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丙烯酰基

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Optimization of polyester condensation process and reactor design;2. The Structure Characters of the Sulfonated Condensation Polymer Series High Performance;3. The pH value of the solution was adjusted,and the co- condensation reaction was taken place between the hydroxy groups forming transparent organic-inorganic hybrid films on polycarbonate.

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质,引入正硅酸乙酯水解产物硅溶胶作为无机增强物,调节两种混合溶液pH值,利用两者羟基之间的共缩聚反应在聚碳酸酯板表面制备有机/无机复合透明耐磨薄膜;采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。

Dimethyldiallylammonium chloride and copolymer comprising DMDAAC and acrylamide have been synthesized from dimethylamine ,allylchloride and AM.

以二甲胺、氯丙烯等为原料合成二甲基二烯丙基氯化铵,再与丙烯酰胺共聚生成共聚物。

In this paper the surface charge density of cationic kraft pulp was chosen as response variable and the preparation conditions of cationic kraft pulp by the in-situ grafting copolymeration of acrylamide and cationic monomer, [2- ethyl] trimethyl-ammonium chloride were optimized by central composite design.

摘 要:以阳离子硫酸盐浆的表面电荷密度为评价指标,采用中心复合设计法对丙烯酰胺和甲基丙烯酰氧基乙基三甲基氯化铵接枝共聚制备阳离子硫酸盐浆的工艺进行了优化。

Pyrene has been used as a fluorescence probe to investigate the associative behaviors of hydrophobically modified water-soluble terpolymers Poly(acrylamide/sodium acrylate/octylacrylamide) \[P(AM/NaAA/C_8AM)\].

采用胶束共聚共水解方法合成疏水改性水溶性聚合物聚(丙烯酰胺/丙烯酸钠/N 辛基丙烯酰胺)[P(AM/NaAA/C8AM)],并以芘为荧光探针,应用稳态荧光光谱法研究了它的疏水缔合行为。

The polymerization reacts from the inverse emulsion . Selecting white oil as continuous medium , Span60 and TX-10 as the complex emulsifier , AM-01﹑(NH4)2S2O4 and NaHSO3 as new-type complex initiator , the copolymerization of dimethylamino ethyl acrylate methyl chloride/acrylamide was developed . The effects of the concentration of monomer﹑emulsifier and initiator﹑ temperature﹑reaction time and pH on the molecular weight﹑intrinsic viscostity﹑conversion ratio and cation degree of copolymer were studied .

以反相乳液为初始聚合体系,油酸失水山梨醇酯Span60和辛基酚聚氧乙烯醚TX-10构成复配乳化剂,白油为连续介质,AM-01、过硫酸铵和亚硫酸氢钠组成新型复合引发体系,进行丙烯酰胺/(2-甲基丙烯酰氧乙基)三甲基氯化铵的反相准微乳液共聚合,研究了单体浓度、乳化剂、反应温度、反应时间、pH等因素对聚合产品分子量、特性粘数、转化率及阳离子度的影响。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂,以烯酸吗啉为模板化合物,以异烟酸为起始原料,通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等,将吡啶-4-基或2-氯吡啶-4-基引入到模板结构中,设计合成了27个4-[3-(吡啶-4-基)-3-取代苯基丙烯酰]吗啉类化合物,其结构通过1H NMR和元素分析确证。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯-b-聚甲基丙烯酸十四酯-b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷,通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构,并研究了其对玻璃纤维/聚丙烯复合材料力学性能的影响。

Ambient temperature self-crosslinking acrylic latexes were prepared through semicontinuous emulsion polymerization using 3 different polymerizable alkoxysilanes, i.e. vinyl tri silane (A172), Vinyl triethoxy silane and γ-methacryloxypropyl trimethoxy silane (A174). The hydrolysis of these siloxanes under different pH was characterized, and dependence of the latex and polymer properties on these siloxanes and their incorporated amounts in the polymers was studied.

使用三种含不饱和双键硅氧烷,乙烯基三硅烷(A172)、乙烯基三乙氧基硅烷和γ-甲基丙烯酰氧丙基三甲氧基硅烷(A174)为功能单体,采用半连续乳液聚合法制备了室温自交联丙烯酸酯乳液,探讨了硅氧烷功能单体在不同pH条件下水解情况以及其种类和用量对乳液及乳胶膜性能的影响。

Using tetrabutyl titanate and methyl methacrylateor 2-Hydroxyethylmethacrylate (HEMA as materials, methacryloxylpropyl trimethoxy siliane as coupling agent, HCl as catalyst, Poly-titania(PMMA-TiO2) nanocomposites and Poly-titania(PMMA-TiO2) nanocomposites were synthesized by sol-gel process.

以盐酸作为催化剂,将钛酸四丁酯水解制备二氧化钛(TiO2)溶胶;随后将所制备溶胶与甲基丙烯酸甲酯、硅烷偶联剂(γ-甲基丙烯酰氧丙基三甲氧基硅烷)相混合,以过氧化苯甲酰作为引发剂,经过聚合、缩合和溶胶-凝胶过程,制备了均匀透明的PMMA-TiO2纳米复合材料和PHEMA-TiO2纳米复合材料。

The results suggested that the reaction temperature, the ratio of oil to water, the amount of ethyl cellulose as dispersant, initial monomers composition, the drop manner and the amount of initiator, the stirring speed, the pH of the buffer and the elution process have great influence on the morphology such as diameter of the hydrogel beads.

研究结果表明,采用反相悬浮聚合法,以丙烯酰胺和N-乙烯基吡咯烷酮为共聚单体,N,N'-亚甲基双丙烯酰胺为交联剂,牛血清白蛋白为模板,可以制备BSA印迹共聚物微球;反应温度、水油比、乙基纤维素分散剂用量、初始共聚单体配比、引发剂用量和加入方式、搅拌速度、水相pH值以及后续洗脱条件等均对粒径等微球结构和形态产生明显影响。

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