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Tetradecyl acrylate was synthesized by direct-etherification from tetradecyl alcohol and acrylic acid with p-methyl benzene sulfuric acid as catalyst.

摘 要:以丙烯酸和十四醇为原料,经酯化反应直接合成丙烯酸十四酯。

The conversion of product reaches 98% under the optimal experiment condition: the molar rate of acrylic acid and tetradecyl alcohol is 1.1; the amount of p-methyl benzene sulfuric acid is 0.8%; the amount of p-benzened...

得出合成丙烯酸十四酯的最佳合成条件:丙烯酸与十四醇摩尔比为1 1,对甲苯磺酸用量为0 8%,对苯二酚用量为0 6%,反应温度为120℃,反应时间为4h。

The resin which was synthesized by the materials of hydroxy silicone oil , 1, 6-hexamethylene diisocyanate, tolylene diisocyanate, pentaerythritol triarylate and 2-hydroxy ethyl acrylate is able to cure rapidly at room temperature by UV.

本实验采用溶液聚合的方法,以端羟基硅油、甲苯二异氰酸酯、六亚甲基二异氰酸酯、丙烯酸—2—羟基乙酯和季戊四醇三丙烯酸酯为原料制备出了新型能够进行快速固化、高效的三官能度封端的光固化反应体系。

The bromo-polyethylenegylcol-monomethacrylate was synthesized by two steps. Firstly, methylacrylic acid was esterified with polyethylene glycol (PEG, M=200, 400) to give polyethyleneglycol-monomethacrylate Secondly, treatment of PEG-MA with phosphorus tribromide gave the aim product.

以聚乙二醉(M分别为200,400)和甲基丙烯酸进行单酯化反应,所得单酯再与三溴化磷进行溴化反应合成了一种新的两端具有功能团的不饱和溴化物,即溴代甲基丙烯酸单聚乙二醇酯。

The effects of MMA and alumina trihydrate on properties of oligourethane methacrylate resins were investigated. And the curing reactivities of unsaturated polyester resin, vinyl ester and UM resin were compared by various methods.

研究了甲基丙烯酸甲酯和三水合氧化铝含量对聚氨酯甲基丙烯酸酯树脂性能的影响,比较了不饱和聚酯树脂、乙烯基树脂和UM树脂的固化反应活性。

Poly silica hybrids were prepared through polymerization, condensation and sol gel processes of the mixture of methyl methacrylate, poly and a small amount of coupling agent methacryloxylpropyl trimethoxy siliane in tetrahydrofuran.

采用溶胶-凝胶技术,以硅酸钠为原料制备聚硅酸/四氢呋喃溶胶,再与甲基丙烯酸甲酯及少许偶联剂甲基丙烯酰氧丙基三甲氧基硅烷(MPTMS 混合,经聚合、缩合和溶胶-凝胶过程制备了有机/无机两相间有— C—Si—O—键的杂化材料——聚甲基丙烯酸甲酯/二氧化硅(PMMA/Si O2 )。

Copolymer was synthesized by acrylic acid and 1H, 1H, 11H-perfluoro undecyl acrylate, then introducing europium ion into the copolymer.

利用丙烯酸全氟酯和丙烯酸共聚合成含氟的共聚物,再引入三价铕离子,从而制得稀土高分子发光材料。

The polymerized film has better antiwear lifethan the unpolymerized film because polymerization enhances the strenthof the thin film.

并用超分子自组装法将其与甲基丙烯酸十二醇酯和双甲基丙烯酸己二醇酯在玻璃基片上共组装成二氧化钛/有机物复合薄膜。

The relationship of the amounts of emulsifier, organosilicon monomer (D4) and initiator with the ratio of fluorescence intensity between first vibronic peak of pyrene (λ= 373 nm) and third vibronic peak of pyrene (λ=384nm)Ⅰ1/Ⅰ3 were discussed during the emulsion polymerization process, in which pyrene was used as fluorescence probe. The polymerization behavior of the organosilicon-acrylate latex with core-shell structure was investigated in line with the relationship of monomer conversion and development of morphology in latex particles with the value of Ⅰ1/Ⅰ3 for probe pyrene during the polymerization process.

以芘为荧光探针,探讨了有机硅-丙烯酸酯核壳乳液聚合过程中,芘的第一振动峰(373nm处)与第三振动峰(384nm处)荧光强度的比值Ⅰ1/Ⅰ3与乳化剂、有机硅单体(D4)和引发剂用量之间的关系,并结合聚合过程中探针芘的Ⅰ1/Ⅰ3 峰值与单体转化率及乳胶粒形态演变之间的关系,研究了核壳结构有机硅-丙烯酸酯乳液的聚合行为。

MATERIALS: Ethylene glycol methacrylate compound with methyl methacrylate was mixed with NaCl solution to obtain porous hydrogel orbital implant; polyurethane membrane was established using electrospinning method. A volume fraction of 75% ethanol was used to make homologous sclera wrappage.

材料:用甲基丙烯酸-β-羟乙酯和甲基丙烯酸甲酯的聚合物单体加入NaCl成孔剂制备多孔水凝胶义眼台;静电纺丝法制备聚氨酯包裹膜;体积分数为75%乙醇浸泡制备同种异体巩膜包裹物。

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