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The polymethyl methacrylate material with super-hydrophobic surface of the invention is prepared in the following steps: 1 the polymethyl methacrylate material is first put into diamine solution, so that the ester group on the surface of the material has ammonolysis reaction with diamine molecules; 2 and then, the product of the step 1 is put into long chain fatty acid solution to be treated and the solvent is volatilized, so as to obtain the polymethyl methacrylate material with super-hydrophobic surface.

本发明具有超疏水表面的聚甲基丙烯酸甲酯材料,是按照如下步骤进行制备的:1将聚丙烯酸甲酯材料先置于二胺溶液中使聚丙烯酸甲酯材料表面的酯基与二胺分子发生氨解反应;2然后,将其置于长链脂肪酸溶液中进行处理,挥发掉溶剂,得到具有超疏水表面的聚甲基丙烯酸甲酯材料。

The influences of N,N'-methene biacrylamide cross-linker,monomer concentration,polymerization time and temperature on swelling ratio were investigated,and reversibility of the hydrogels under various pH conditions at given temperature.

目的通过合成聚丙烯酸-co-α-甲基丙烯酸水凝胶,研究N,N'-亚甲基双丙烯酰胺交联剂、丙烯酸和α-甲基丙烯酸单体浓度、聚合时间对其水凝胶溶胀率的影响,以及温度和不同pH值时水凝胶的pH可逆性。

With the acid and alkali titrate method,we got the mean molecular weight and discussed the monomer density,the initiator amount used, chain transfer agent factor as well as reaction temperature to molecular weight influence tendency and d.

丙烯酸钠在很多领域的广泛应用,我们采用水溶液聚合法中的中和法合成低分子量聚丙烯酸钠,用酸碱滴定的方法测得聚丙烯酸的平均分子量,并探讨了单体浓度、引发剂用量、链转移剂用量以及反应温度等因素对聚丙烯酸钠分子量的影响趋势和程度。

Results indicate that as the molecular mass of polyethylene glycol increases, the conductance is increased obviously, and the surface tension is decreased from 36.28 mN/m to 31.30 mN/m, while the cloud point is increased from 39.6 ℃ to 58.9 ℃. Their emulsifying abilities to BA, MMA and BMA are superior to that of OP-10, and the surfactants is homopolymerize or copolymerize with acrylate at 70 ℃ under the initiation of AIBN.

结果表明,随聚乙烯醇分子量的增加,非离子表面活性剂的电导率显著增加、表面张力由36.28 mN/m降低至31.30 mN/m、浊点由39.6 ℃增加至58.9 ℃,对丙烯酸丁酯、甲基丙烯酸甲酯和甲基丙烯酸丁酯的乳化能力均优于常用乳化剂OP-10,以AIBN作引发剂在70 ℃下既能均聚又可与丙烯酸酯进行共聚反应。

From the influnce of pH change in water on the copolymerization, the copolymerization mechanism was provided. The copolymerization mechanism is that there is hydrogen bond, which can enhance the copolymerization, between acrylic acid and crotonaldehyde at low pH and there is"Charge Transfer Complex", which gives the more crotonaldehyde in P (acrylic acid-crotonaldehyde), between acrylic acid and crotonaldehyde at high pH.

根据共聚合反应介质pH值变化对丙烯酸-丁烯醛共聚合反应的影响,提出了丙烯酸-丁烯醛共聚合反应机理,即在低pH值时,丙烯酸、丁烯醛之间可形成氢键,从而使共聚合体系具有较高的聚合反应速率和转化率;在较高pH值时,丙烯酸、丁烯醛之间则有电荷转移络合物形成,从而使共聚物中含有更多的丁烯醛链段。

The title nano-sized polymeric microgels were synthesized by emulsion polymerization method,using divinyl benzene as crosslinking agent and methyl methacrylate,hydroxyl ethyl methacrylate,butyl acrylate as monomers.

通过乳液聚合的方法,以二乙烯基苯为交联剂,用甲基丙烯酸甲酯、甲基丙烯酸-β-羟乙酯、丙烯酸丁酯等丙烯酸酯类单体合成纳米尺寸的聚合物微凝胶粒子。

The water absorbed in the vulcanizates presents thermodynamic properties somewhat different from those of water in the bulk liquid, and exists in three states in the vulcanizates: free water, freezable bound water and non-freezable water.

硫化时,在过氧化物自由基的引发作用下,橡胶产生了共价交联、丙烯酸盐单体也发生了均聚,同时被部分接枝到橡胶分子链上,最终在硫化胶中生成交联橡胶、丙烯酸盐均聚物、丙烯酸盐和橡胶的接枝聚合物以及未聚合的丙烯酸盐单体。

Two kinds of cross-linked polyacrylate latices with relatively narrow distribution of particle diameters, which are abbreviated to P and P/P, were synthesized by seeded emulsion co-polymerization, respectively. Butyl acrylate and 2-ethylhexy! acrylate were used as comonomers of ACR core, styrene and methyl methacrylate were employed as comonomers of ACR shell, and 1,4-butanediol diacrylate was used as cross-linking agent.

采用丙烯酸丁酯和丙烯酸2-乙基己酯(2-EHA)为核层单体、苯乙烯和甲基丙烯酸甲酯为壳层单体、1,4-丁二醇二丙烯酸酯为交联剂,通过多步种子乳液聚合方法合成了P、P/P两种具有窄粒径分布的共聚丙烯酸酯胶乳。

Thermoset acrylic coating are based on resins prepared from acrylic and methacrylic esters, acrylic and methacrylic acids, and /or styrene.

热固型丙烯酸涂料是由丙烯酸和甲乙基丙烯酸酯,丙烯酸和甲基丙烯酸,或苯乙烯反应而成。

Adding a small quantity of three functional group of polyvalent can improve the water resistance and decoration of copolymer emulsion after film forming. The structure form of interpenetrating networks has a greater destroy degree to the micro crystal of polyurethane film forming substance than the effect of the prepolymer capping graft copolymer.IV, This article studies on the heat stability of acrylate modified polyurethane dispersion, researches the changes of the structure of acrylate modified polyurethane dispersion afterheating, and analyses by the heat analysis, infrared ray and heat analysis, and mass spectrometery.

利用拉曼光谱和扫描电镜、红外光谱等测试技术,分析了丙烯酸酷及丙烯酸酷一有机硅等改性聚氨酷水分散体的成膜过程—利用预聚体封端技术合成的丙烯酸酷改性聚醚聚氨酷的成膜过程包括乳液颗粒的挤压成膜与分子硬段的微区结晶,有机硅氧烷的引入将同时出现硅氧烷的水解缩合;具有互穿网络结构的丙烯酸酷改性聚氨酷水分散体因丙烯酸酷的互穿而限制了聚氨酷硬段在成膜过程中的结晶,聚合物成膜以挤压成膜为主,有机硅的复合改性同样出现硅氧烷水解缩合现象。8。

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It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发,分析对称连杆曲线上鲍尔点的产生条件,提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品,年生产总值3000万美元,产品价廉物美、选料上乘、质量保证,深受国内外客户的青睐

The eˉtiology of hemospermia is complicate,but almost of hemospermia are benign.

血精的原因很,以良性病变为主。