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The influence of microwave radiation on Ullmann reaction has been investigated by three Ullmann reactions, including triphenylamine formed by treating the diphenylamine with bromobenzene or Chlorobenzene which substitutes Iodobenzene; 4,4\'-dimethyltriphenylamine formed by treating 4,4\'-dimethyldiphenylamine with bromobenzene which substitutes Iodobenzene; 4,4\',4-trinitrotriphenylamine formed by treating 4-chloronitrobenzene with p-nitroaniline in this paper.

实验表明,在微波辐射条件下,顺式比反式迈克尔反应活性高;若在丁烯二酸的双键上引入甲基后,降低了进行迈克尔加成反应的活性;引入酯基对双键的影响比腈基有利于进行迈克尔反应,丙烯酸甲酯较丙烯腈的迈克尔反应活性高。

Their chemical structures were characterizd on the basis of spectral and chemical evidences to be: Sarracenin (1), 2-methyl-5-hydroxy-7-O-ethyl caffeate chromome (2), Naringenin(3), 2-methyl-5, 7-dihydroxychromome (4), 2-methyl-6-hydroxyl-cinnamic acid methyl ester (5), eriodictyol (6), quercetin (7), Naringenin-7-O-β-D-glucoside( 8 ), eriodictyol-7-O-α-D-glucoside (9), quercetin-3-O-β-D-glucoside(10). In addition, one compound was abtained from the n-butanol frationk, which was finally identified as Morrosiside(11) by spectral and chemical evidences.

以波谱数据及其理化性质鉴定为:Sarracenin(1),2-甲基-5-羟基-7-O-咖啡酸乙酯色原酮(2),柚皮素(3),2-甲基-5,7-二羟基色原酮(4),2-甲基-6-羟基苯丙烯酸甲酯(5),圣草酚(6),槲皮素(7),柚皮素-7-O-β-D-葡萄糖苷(Naringenin-7-O-β-D-glucoside)(8),圣草酚-7-O-α-D-葡萄糖苷(eriodictyol-7-O-α-D-glucoside)(9),槲皮素-3-O-β-D-葡萄糖苷(quercetin--3-O-β-D-glucoside)(10);另外从正丁醇萃取部位分离得到1个化合物,以波谱数据和文献对照鉴定为:Morroniside(11)。

Ingredients: Water,Hamamelis Virginiana Water,Glycerin,Propylene Glycol,Glyceryl Polymethacrylate,Betaine,Aloe Barbadensis Leaf Juice,Hydro-lyzed Wheat Protein,Sodium Pca,Tocopheryl Acetate,Polysorbate 20,Creatine,Hyaluronic Acid,Tetrasodium Edta,Perfume,Phenoxyethanol,Caprylyl Glycol,Sorbic.

成分:去离子水,金缕梅蒸馏液,甘油,丙二醇,甘油聚甲基丙烯酸酯,甜菜碱,芦荟叶提取物,水解小麦蛋白,吡咯烷酮羧酸钠,生育酚乙酸酯,聚山梨醇酯-20,肌酸,透明质酸,乙二胺四乙酸四钠,香精,苯氧乙醇,辛二醇,山梨酸。

In this paper,we have reported the regularities of graft copolymerization of butyl acrylate onto potato starch using ceric ammonium nitrate as an initiator.

本文以硝酸铈铵为引发剂,研究了丙烯酸丁酯与土豆淀粉接枝共聚的反应规律。

Graft copolymerizaton of bleached eucalyptus pulp with glycidyl methacrylateusing a ceric salt initiator system was studied in detail.

研究了铈盐引发体系引发漂白化学桉木浆与甲基丙烯酸缩水甘油酯的接枝共聚。

With cerous ammonium nitric-ethylene diamine tetraacetic acid as an initiator, and with the protection of the nitrogen the graft-copolymerization of methylacrylic acid and vinyl acetate on chitosan grafting was studied.

以硝酸铈铵-乙二胺四乙酸为引发剂,在N2气的保护下,研究了壳聚糖与甲基丙烯酸和醋酸乙烯酯两种单体的接技共聚反应。

The CMC grafted polyacrylamide co polyacrylic acid at the same time was produced. The redox system of patassium sulfate and sodium bisulfite was used as the initiator instead of the cerous ammonium nitrate because of its cheapness.

以羧甲基纤维素为基质,以过硫酸钾-亚硫酸氢钠氧化还原引发体系代替相对昂贵的硝酸铈铵引发剂,成功的制备了羧甲基纤维素同时接枝聚丙烯酰胺-聚丙烯酸共聚物。

The degradable starch treated by α-amylase was grafted onto methyl acrylate to produce graft copolymer initiated by ammonium cerous nitrate, the degradable film was produced by molten mixing the above copolymer and linear low density polyethylene, the properties of the degradable film were characterized by means of mechanical property testing, SEM, TG analysis and degradation experiment.

将α-淀粉酶降解淀粉在引发剂硝酸铈铵的作用下与丙烯酸甲酯接枝生成共聚物,用该共聚物与线型低密度聚乙烯熔融混炼制成可降解薄膜,通过力学性能测试、扫描电镜、热失重分析和降解性能实验等对其进行表征。

In this paper,sand culture experiment was carried out to study the effect of cinnamic acid,p-hydroxybenzoic acid stress on photosynthesis of cucumber seedlings.

采用砂培试验研究了有机肥对外源自毒物质苯丙烯酸、对羟基苯甲酸胁迫下黄瓜光合作用的影响。

Series of FAnC(n=1~4) were synthesized by acylation reaction of FAn (scheme 1) with cinnamyl choride.

通过肉桂酰氯与ε-己内酯改性丙烯酸酯间的酰基化反应,合成了一系列光敏性大单体。

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