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丙烯腈

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Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明,催化剂中吡啶衍生物配体越易解离,其初活性越高,催化活性越好。

Cloud point curves from light scattering experiment verify the calculation results;The agreement between the cloud point curve s and the binodal is quite well.

用浊点测定、傅里叶变换红外光谱和微差扫描热分析等方法研究了苯乙烯-顺丁烯二酸酐共聚物与苯乙烯-丙烯腈共聚物共混物的相容性。

The influence of microwave radiation on Ullmann reaction has been investigated by three Ullmann reactions, including triphenylamine formed by treating the diphenylamine with bromobenzene or Chlorobenzene which substitutes Iodobenzene; 4,4\'-dimethyltriphenylamine formed by treating 4,4\'-dimethyldiphenylamine with bromobenzene which substitutes Iodobenzene; 4,4\',4-trinitrotriphenylamine formed by treating 4-chloronitrobenzene with p-nitroaniline in this paper.

实验表明,在微波辐射条件下,顺式比反式迈克尔反应活性高;若在丁烯二酸的双键上引入甲基后,降低了进行迈克尔加成反应的活性;引入酯基对双键的影响比腈基有利于进行迈克尔反应,丙烯酸甲酯较丙烯腈的迈克尔反应活性高。

Grafting polymerization of acrylic acid onto flax initiated by ceric salt has been studied.

研究了利用铈盐引发丙烯腈与亚麻接枝共聚反应。

By using ceric ammonium nitrate as the initiator, a superabsorbent polymer was prepared from graft copolymer of corn starch and acrylonitrile.

用硝酸铈铵作引发剂,通过水溶液聚合法制得了玉米淀粉接枝丙烯腈高吸水性树脂。

Use: The solvent, colored cinefilm develop pharmaceutical to use as reeling off raw silk from cocoons with polyacrylonitrile fiber, chemical analysis reagent, make plant take off leaf pharmaceutical and herbicide that weed, and rubber industry make rubber deal with pharmaceutical, electroplate industry formulate, plate nickel electroplate liquid.

用作聚丙烯腈纤维抽丝溶剂、彩色电影胶片冲洗剂,化学分析试剂,制造植物脱叶剂和除草的除莠剂,以及橡胶工业作橡胶处理剂、电镀工业配制镀镍电镀液。

N-p-tolylmaleimide is a kind of monomer to copolymerize with MMA to enhance the thermal stabilities of PMMA.In this article, NPTMI was prepared from the reaction of maleic anhydride and p-toluidine in one stage, which was testified by FTIR. The mp. of NPTMI was 154 and consistent with the literature.

目前国外对这方面的研究比较成熟,国内研究的较少,且还没有对N-对甲基苯基马来酰亚胺、MMA和第三单体丙烯腈或苯乙烯共聚以制备耐热PMMA树脂及其性能的研究。

Various mole ratios of acrylonitrile and methyl methacrylate were used to copolymerize in aqueous solution by Redox and the copolymers were obtained. The copolymers containing MOCT were synthesized by adding MOCT before copolymerization. The copolymer were derived from the copolymerization of AN and MMA in 30L kettle and then were mixed with various contents of MOCT, the copolymer films were cast by solution of the copolymer containing MOCT.

本课题采用不同摩尔比的丙烯腈和甲基丙烯酸甲酯进行水相沉淀聚合,制备了AN/MMA共聚物;在聚合阶段加入正十八烷微胶囊,制得了正十八烷微胶囊含量不同的共聚物;选择合适的条件进行大釜聚合,得到共聚物后与不同比例的正十八烷微胶囊混合,通过流延制得正十八烷微胶囊含量不同的共聚物膜;并尝试进行了纺丝实验。

Polyacrylonitrile fibers ; Pre-oxidization ; Crystallitic structure

丙烯腈纤维;预氧化;微晶结构

Good thermal stability, High mechanical strength.Used as catalyst or catalyst carrier in the manufacturing of the important industrial products, such as cyanuramide, benzene anhydride, maleic acid anhydride, butadiene rubber, acrylic nitrite, etc.

用途:本产品在三聚氰胺、苯酐、顺丁烯二酸酐、顺丁橡胶、丙烯腈等重要工业品生产中用作催化剂及催化剂载体,也广泛用于石化产品的精制脱除芳烃,也可用于有机气体、液体的选择性吸附分离及离子交换脱除水中多价有害元素等。

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