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And VTMS is added in late stage of polymerization, in this situation the system has the lowest coagulum. When the hydroxyl value of such polymer increases, the coagulum decreases; and solid content of such polymer increases, the coagulum increases greatly, so it is difficult to get higher solid content emulsion.

采用正交实验方法,通过对有机硅改性丙烯酸乳液聚合过程中凝聚物含量、乳液粘度影响的研究,确定的最佳的反应条件是:以SLS/OP为乳化剂、比例为4/6、用量为2%、丙烯酸单体的用量1.5%、反应温度为75℃、改性剂VTMS用量是1.5%、改性剂后加入方式下聚合反应过程中有最低的凝聚物含量。

It is extremely difficult to solve the problem of tunnel leak, because there are many muddiness, greasy dirts and slushes on the top of the tunnel, thereby it is hard to conglutinate the waterproof materials. Test results show that the impervious pressure and the splice strength of the acrylic acid waterproof material will be up to 1.2 MPa and 1.8 MPa in 30 min with new formula and unique construction craft 50 that reduce the difficulty of conglutination.

实验结果表明:使用新型丙烯酸防水材料配方和施工工艺,使丙烯酸防水材料的抗渗压和粘结强度在30 min里能够迅速分别达到1.2 MPa和1.8 MPa,从而降低粘结难度,很好地解决了既有隧道的顶部因有很多的淤泥、油污、水垢等杂物而使普通防水材料难以粘结的问题。

A very mild and extremely efficient hydrolysis method for transformation of polystyrene-b-poly (tert-butyl acrylate) to polystyrene-b-poly was designed and carried out using more convenient and inexpensive chlorotrimethylsilane/sodium iodide as reagents.

在温和的条件下使用廉价方便的三甲基硅氯烷/碘化钠作试剂,在乙腈溶剂中,50℃下使聚苯乙烯-嵌-聚丙烯酸特丁酯高效的水解。用透射电镜和动态光散射对嵌段共聚物聚苯乙烯-b-聚丙烯酸在水介质中的胶束化进行了研究。

The Surface composition of grafted PET fiber was characterized by ATR-FTIR. THE results showed that there were no obvious differences between ungrafted and graft PET fiber in the spectra ,except that the typical peak of-OH in 3100cm~(-1) appeared in both Citric acid treated PET fiber and Acrylic acid treated PET fiber indicated citric acid and acrylic acid had been successfully grafted on the surface of PET fiber.

对样品的接枝效果进行红外光谱表征,发现无论是经过丙烯酸接枝处理,还是柠檬酸接枝处理,处理前后纤维的红外吸收光谱图都没有明显的区别,说明接枝前后纤维的主体性质没变,但是,二者在3100cm~(-1)处都出现了羟基的特征吸收峰,说明柠檬酸和丙烯酸都已经接枝上了PET纤维表面。

The influences of inter-crosslinker and ratio of polyurethane-polyether to acrylic resin on the hydrophilic coating were investigated.The experimental data show that when the initiator is ammonium ceric nitrate and the inter-crosslinker is divinylbenzene in the preparation of polyurethane-polyether,the amount of ...

实验结果表明,在聚氨酯-聚醚树脂的制备中,用硝酸铈铵作引发剂,用二乙烯苯作内交联剂,在丙烯酸树脂的制备中,引发剂量为单体总质量的1.00%,聚氨酯-聚醚树脂与丙烯酸树脂的质量比为15∶1,制备的树脂转化率高,涂料亲水性能优异。

The cure reactions of ternarysystem containing poly, poly and HDI isocyanurate, and the effect of the ratio ofPGA/POH on the thermal, mechanical and surface properties of curedresin have also been examined.

本文还研究了聚丙烯酸环氧丙酯、聚丙烯酸羟丙酯和六亚甲基二异氰酸酯三聚体的反应及三元反应体系中PGA/POH的不同比例对交联后树脂的热性能、力学性能及表面性能的影响。

A second group includes those compositions, which include an organic polymeric binding material, eg, mixed cellulose esters of monobasic or dibasic acids such as cellulose acetate succinate; an addition-polymerizable ethylenically unsaturated compound, eg, vinylidene and vinyl monomers, preferably of the acrylic or alkacrylic ester type; eg, triethylene glycol diacrylate; and an addition-polymerization initiator which forms radicals under the influence of actinic radiation, eg, anthraquinone.

第二组包括那些作品,其中包括有机聚合物具有约束力的物质,例如,对一元或二元酸混合纤维素酯,如醋酸纤维素琥珀酸; 1此外,聚合ethylenically不饱和化合物,例如,偏和乙烯基单体,丙烯酸最好的或alkacrylic酯类型,如,三乙二醇二丙烯酸酯;和加成聚合引发剂的形式下光化辐射的影响自由基,例如,蒽醌。

The photosensitiviy of Novel synthiesized polyether acrylate ANE and Si-containing ANS were studied in this paper.The photosensitiviy and physicomechanical properties of their cured products,inchuding transparency,water absorption,hardness and Tg were investigated in terms of the quantity of reactive diluent hydroxyethylacrylate.

本文主要研究了合成的新型聚醚丙烯酸酯ANE和有机硅丙烯酸酯ANS的感光性、活性烯释剂HEA用量对ANS、ANE的感光性能及ANS、ANE光固化材料物理机械性能的影响。

Monomer which is used to synthesize polypropylene ester, mechanism of polymerization, a formula and technique parameters of synthesizing propenoic acid ester polymer are studied. An emulsifying stabilizer with good properties is synthesized.

本文研究了合成聚丙烯酸酯类物质的单体、聚合反应的机理、合成丙烯酸酯类聚合物的配方以及工艺参数,合成了具有良好性能的乳化稳定剂。

Secondly,UV spectrophotometry was adopted to research the combination action on SM_2 and SIZ with MAA and 4-Vp.The combination action of functional monomer with template molecules were produced in the results. Then,the prediction imprinting principle of SM_2 and SIZ were given. The diagrams of infrared spectrum were analysed in MAA and 4-Vp and IMPs of SM_2. It was discoved that the absorbability peak of C=C function group in the IMPs were turn to be very low ,but the function group of carboxylic acid and pyridyl in the IMPs were no evidence change, and the condition was created in the molecular recognition of MIPs. Thermal Analysis was adopted to research IMPs ,in which ,a better thermal stability and its decompose temperature were showed in the results.

其次,本文利用紫外分光光度法研究磺胺二甲嘧啶和磺胺异噁唑与甲基丙烯酸或4-乙烯基吡啶的结合作用,结果表明,溶液中的功能单体与模板分子之间产生了结合作用,并预测磺胺二甲嘧啶和磺胺异噁唑印迹机理;分别分析了功能单体甲基丙烯酸、4-乙烯基吡啶、磺胺二甲嘧啶和磺胺异噁唑分子印迹聚合物的红外谱图,经过对比发现制得的印迹聚合物中C=C双键峰很小,并且功能键羧酸键和吡啶氮没有明显变化,这为聚合物特异识别特性创造了条件;利用综合热分析仪,对分子印迹聚合物进行综合热分析,结果表明分子印迹聚合物具有较好的热稳定性,分解温度也较高。

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