丙烯酰基

The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子，苄正离子亲电进攻3，4，5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

ZnO nanorings were prepared on a large scale by a facile solution-based method at 70 ℃ for 5 h via hexamethylenetetramine(C6H12N4) and Zn(NO3)2·2H2O as the raw materials in the presence of surfactant PAM-CTAC.

以六次甲基四胺(Hexamethylenetetramine， C6H12N4)和水合硝酸锌[Zn(NO3)2·2H2O]为原料，表面活性剂聚丙烯酰胺-氯化二烯丙基二甲基铵为形貌控制剂，采用液相沉淀法合成了ZnO纳米环。

It provides a route tothe compounds which contains three functional groups, two carbon-nitrogentriple bonds and one carbon-carbon double bond. In water, metallic indiumpromotes carbon-sulfur bond coupling reaction of aromatic sulfonyl chloride withsuitable organic halides to afford sulfones. In the last chapter, metallic tin mediated allylation of aldimines with allylbromide was revealed.

第三章，我们研究了在水相介质中金属铟促进的烯丙基溴对1，1-二氰基-2-芳基乙烯的Michael加成反应，生成一个含碳碳双键和二个碳氮叁键的三官能团化合物，另外，金属铟在水介质中还可以促进芳基磺酰氯与卤代烃发生碳硫键的偶联，生成砜。

Methods Naloxone was synthesized starting from oxidation of thebaine, followed by hydrogenation, acylation, cyanidation, O-demethylation, hydrolyzation and N-allylation. The alternative method of O-demethylation, methane sulfonic acid/DL-methionine and hydrobromic acid were investigated.

在以蒂巴因为原料，经氧化、氢化、酰化、氰化、去氧甲基、水解、N-烯丙基化得到纳洛酮的合成路线中，分别采用甲磺酸／DL-甲硫氨酸和氢溴酸代替三溴化硼进行去氧甲基化和后续水解反应。

Objective To research the effects of a chiral aminoalcohol in the asymmetric allylation of acylhydrazones.

目的 研究手性氨基醇在酰腙不对称烯丙基化反应中的促进作用。

Last, we studied the allylation of benzoylhydrazones with allyltrichlorosilane.

在研究过程中，发现了一个C=N双键烯丙基化的新方法，和苯甲酰肼的新的合成方法。

We also studied the enantioselective conjugate addition of chalcone in the presents of chiral Ni2 aminoalcohol complexes.

我们还研究了手性氨基醇配体/镍盐催化的a，β-不饱和酮的不对称迈克尔加成反应，以及酰腙的不对称烯丙基化反应。

Employing acetyl chloride as the electrophile afforded the β-acetoxyvinyl-γ-butyrolactone 3 as the product, which provided an experimental evidence to the mechanism involving the palladium enolate intermediate.

使用乙酰氮作为亲电试剂得到了β－乙酰氧基烯基－γ－丁丙酯3，这一结果为烯醇钯中间体的机理提供了一个实验证据。

The results of IR and DSC indicated that the curing reaction of BMI-modified phenolic resin mainly consists of two steps: the allyl groups in the Novolak resin react with maleimide group via"Ene"addition, and addition reactions of the C=C bonds formed thereby are followed.

IR与DSC方法研究表明：BMI改性酚醛树脂的固化反应主要是Novolak树脂上的烯丙基首先与酰亚胺基团的烯加成反应，然后烯加成反应所形成的C=C双键发生进一步加成。

For a big chunk of credit-card losses; the number of filings (and thus charge-off rates) would be rising again, whether

年美国个人破产法的一个改动使得破产登记急速下降，而后引起了信用卡大规模的亏损。

Eph. 4:23 And that you be renewed in the spirit of your mind

弗四23 而在你们心思的灵里得以更新