丙烯酰

From 3-chloropropene bycondensation with sodium ethylate in ethanol to form 3-ethoxypropene followed by anti-Markovnikov addition with HBr inthe presence of benzoyl peroxide.

3-氯丙烯与乙醇钠在乙醇中回流制得3-乙氧基丙烯，继而在过氧苯甲酰存在下，与溴化氢经反马氏加成制得1-溴-3-乙氧基丙烷，总收率89。

ABSTRACT Immobilized penicillin acylase (from E.coli) was used to catalyze 7 phenylacetamido 3 E propenyl cephalosporanic acid hydrolyzation into 7 amino 3 E propenyl cephalosporanic acid. Then, trans APRA was acylated with hydroxyethyl ester of 4 hydroxy D phenylglycine to obtain trans cefprozil.

以7 苯乙酰氨基 3 E 丙烯基 3 头孢菌素 4 羧酸为原料，在青霉素酰化酶作用下，首先酶法水解得到3 E 丙烯基 3 头孢菌素 4 羧酸，过滤固相酶，滤液调pH分离得到反式APRA固体；在青霉素酰化酶作用下，反式APRA再与对羟基苯甘氨酸乙二醇酯缩合，得到反式头孢丙烯；酶法合成所得的产品与进口反式头孢丙烯对照品一致。

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

The synthesis of divinyl liquid crystalline monomer 4-undecenyloyloxybenzoyl-4'-allyloxybenzoyl-p-benzenediol bisate and network polymers was described. The chemical structures of the synthesized monomer and network polymers were confirmed by FT-IR spectrum.

以双烯类液晶单体4-十一烯酰氧基苯甲酸-4'-烯丙氧基苯甲酸对苯二酚双酯为交联剂，通过与聚矽氧烷接枝反应，合成了系列网络聚合物P1~P5。

In order to supply basic thermodynamic data for the separation design of acetyl acetone from the isomerization reaction of isopropenyl acetate,vapor-liquid equilibrium data of isopropenyl acetate-acetyl acetone system under 101.3 kPa was measured using Ellis equilibrium still.

为了给乙酸异丙烯酯异构化生产乙酰丙酮工艺的产物分离设计提供基础热力学数据，用埃利斯平衡蒸馏器测定了101.3 kPa下乙酸异丙烯酯-乙酰丙酮体系的汽液平衡数据，结果表明，该二元体系未形成共沸物，实验数据通过了Herrington面积法的热力学一致性检验。

A concentration of 2.5 micrograms per millilitre was effective at reducing the acrylamide-induced ROS production, as well as the preventing the fragmentation of DNA, and effects of cytotoxicity, report Cao and co-workers.

曹及其同僚表示，浓度为2.5微克/毫升的姜黄色素就能有效的减少由丙烯酰胺引起的活性氧自由基的产生，从而可以防止DNA的裂解，同时有效阻止细胞毒素。

The company has also developed two kinds of non-acrylamide polymer and mineral oil products.

该公司还开发了两种非丙烯酰胺聚合物和矿物油产品。

High absorption and retentions clinoptilolite /Starch/ PAANa composite was synthesized by water-solution copolymerization with clinoptilolite and acrylic acid as principal raw materials,with N N-methylene-bis-acrylamideand as crosslinker, and with potassium persulphate as initiator .

以丙烯酸、斜发沸石为主要原料，以N，N'-亚甲基双丙烯酰胺为交联剂、过硫酸钾为引发剂，采用水溶液聚合法合成了斜发沸石/淀粉/聚丙烯酸高吸水保水性复合材料。

This paper discuss the method and application of polyacrylamide modified by starch, cellulose, chitin respectively.

本文综述了用淀粉、纤维素、壳聚糖这三种天然高分子改性丙烯酰胺的研究和应用情况。

The control group were injected peritoneal physiological saline injection.Three study groups were injected acrylamide solution 5 mg.kg-1.d-1,30 mg.kg-1.d-1,and 60 mg.kg-1.d-1,respectively.On the 5th day,brains of each group were taken out quickly,fixed by Zamboni fixation solution,made into conventional freezing moviemaking,stained by immunohistochemistry staining,and then observed by light microscope.

对照组小鼠腹腔注射生理盐水；实验组小鼠分别代以5 mg·kg-1·d-1、30 mg·kg-1·d-1、60 mg·kg-1·d-1丙烯酰胺水溶液腹腔注射。5 d时分别处死各组小鼠，取出大脑，Zamboni固定液固定，常规冰冻制片，免疫组织化学染色，光镜观察。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。