丙烯酸

At the PAA polybutycyanocrylate metog acylate nanopolyaniline, or polybutycyanocrylate acid, butylacralate or methylacryte, methylacryte and microdosis butylacralate in LaTeX fleece printing of ofmaize.

凡是以合丙烯酸丁酯为主的乳液，或丙烯酸酯与丙烯酸丁酯共合体，或甲基丙烯酸甲酯、丙烯酸甲酯和丙烯酰胺共合体乳液为起绒印花用的粘合剂。

In view of rising feedstock and energy costs, BASF will further increase prices for its acrylic acid and acrylic esters (glacial acrylic acid; methyl acrylate, ethyl acrylate, n-butyl acrylate, 2-ethyl hexyl acrylate), as contracts permit.

在原料和能源成本，巴斯夫公司将进一步提高其丙烯酸和丙烯酸酯（冰丙烯酸，丙烯酸甲酯，丙烯酸乙酯，丁酯丙烯酸2乙基己基丙烯酸酯），价格为合同许可。

Water, Cyclomethicone, Glycerin, Sd Alcohol 40-B (Alcohol Denat.), Propylene Glycol, Melia Azadirachta Leaf Extract, Lecithin, Arctium Lappa Root Extract, Xylitol, Lactitol, Alpha-Glucan Oligosaccharide, Lactoferrin, Potassium Thiocyanate, Glucose Pentaacetate, Glucose Oxidase, Lactoperoxidase, Glycoproteins, Panax Ginseng Root Extract, Equisetum Arvense Extract, Hydrolyzed Milk Protein, Peg-8, Caprylyl Glycol, Sebacic Acid, Sodium Polyacrylate, Betula Alba Bark Extract, Cupressus Sempervirens Leaf Extract, Hamamelis Virginiana Extract, Avena Sativa Meal Extract, Humulus Lupulus Extract, Silk, Nylon-12, Polyacrylamide, Polymethyl Methacrylate, Butylene Glycol, Salicylic Acid, Lauryl Methacrylate/Glycol Dimethacrylate Copolymer, Tocopheryl Acetate, C13-14 Isoparaffin, Laureth-7, Triethanolamine, Xanthan Gum, Acrylates/C10-30 Alkyl Acrylate Crosspolymer, Phenoxyethanol, Chlorphenesin, Benzoic Acid, Methylparaben, Fragrance, Titanium Dioxide

水，环甲硅脂，甘油，Sd Alcohol 40-B，丙二醇，印度楝树叶萃取，卵燐脂，牛蒡根萃取，木糖醇，乳糖醇，α-葡低聚糖，乳铁蛋白，硫氰酸钾，葡萄糖五乙酸酯，葡萄糖氧化酶，乳过氧化物酶，糖蛋白，人参根萃取，问荆萃取，水解牛奶蛋白，聚乙二醇-8，辛乙二醇，癸二酸，聚丙烯酸酯钠，白桦萃取，丝柏叶萃取，金缕梅萃取，燕麦萃取，啤酒花萃取，丝，尼龙－12，聚丙烯醯胺，聚甲基丙烯酸甲酯，丁二醇，水杨酸，甲基丙烯酸十二酯，醋酸盐维他命E，C13-14 异烷烃，月桂醇聚醚-7，三乙醇胺，山羊胶，丙烯酸/C10-30烷基丙烯酸聚合物，苯氧乙醇，氯苯甘醚，苯甲酸，羟苯甲酯，香料，二氧化钛

LIN Hailin,CUI Yingde,DU Lin,CHEN JianpingInstitute of Applied Chemistry,Zhongkai University of Agriculture and TechnologySuper water absorbent resins P,SA/NaAA,SA/NaAA/PVA and SA/NaAA/AM were synthesized from sodium alginate,acrylic acid,polyvinyl alcoholand acrylamide,with N,N–methylenebisacrylamide as crosslinking agent,(NH4)2S2O8 - NaHSO3 as initiator,by means of aqueous solution polymerization.

以醚化海藻酸钠、聚乙烯醇、丙烯酰胺、丙烯酸为单体，N， N–亚甲基双丙烯酰胺为交联剂，过硫酸铵-亚硫酸氢钠为引发剂，采用水溶液法制备聚丙烯酸钠p吸水树脂和海藻酸钠/丙烯酸钠、海藻酸钠/丙烯酸钠/聚乙烯醇（SA/NaAA/PVA）及海藻酸钠/丙烯酸钠/丙烯酰胺吸水性复合树脂。

However, common polyacrylate emulsion has some disadvantages such as poor water-resistance, poor film-forming in low temperature, becoming pastiness in high temperature, polluting environment with emulsifier and so on.

由于聚丙烯酸酯乳液具有耐热、耐光和耐老化等优点在涂料工业中得到了广泛的应用，但普通的聚丙烯酸酯乳液还存在耐水性差、低温下不易成膜、高温发粘以及含乳化剂的废液会对环境造成污染等缺点，因此，本文结合无皂乳液聚合和核壳乳液聚合技术，合成了聚丙烯酸丁酯/丙烯酸钠齐聚物，并以此为乳化剂，采用种子半连续法合成了以聚丙烯酸丁酯为核，聚甲基丙烯酸甲酯-苯乙烯为壳的无皂核壳聚丙烯酸酯乳液。

The main contribution of this paper is summarized as follow:1 Copolymer acrylate resin including hydroxyl, carboxylic and amina(-NH_2) is a new type of antifogging system and ahydrophi- lic antifogging constituents which is not found before.2 Water-soluble acrylate resin hydrophilic antifogging coating material is a new-type environmental protection material which takes ethanol as solvent and whose pastiness is adjusted by deionized water.3 The quality rate of accessory soft monomer ethyl acrylate and accessory hard monomer butyl methacrylate is 6 to 4, the quality rate of functional monomers in all monomers is 20 percent, the quality rate of MAA in the functional monomers is 22 percent, the quality rate of β-hydroxyl ethyl acrylate in the functional monomers is 8 to 10 percent and the remainder of functional monomer is acrylic acid.4 Cross-linking agent methylol acrylamide belongs to self-cross-linking system.

本文的主要贡献概述如下： 1 含有亲水羧基、羟基和氨基(-NH_2)丙烯酸共聚树脂是一种新型高效的防雾体系，用的亲水防雾组分是前所未有的。 2 以乙醇为溶剂制得水溶性丙烯酸树脂具有很好的水溶性能和防雾性能，只需加入去离子水就可以调节它的粘度，是一种新型的环保型防雾材料。 3 辅助软单体丙烯酸乙酯和辅助硬单体甲基丙烯酸甲酯最佳配比为质量比6∶4；官能单体占单体总量的20%，甲基丙烯酸占官能单体总量10～15%，甲基丙烯酸β-羟乙酯占官能单体总量的8～10%，剩下的为丙烯酸。

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Fine chemicals to add auxiliary Series: lubricating oil pour point depressant, calcium zinc magnesium methacrylate, methyl acrylic acid lauryl ester, tetradecane methacrylate ester, methacrylic acid octadecyl ester, a acid ethylene glycol, diethylene glycol methacrylic acid ester, glycidyl methacrylate, the second reduction of three ethylene glycol dimethyl acrylate, acrylic acid lauryl ester, tetradecyl acrylate, octadecyl acrylate, acrylic acid ethylene glycol, diethylene glycol acrylate esters, glycidyl, two shrink three acrylate such as ethylene glycol.

精细化工添加助剂系列：润滑油降凝剂，甲基丙烯酸钙锌镁，甲基丙烯酸月桂酯，甲基丙烯酸十四烷酯，甲基丙烯酸十八烷基酯，甲基丙烯酸乙二醇，甲基丙烯酸二乙二醇酯，甲基丙烯酸缩水甘油酯，二缩三乙二醇二甲基丙烯酸酯，丙烯酸月桂酯，丙烯酸十四酯，丙烯酸十八酯，丙烯酸乙二醇，丙烯酸二乙二醇酯，丙烯酸缩水甘油酯，二缩三乙二醇丙烯酸酯等。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

Polyurethane-acrylics hybrid latexes were prepared using isophorone diisocyanate, dimethylol propanoic acid and polypropylene oxides of different molecular weights as main materials for PU component, and butyl acrylate, methyl methacrylate and a crosslinker, trihydroxymethyl propanetriacrylate as main acrylic monomers. Hydroxyethyl acrylate was used as the coupling agent between PU and AC.

以异佛尔酮二异氰酸酯、二羟甲基丙酸和聚丙醚二醇等为聚氨酯原料，丙烯酸丁酯、甲基丙烯酸甲酯、三羟甲基丙烷三丙烯酸酯为丙烯酸酯类单体，丙烯酸羟乙酯为聚氨酯和聚丙烯酸酯间的偶联剂合成了丙烯酸酯改性水性聚氨酯乳液。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。