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And the epoxy acrylic cationic resin applicable to cathodic electrodeposition coating was synthesized by using aminating agent of diethanolamine and neutralizing agent of acetic acid.

并以二乙醇胺为胺化剂、冰醋酸为中和剂合成了可用于阴极电沉积涂料的环氧丙烯酸阳离子树脂。

The paint includes liquid A, which consists of acrylic resin, mixed solvent of xylene, acetone and isophorone, organic silicone solution, superfine silica powder, titanium dioxide powder, methyl-(N-beta-amino ethyl gamma-amino propyl)-dimethoxy siloxane solution, gamma-methyl acrylyloxy propyl tromethoxy siloxane solution and fluorocarbon modified siloxane; and liquid B, which consists of hexamethylene diisocyanate, polydiisocyanate, xylene, and methoxy propyl acetate. When the paint is used, two components are mixed together.

丙烯酸树脂、二甲苯和丙酮及异佛尔酮混合溶剂、有机硅酮溶液、超细二氧化硅粉、钛白粉、甲基(N-β-氨乙基γ-氨丙基)二甲氧基硅烷溶液、γ-甲基丙烯酰氧基丙基三甲氧基硅烷溶液、氟碳改性硅氧烷溶液组成A液,由六亚甲基二异氰酸酯聚异氰酸酯、二甲苯和甲氧基乙酸丙酯混合溶液组成B液,使用时将两组分混合。

Dimethylamino)ethyl methacrylate was polymerized using PS-CH_2Cl as macroinitiator and CuCl/ 2,2 '-Bipyridyl as catalyst in toluene to acquire amphiphilic brush-type copolymers of PS-g-PDMAEMA.

再以氯甲基化的聚苯乙烯(PS-CH_2Cl)为大分子引发剂,在CuCl和2,2′-联吡啶(2,2′-Bipyridyl,bpy)存在下,以甲苯为溶剂,进行甲基丙烯酸N,N-二甲胺基乙酯2-(Dimethylaminoethyl methacrylate,DMAEMA的ATRP聚合,得到两亲性的梳状共聚物PS-g-PDMAEMA。

Radiation-induced grafting of binary vinyl monomers of styrene/ maleic anhydride, St/ dimethylamino ethyl methacrylate and St/ vinyl acetate onto cotton cellulose was carried out byγ- radiation from a60 Co source at room temperature under nitrogen.

在氮气气氛下用γ线辐照的方法在棉纤维上接枝苯乙烯/来酸酐、乙烯/基丙烯酸二甲胺乙酯、乙烯/酸乙烯酯二元单体。

Radiation-induced grafting of binary vinyl monomers of styrene/maleic anhydride, St/dimethylamino ethyl methacrylate and St/vinyl acetate onto cotton cellulose was carried out by γ-radiation from a 60Co source at room temperature under nitrogen.

在氮气气氛下用γ射线辐照的方法在棉纤维上接枝苯乙烯/马来酸酐、苯乙烯/甲基丙烯酸二甲胺乙酯、苯乙烯/醋酸乙烯酯二元单体。

Radiation-induced grafting of binary vinyl monomers of styrene/maleic anhydride, St/dimethylamino ethyl methacrylate and St/vinyl acetate onto cotton cellulose was carried out by γ-radiation from a 60Co source at room temperature under nitrogen.

闫宇,伊敏,彭金粉,翟茂林*,哈鸿飞摘要:在氮气气氛下用γ射线辐照的方法在棉纤维上接枝苯乙烯/马来酸酐、苯乙烯/甲基丙烯酸二甲胺乙酯、苯乙烯/醋酸乙烯酯二元单体。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的,将反相微乳液法运用到其制备及改性的有关环节,通过反相微乳液聚合工艺,将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1,8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1,8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚,制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM,并研究其应用性能。

A series of acrylic resins were synthesized by using ditertiary butyl peroxide as a free radical initiator and 2-mercaptoethanol as a chain transfer agent.

以过氧化二叔丁基为自由基引发剂、巯基乙醇为链转移剂,合成了高固体分、低粘度的羟基丙烯酸树脂,其粘度在1000mPa·s以下,固体分高达65%~70%。

Results showed that the monomer conversion increased slightly in the presence of the crosslinking agents The size of particles decreased slowh as the amount of cmsslinking agent increased.and the size distribution of the particles broadened at a higher amount of cmsslinking agent Divinyl benzene was more effective than ethyl glycol dimethyl methacrylate to make polymer crosslinked.During alkali treatment process,void latex particles can be obtained when no DVB or less than 0.5 wt% of EGDMA was used,while muhihollow structure was generated when DVB or more than 1.0 wt% of EGDMA was introduced.The volume expansion of the particles decreased with increasing the amount of emsslinkirlg agents.

结果表明,体系中加入交联剂后,单体转化率都有不同程度的提高;随交联剂用量的增加,乳胶粒粒径略有减小,交联剂用量较高时,乳胶粒粒径分布加宽;二乙烯基苯的交联效率稍高于双甲基丙烯酸乙二醇酯;不加入交联剂及EGDMA用量低于0.5%时,处理后乳胶粒呈空腔结构,加入DVB及EGDMA用量高于1.0%时,处理后乳胶粒呈多孔结构,并且乳胶粒体积增量随交联剂用量的增加而减小。

Self-assembly of PEO-b-PB (M〓of PEO=5100 g/mol and M〓 of PB=5100 g/mol) and poly (PAA, M〓=2000 g/mol) was obtained in THF/dodecane mixtures via PEO/PAA complex. The effect of ratio of PEO-b-PB: PAA was investigated.

通过PEO-b-PB(PEO和PB分子量均为5100g/mol)中PEO链段和聚丙烯酸(PAA,分子量为2000g/mol)的氢键相互作用,我们在THF/正十二烷混合溶剂中获得了PEO-b-PB/PAA的自组装体,并研究了PAA用量对自组装行为的影响。

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