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丙烯酰

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The production methods of glutaraldehyde,including those of addition reaction of acraldehyde , oxidation of 1,5-pentadiol,reduction of glutaryl chloride and oxidation of cyclopentene,are summarized.

综述了丙烯醛加成、 1,5 -戊二醇氧化、戊二酰氯还原和环戊烯氧化等戊二醛的合成路线和制备方法,考察了目前戊二醛的生产厂家及其在皮革鞣剂、油田注水杀菌剂和医药杀菌等领域的应用市

The preparation of potassium malonyloxyborohydride in situ and its seletive hydroborating alkene are described.

介绍了丙二酰氧基硼氢化钾的制备及其原位与烯烃的选择性硼氢化。

For developing an immunoassay for multiple residues of pyrethroid pesticides, the hapten N-2- carbanmoyl-(3"-phenoxyphenyl) methyl 3-(2"-Cldoro-3",3",3"-trifluoropropenyl)-2, 2-dimethylcyclopropane- carboxylate was synthesized from cyanohydrin and 3-(2"-Chloro-3",3",3- trifluoropropenyl)-2, 2-dimethylcyclopropanecarboxylic acid via hydrolysis and esterification. The synthesis of the hapten was foundation of preparaing anti- cyhalothrin polyclonal antibodies.

为了制备对单一拟除虫菊酯高特异性的抗体,以菊酸和氰醇为起始原料,通过水解、酯化反应合成了半抗原N-2-氨甲酰-(3-苯氧基苄基)甲基-3-(2-氯-3,3,3-三氟丙烯基)-2,2-二甲基环丙烷羧酸酯,为进一步制备抗三氟氰菊酯的特异性抗体奠定基础。

It is shown from both the electronic and stereo structural analyses, that PDBP is a superior coordinate ligand as compared with TPP, which was employed in the rhodium/phosphonium catalyst for the hydroformylation reaction.

采用元素分析、红外、核磁等方法,对其结构进行了表征,并将PDBP用于丙烯氢甲酰化反应的催化剂配体。

It starts with an aldol-type condensation in which a solution of the now commercially available E -[3-(4-fluorophenyl)-1-(1-methylethyl)-1 H-indol-2-yl]-2-propenal, 4 , 5 in THF is added to the preformed sodium-lithium salt of tert -butyl acetoacetate 5 at room temperature in THF.

它从一个醛型缩合其中一个解决现在的电子商业可-[3-(4-fluorophenyl)-1-(1-methylethyl)-1吲哚-2-基]-2-丙烯醛、4,5年增加了预四氢呋喃钠-锂盐叔丁基乙酰四氢呋喃在常温5。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料,经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2,3,5,6-四氟苄醇,甲基苄醇与-(1RS,3RS)-3-(2-氯-3,3,3-三氟丙-1-丙烯基)-2,2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

Keywords isopropenyl acetate;acetyl acetone;vapor-liquid equilibrium

乙酸异丙烯酯;乙酰丙酮;汽液相平衡

Some aqueous catalysis systems have been applied in the industrial production of butyl aldehyde by propene hydroformylation.

其中水溶性催化剂体系已经用于丙烯氢甲酰化反应制备丁醛的工业化生产,然而,长链烯烃在含有催化剂的水相中溶解性较差,反应速率较慢。

The result of potassium malonyloxyborohydride as a new hydroboration reagent reacts with terminal alkenes and alkynes is described.

介绍新的硼氢化试剂丙二酰氧基硼氢化钾与链端烯炔烃的作用,烯烃的硼氢化物在PTC条件下,插入∶CCl2 ,可得饱和羧酸;炔烃则难以与之硼氢化。

Malonyloxyborohydride,a hydroboration reagent,is prepared by reaction of malonic acid and sodium borohydride,and is used to react with dihydromyrcene in THF.

用一种硼氢化试剂———丙二酸与硼氢化钠反应生成的丙二酰氧基硼氢化钠在THF中与二氢月桂烯反应制备香茅醇。

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We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称;三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起,称之为挽歌体诗人或者史诗诗人,他们被称为诗人,似乎只是因为遵守格律写作,而非他们作品的模仿本质。

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这不是纸上谈兵式的交易,这是人与人的业务,而且涉及金额巨大。