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In this paper, grafting of crotonic acid, undecylenic acid, oleic acid, and acrylic acid onto acrylonitrile-butadiene-styrene terpolymer were studied. Experimental factors influencing grafting, kinetics and mechanism of grafting, the reactivity of grafted polymer, and the compatibilization effects of grafted ABS on ABS blends were investigated.

本文主要研究反式丁烯酸、10-十一烯酸、油酸、丙烯酸接枝ABS树脂的影响因素、接枝反应机理和动力学、接枝物的反应活性,以及接枝物对ABS共混物的增容作用。

Ninth Five-Year Plan period, the Company conducted a medical intermediates of the pre-development and market research, the introduction of the development of superior strength skin, crotonic acid, crotonic anhydride and other products; also produced 3,3 dimethyl methacrylate, antibiotics raw material products, as well as more than 20 kinds of iso-vanillin and other pharmaceutical intermediates.

九五期间,本公司进行了医化中间体的前期开发和市场调查,引进开发了优力肤、巴豆酸、巴豆酸酐等系列产品;还生产了3,3二甲基丙烯酸甲酯、抗生素原料药系列产品以及异香兰素等二十多种医药中间体。

Grafting degree increased with increasing monomer concentration in acrylic acid and crotonic acid systems. In undecylenic acid and oleic acid systems, grafting degree increased with monomer concentration initially but decreased after monomer concentration reaching at 0.30 mol/L.

丙烯酸、反式丁烯酸体系的接枝率随单体浓度的增加而增大。10-十一烯酸、油酸体系的接枝率初始时随单体浓度的增加而增大,单体浓度超过0.30mol/L后,接枝率降低。

Grafting of crotonic acid, undecylenic acid, oleic acid, and acrylic acid onto ABS was initiated by benzoyl peroxide in 1, 2-dichloroethane solution.

以过氧化二苯甲酰为引发剂,在1,2-二氯乙烷溶液中进行反式丁烯酸、10-十一烯酸、油酸、丙烯酸接枝ABS树脂。

There were crystallizable water and non-crystallizable water in polyacrylate hydrogel; the content of the non-crystallizable water was 2.13 g/g dry resin, much higher than that in non-ionic hydrogels.

丙烯酸钠水凝胶中的水有相变水和非冻结水两种存在形式,其中非冻结水含量为2.13g水/g绝干树脂,该数值大大高于非离子型水凝胶。

Three potential initiation processes were identified during the cumyl phenyl dithioacetate mediated acrylate polymerizations.

三个可能的启动过程期间,没有发现基苯基dithioacetate介丙烯酸聚合。

In spite of this, the preparation of thiol-end functionalized PMMA was achieved by introducing a short block of polystyrene after the RAFT polymerization of MMA.Third, RAFT technique was applied to design and synthesize some well-defined poymers. Five monomers, lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate, poly methyl ether methacrylate, 4-(4\'-cyanobiphenyl-4-yloxy) butyl methacrylate and 2-ethyl methacrylate were chosen to RAFT homopolymerization or copolymerizations mediated by cumyl dithiobenzoate.

RAFT方法在具有特定结构聚合物的设计与合成上的应用,在机理研究的基础上,本论文选择五种不同结构的甲基丙烯酸酯类单体:lauryl methacrylate,(N,N-dimethylamino)ethyl methacrylate,polymethyl ether methacrylate,4-(4'-cyanobiphenyl-4-yloxy)butyl methacrylate和2-ethyl methacrylate,用CDB调控RAFT聚合的方法设计合成了一些特定结构的聚合物,详细而深入地研究了它们的均聚、共聚动力学,发现了双硫酯并非在聚合反应初期就全部转化,而是随着反应进行逐步消耗,这与理想的活性聚合体系有很大差别。

Polyaspartate can also be obtained through chemical synthesis, but is currently produced only in small quantities. It is more biodegradable than comparable polyacrylates, but not totally biodegradable like the polyaspartate produced in cyanophycin.

聚天冬氨酸也可以通过化学方法合成,但是,目前只能少量生产,其生物降解性比聚丙烯酸酯更好,但不能够像蓝细菌中产生的聚天冬氨酸那样完全被生物降解。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3,2-b]异喹啉-11-酮8和11H-苯并噻唑[3,2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈,丙烯酸甲酯,富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

In present study, a liquid-liquid extraction method was employed to extract the volatile components in mulberry fruit sparkling wine. The analysis with gas chromatography-mass spectrometry detected 69 peaks, among which 63 volatile components were identified. The first 9 volatile components with high relative content were benzyl alcohol, 2-methyl-1-butanol, mono-(2-ethylhexyl)-1, 2-benzene dicarboxylic acid, 3-methyl-1-butanol, toluene, acrylic acid butyl ester, 1H-indole-3-ethanol, isodecyl octyl phthalate and decyl octyl phthalate.

采用液-液萃取法提取桑椹汽酒中的挥发性成分,经气相色谱-质谱联机分析,共检测出69个峰,鉴定出63种挥发性化合物,其相对含量排在前9位的挥发性化合物分别是苯乙醇、2-甲基-1-丁醇、1,2-苯二酸单(2-乙基)己酯、3-甲基-1-丁醇、甲苯、丙烯酸丁酯、1H-吲哚-3-乙醇、邻苯二甲酸异癸基辛基二酯、邻苯二甲酸癸基辛基二酯。

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