丙烯腈

The results show that by providing wastewaters pH of about 3 and reaction time of 2 hours, the quantity of H2O2 of 40 mL/L, the concentration of ferrous iron is 0.4 g/L, the effluent of microelectrolysis goes into Biological contact oxidation process, in which DO, HRT and volume load are 4.5 mg/L, 10 hours and 1.0 kg CODCr/(m3·d) respectively, satisfying the first grade of the national standard.

结果表明，在废水pH值为3左右、反应时间2 h的前提下，双氧水投加量40 mL/L，二价铁离子质量浓度为0.4 g/L，再经过微电解处理后的出水进入接触氧化阶段。在溶解氧为4.5 mg/L左右，水力停留时间为10 h、容积负荷1.0 kg CODCr/（m3·d）左右的条件下，出水CODCr小于100 mg/L，可达到国家对丙烯腈废水处理要求的一级标准。

The experiment results show that the yield of hexane catalyzed by the nano-fibrous catalyst was 4.7 times higher than that of PdCl_2/γ-Al_2O_3 catalyst. The hydrogenation ofα-tetradecylene, cyclohexene, nitrobenzol and styrene by the nano-fibrous catalyst was also studied, the selectivity to primary products of the hydrogenation of cyclohexene, nitrobenzol and styrene was 100%.

苯乙烯-丙烯腈共聚物负载纳米钯超细纤维形态催化剂在常温，氢气压力101.3Pa下催化α-己烯加氢时表现出很高的活性，催化剂PSAN-Pd10催化氢化α-己烯选择生成正己烷的产率在150 min就达到87%以上，与无机物负载的催化剂相比，加氢效果有显著提高，并且催化剂的重复使用性较好。

N,N '- ditertbutyl nitroxyl radical, 2, 2,6,6- tetramethyl-4 - hydroxyl piperdinehy droxylamine and its nitroxyl radical, as inhibitors of the BPO- initiated copolymerization of styrene (M 1 ) with acrylonitrile (M2 ), at 60℃,has been studied.

研究了二叔丁基羟胺，二叔丁基氮氧自由基，2，2，6，6－四甲基－4－羟基哌啶羟胺和2，2，6，6－四甲基－4－羟基哌啶－1－氧自由基对过氧化苯甲酰60℃引发的苯乙烯（M1）－丙烯腈（M2）共聚合的阻聚行为。

The graft polymerization of acrylonitrile on Crosslinked polyvinyl alcohol microspheres CPVA microspheres was performed by using cerium ammonium sulfate as initiator, and grafted microspheres CPVA-g-PAN were prepared. Subsequently, the grafted PAN was converted into poly via amidoximation reaction with hydroxylamine hydrochloride as reagent, resulting in the functional microspheres CPVA-g-PAO. The chemical structure and physicochemistry characters were adequately characterized with infrared spectrum, scanning electron microscope and determining Zeta potential. The effects of main factors on the amidoximation transform reaction of the grafted PAN were researched with emphasis, and the adsorption property of the functional microspheres CPVA-g-PAO for some biomolecules was examined preliminarily with uric acid as a model biomolecule.

以硫酸铈铵为引发剂，实施了丙烯腈在交联聚乙烯醇微球表面的接枝聚合，制备了接枝微球CPVA-g-PAN，然后以盐酸羟胺为试剂，通过偕胺肟化转变，将接枝的PAN转变为聚偕胺肟，制得了接枝有聚偕胺肟的功能微球CPVA-g-PAO，采用红外光谱法、扫描电子显微镜及Zeta电位测定等法，对功能微球CPVA-g-PAO的化学结构及物理化学特性进行了表征，重点考察了各主要因素对接枝PAN的偕胺肟化转变反应的影响，也以脲酸为模型分子，初探了功能微球CPVA-g-PAO对生物分子的吸附性能。

The research of polymer/layered silicate nanocomposite was introduced detailedly, including the classify, property and the latest research advance. On the basis of consulting the document and the exploratory experiment, the experimental method which first creative preparing poly (acrylonitrile-vinyl acetate)/raontmorillonite nanocomposite by emulsion intercalation copolymerization was established; the structure and property of polyacrylonitrle different molecule weight with inorganic mineral super fine nanocomposite was reseached. The reaction principle of PMMA by photo-initution was explored. The mixture principle with productor condition, property of PE/Clay nanocomposite milt insert was seal prived. By PS/Clay nanocomposite munufacture, the monomer ins-polymerization and polymerial solution was proved.

在查阅文献和探索性实验的基础上，确定采用乳液原位插层聚合方法首先创制了聚/蒙脱土纳米复合材料，利用正交实验得出了最佳实验条件，通过X射线衍射和红外光谱对纳米复合材料的结构进行表征，研究了复合材料的溶解性能，并测定了其溶液的绝对粘度；研究了不同相对分子质量的聚丙烯腈与不同的无机矿物超细粉复合材料的结构与性能；探讨了在蒙脱土中光引发聚甲基丙烯酸甲酯的反应机理；通过聚乙烯与粘土的纳米复合材料制备，探讨了热塑性树脂熔融插层复合机理与最佳工艺条件和复合材料性能关系；通过聚苯乙烯与蒙脱土纳米复合材料制备，验证了单体原位聚合插层和聚合物溶液插层机理。

When introduced the ultrasound into EHD of acrylonitrile, the yield of propionitrile is increased, but the yield of hydrotrimer is decreased as compare to the silent condition.

对丙烯腈电化学氢化二聚反应生成己二腈的体系中施加超声的结果表明，对这一后置化学反应的体系，超声可以改变反应的机制，并最终对电解产物的分布产生影响。

Proton exchange membranes based on polyacrylonitrile /silica composites doped with heteropolyacids such as phosphotungstic acid or silicotungstic acid were prepared by sol-gel method.

采用溶胶－凝胶法制备了杂多酸掺杂聚丙烯腈－二氧化硅(PAN-SiO2)复合质子交换膜，并研究了其质子导电性能、保水能力和抗化学氧化性能。

The copolymerizations of vinyl sulphone dyes with acrylonitile were carried out in the media of water and DMF, and in an emulsion system.

对乙烯砜型染料在较高浓度下与丙烯腈在沉淀、溶液、乳液等不同体系中的共聚反应进行了研究。

In the third chapter, the photoabsorption of NO, CO, acetonitrile, acrylonitrile, benzene and toluene of benzene series have been measured by using a homemade experimental apparatus of cylindrical multi-stage ion chamber with high flux SR source. The ionization energies of some electron states are given. Their superexcited states, autoionization Rydberg states have been analyzed. By the analysis and comparison, our results are accurate and credibility.

在第三章中，利用高通量的同步辐射光源和自制的多级光电离吸收池装置，测量了NO、CO、乙腈、丙烯腈、苯系物中的苯和甲苯的光吸收谱，给出了部分电子态的电离能，分析了其中的自电离Rydberg态结构和一些振动能级，对部分结构做了精确指认，经过分析和比较，我们所得的结果比较精确和可靠。

The results from property measurements showed that the mould resistance of the blended polyurethane was much better than that of unblended ones.

对该共混物进行的性能测试结果表明，聚氨酯与聚丙烯腈共混以后，其抗霉性有显著提高。

What would he tell Judith and the children?

他将怎样告诉朱迪丝和孩子们呢？

I this is at that time, the opinion with peacockish true girl is full of in a heart.

这就是当时的我，一个心中布满虚荣的女孩子真实的想法。