low detection limit were got.

测定环境空气中的丙烯酸甲酯、丙烯酸丁酯和甲基丙烯酸甲酯时,气样采用活性炭吸附,用二硫化碳解析,直接进气相色谱仪检测,根据保留时间定性,外标法定量,能获得良好的线性和较低的方法检出限,不仅精密度、灵敏度和重复性良好,而且可操作性强,易于在环境监测系统中推广。

The Automotive Finishes was composed of Cardura E 10-based acrylic resin with high-solids and excellent weather resistance as main resin, and Cardura E10-based polyester resin with high-solids as additional resin to be used to improve decorative properties, such as chubbiness, gloss, PGD,and so on, of the only acrylic amido automotive finishes.

该面漆以叔碳酸缩水甘油酯(商品名E10)改性高固体份丙烯酸树脂作为主体树脂,该树脂是具有高耐候性的丙烯酸树脂,以叔碳酸缩水甘油酯改性高固体份聚酯树脂作为添加树脂,弥补单纯丙烯酸氨基漆在丰满度、光泽、鲜映性等外观装饰性等方面的不足,从而形成高耐候性、高装饰性的高品质、高固体份汽车面漆。

In this paper, three kinds of hydroxyl component are prepared for two-component waterborne polyurethane paint, that is, acrylic dispersion, acrylic emulsion and silicone-modified acrylic emulsion. The influence of the composites of these dispersion and emulsions on polymerization process, viscosity, particle size and coagulum are investigated, infrared spectroscopy , inductance coupling plasma , transmission electron microscopy and thermogravimetric analysis are used to characterized their structure, composite, morphology and thermal stability, respectively.

本论文制备了三种用于水性双组分聚氨酯涂料的含羟基组分,即丙烯酸分散体、丙烯酸乳液和有机硅改性丙烯酸乳液,研究了这些分散体和乳液在制备过程中聚合物的羟值、酸值、玻璃化温度、乳化剂、反应温度等对聚合转化率、凝聚物含量、聚合物粘度和粒径的影响,用红外光谱、热重分析、透射电镜和感应偶合等离子技术表征了其结构、组成、形态和热稳定性。

At first, the polymerization characteristic of BMA was discussed in the paper, by contrast with MMA, using the instrument dilatometer. It was confirmed that the polymerizing activity of BMA was lower than MMA, and its polymerizing condition was stricter.

本文首先对甲基丙烯酸丁酯和甲基丙烯酸甲酯的聚合特性进行了对比研究,用膨胀计法测定了两者在不同引发条件下的聚合动力学,证实了甲基丙烯酸丁酯的聚合活性比甲酯要低,聚合条件更为严格。

High oil absorption resins of higher n-alkyl acrylates modified cotton linter were synthesizedby supension graft copolymerization. The effects of the ratio of n-alkyl acrylates to linter, the kinds and amounts of crosslinker, the amounts of initiator, as well as reaction temperature and time on oil absorbency were investigated.

以棉短绒为基材,丙烯酸长链酯为单体,双丙烯酸二元醇酯为交联剂,采用悬浮接枝共聚法合成了高吸油性材料,考察了棉纤维与单体的投料比、交联剂种类与用量、引发剂用量、聚合反应温度与时间等因素对该材料吸油性能的影响,得到了不同丙烯酸长链酯与棉纤维接枝聚合制备吸油材料的最佳工艺条件。

Molecularly imprinted polymers of sulfamethazine(SM 2 ) were prepared with silica gel as a sacrificial material, methacrylic acid and 4 vinylpyridine(4 Vp) as functional monomers, glycol dimethacrylate as crosslinker. The polymer properties were investigated by static adsorption experiments. Scatchard analysis shows that the adsorption ability of MAA MIP is superior to that of 4 Vp MIP. The dissociation constant of MAA MIP is 9 59×10 -4 mol/L. The value of apparent binding a...

以磺胺二甲嘧啶为模板分子,分别用甲基丙烯酸和4乙烯基吡啶为功能单体,二甲基丙烯酸乙二醇酯为交联剂,采用牺牲硅胶法合成了磺胺分子印迹聚合物,通过静态吸附实验,系统研究了不同单体对聚合物识别性能的影响;Scatchard分析表明,以甲基丙烯酸为单体的聚合物具有较高的吸附能力,其离解常数Kd为959×10-4mol/L,最大表观结合位点数Qmax为3070μmol/g。

Thirdly, the acrylic rosin was synthesized by the addition reaction from gum rosin andacrylic acid. The levo-pimaric acid was converted into acrylic pimarie acid throughDiels-Alder addition with acrylic acid. The abietic-type acids in the gum rosin were inisomerization balance under high temperature, and the abietic acid and palstric acid would beconverted into levo-pimaric acid and reacted in the later type.

第三,通过脂松香与丙烯酸加成合成了丙烯酸松香,该反应是左旋海松酸与丙烯酸发生Diels-Alder加成反应生成丙烯海松酸,由于脂松香中的枞酸型树脂酸在高温下处于异构化平衡状态,因此随着反应的进行枞酸、长叶松酸等会异构化为左旋海松酸参与反应。

The experimental results show that the composite emulsion of nitrocellulose -alkyd resin acrylate, which is prepared by modifying the nitrocellulose with non -drying or alkyd resin, methyl methacrylate and butyl acrylate monomer under the optimized experimental conditions have good stability and excellent performance.

实验结果表明,以不干性油醇酸树脂、甲基丙烯酸甲酯和丙烯酸丁酯单体为主要原料,在优化的实验条件下对硝基纤维素进行改性,可制得稳定性好的硝化纤维素-醇酸树脂-丙烯酸酯复合乳液。

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