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The effects of reaction time, temperature, alkalic degree and the feed ratio on the hydrolysis reaction were investigated by means of the orthogonal design method. And the optimum operating conditions were got. Polyacrylate sodium was prepared under the optimum conditions.

利用正交设计,讨论了反应时间、温度、碱浓度、投料比等因素对水解反应的影响,获得了优化的水解反应条件,并在最优化的条件下制得聚丙烯酸钠。

Third, Polymerization behaviors of alkenyl substituted Cp Lanthanide complexes as Methyl Methacrylate polymerization catalysts were also studied.

最后,本文还分别考察了烯丁基和烯丙基取代茂的稀土络合物对甲基丙烯酸甲酯的催化聚合反应。

In addition to the multi-ring alkenyl ethers and alpha-fluorinated acrylates, additional monomers comprising one or more cyclic aliphatic and heterocyclic compounds, both unsubstituted and substituted, in particular dihydropyrans, may be incorporated into the photosensitive polymers.

除了多环烯基醚和α-氟化丙烯酸酯之外,可向所述光敏聚合物引入另外的单体,所述单体包括一种或多种未取代的和取代的环状脂肪族化合物和杂环化合物,特别是二氢吡喃。

Provided are a variety of monomers suitable of producing photosensitive polymers, that are in turn, useful in photoresist compositions, through radical polymerization including at least one multi-ring alkenyl ethers and one alpha-fluorinated acrylate.

本发明提供多种单体,所述单体适用于通过包括至少一种多环烯基醚和一种α-氟化丙烯酸酯的自由基聚合制造光敏聚合物,所述光敏聚合物又可用于光致抗蚀剂组合物中。

Specifically, it is applicable to the production of dissolvent type of coating materials such as formaldehyde phenol resin, alkide resin, epoxy resin, epoxy polyester and acrylic resin as well as water-soluble resin coating materials such as highly adaptable water-soluble epoxy ester dipping paint.

适用于酚醛树脂、醇酸树脂、环氧树脂、环氧聚酯以及丙烯酸树脂等溶剂型涂料以及各种水溶性树脂涂料(如:高适应性水性环氧酯浸涂漆等);还可应用于厚浆型涂料、粉末涂料、有机钛防腐蚀涂料、带锈涂料和沥清漆、富锌底漆、防火涂料、耐热涂料等。

This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.

中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis,characterization of novel Cp,oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容:1)有机金属钛络合物的合成;2)烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究;3)烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。

In regard to C〓-functionalized hydrophilicpolymer , we synthesized the adducts of C〓 with polyallyl-amine and poly( allylamine- co -hydroxypropyl methacrylate ).

作为〓修饰的水溶性高分子体系,我们合成了烯丙基胺均聚物和烯丙基胺-甲基丙烯酸羟丙酯共聚物,并使之与〓进行反应。

Using N, N-dimethyl-ethylenediamine as cationic substitute and 2-hydroxyethyl methacrylate or allylamine as co-substitute, a kind of pH-sensitive polyorganophosphazenes bearing unsaturated side group was prepared.

以N,N-二甲基乙二胺为阳离子型取代基,甲基丙烯酸羟乙酯或烯丙胺为共取代基,制备了同时带有pH响应性侧基和不饱和双键侧基的聚膦腈。

During the low temperature plasma polymerization, different factors (reaction power, pulse duty factor, reaction time, bias voltage and pressure) were investigated to get the best film. The results of X-ray photoelectron spectroscopy and Fourier transformed infrared spectoscopy implied that polymer nano-film containing carboxyl or amido were deposited successfully by using allylamine or acrylic acid as a reagent, respectively.

低温等离子聚合过程中,研究了反应的功率、脉冲占空比、反应时间、偏压、反应室压强这五个因素对薄膜性质的影响,确定了最佳的工艺参数。X光电子能谱和傅立叶转换红外光谱分析结果表明,以丙烯胺和丙烯酸为反应物可以在样品表面分别得到含有羧基或氨基的有机薄膜。

Microwave; polymerization; Methacrylic acid; 2- ethyl ester; Allylthiourea; Polymer-Metal Complexes; catalyze; adsorption.

微波; 聚合;甲基丙烯酸N; N-二甲胺乙酯;烯丙基硫脲;高分子金属配合物;催化;吸附

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