丙烯酸树脂

Acrylate monomer ratio was computed by Fox equation which was used to design the glass temperature of acrylate resin.

通过Fox方程设计丙烯酸树脂的玻璃化温度以确定各类丙烯酸单体的配比，对所得到的丙烯酸树脂性能进行了讨论分析。

The Automotive Finishes was composed of Cardura E 10-based acrylic resin with high-solids and excellent weather resistance as main resin, and Cardura E10-based polyester resin with high-solids as additional resin to be used to improve decorative properties, such as chubbiness, gloss, PGD,and so on, of the only acrylic amido automotive finishes.

该面漆以叔碳酸缩水甘油酯(商品名E10)改性高固体份丙烯酸树脂作为主体树脂，该树脂是具有高耐候性的丙烯酸树脂，以叔碳酸缩水甘油酯改性高固体份聚酯树脂作为添加树脂，弥补单纯丙烯酸氨基漆在丰满度、光泽、鲜映性等外观装饰性等方面的不足，从而形成高耐候性、高装饰性的高品质、高固体份汽车面漆。

Poly-acrylic acid resin was synthesized by emulsion polymerization with meth-acrylic acid and methyl meth-acrylate as monomers. Which used as enteric film-coating material: aqueous poly-acrylic acid resin Ⅲ. and then desiccate them to resin powder by sprayer.

以甲基丙烯酸与甲基丙烯酸甲酯为共聚单体，用乳液聚合法制备肠溶型水性聚丙烯酸树脂Ⅲ乳液，喷雾干燥成树脂粉末。

The main contribution of this paper is summarized as follow:1 Copolymer acrylate resin including hydroxyl, carboxylic and amina(-NH_2) is a new type of antifogging system and ahydrophi- lic antifogging constituents which is not found before.2 Water-soluble acrylate resin hydrophilic antifogging coating material is a new-type environmental protection material which takes ethanol as solvent and whose pastiness is adjusted by deionized water.3 The quality rate of accessory soft monomer ethyl acrylate and accessory hard monomer butyl methacrylate is 6 to 4, the quality rate of functional monomers in all monomers is 20 percent, the quality rate of MAA in the functional monomers is 22 percent, the quality rate of β-hydroxyl ethyl acrylate in the functional monomers is 8 to 10 percent and the remainder of functional monomer is acrylic acid.4 Cross-linking agent methylol acrylamide belongs to self-cross-linking system.

本文的主要贡献概述如下： 1 含有亲水羧基、羟基和氨基(-NH_2)丙烯酸共聚树脂是一种新型高效的防雾体系，用的亲水防雾组分是前所未有的。 2 以乙醇为溶剂制得水溶性丙烯酸树脂具有很好的水溶性能和防雾性能，只需加入去离子水就可以调节它的粘度，是一种新型的环保型防雾材料。 3 辅助软单体丙烯酸乙酯和辅助硬单体甲基丙烯酸甲酯最佳配比为质量比6∶4；官能单体占单体总量的20%，甲基丙烯酸占官能单体总量10～15%，甲基丙烯酸β-羟乙酯占官能单体总量的8～10%，剩下的为丙烯酸。

The influences of inter-crosslinker and ratio of polyurethane-polyether to acrylic resin on the hydrophilic coating were investigated.The experimental data show that when the initiator is ammonium ceric nitrate and the inter-crosslinker is divinylbenzene in the preparation of polyurethane-polyether,the amount of ...

实验结果表明，在聚氨酯-聚醚树脂的制备中，用硝酸铈铵作引发剂，用二乙烯苯作内交联剂，在丙烯酸树脂的制备中，引发剂量为单体总质量的1.00%，聚氨酯-聚醚树脂与丙烯酸树脂的质量比为15∶1，制备的树脂转化率高，涂料亲水性能优异。

A photosensitive resin for UV curing acrylic powder coating has been synthesized by esterification of methacrylic acid and GMA-type acrylic resin at the presence of ethyl acetate as solvent, tetramethylammonium chloride as catalyst, YK as inhibitor.

以醋酸丁酯为溶剂，四甲基氯化铵为催化剂，氮氧自由基为阻聚剂，由甲基丙烯酸缩水甘油酯类丙烯酸树脂与甲基丙烯酸酯化反应制得了UV固化粉末涂料用感光性丙烯酸树脂。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

It is considered in this paper that the light and heat oxygen resistance ageings of silicone acrylate resin are better than those of normal acrylic and polyurethane resins, through the theoretic investigations into the reaction mechanisms of the light and heat oxygen ageings of high molecular polymer and contrasting, when exposed to light and under a high temperature, the changes in colour,shape, tensile strength and elongation of Silicone Acrylate Resin DX 8501 to the normal acrylic and polyur...

本文通过对高分子聚合物的光氧老化、热氧老化的反应机理的理论探讨和对DX8501硅丙树脂、普通丙烯酸树脂、普通聚氨酯胶膜在紫外光照射下和高温条件下的颜色、形态、抗张强度、伸长率的变化情况对比，认为硅丙树脂的耐光氧老化和耐热氧老化的性能优于普通的丙烯酸树脂和普通的聚氨酯。表3，参考文献8

UV curing powder coatings ; acrylic resin ; methacrylic acid ; glycidyl methacrylate ; photosensitive resin

UV固化粉末涂料；丙烯酸树脂；甲基丙烯酸；甲基丙烯酸缩水甘油酯；感光树脂

Effects of hard/soft monomer ratio,the content of acrylic acid,the content of aromatic monomer BNMA,the ratio of amino resin curing agent to acrylic resin,the conditions of curing on properties of the films were investigated.

合成了水性丙烯酸树脂并用其配制了汽车罩光清漆，研究了硬/软单体配比、丙烯酸单体的用量、芳香酯单体的用量、氨基树脂固化剂/丙烯酸树脂的配比及固化条件对漆膜性能的影响。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。