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丙烯腈-丁二烯-苯乙烯

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KF/NaZnPO4 was used as the catalyst for Michael addition reaction of ethyl acetoacetate and acrylonitrile.

以磷酸锌钠负载KF为催化剂,催化乙酰乙酸乙酯与丙烯腈进行Michael 加成反应。

chelating fiber with amidoxime group, synthesis, structure, property

第二种合成路线得到的偕胺肟基纤维氰基转化率可到100%,但合成路线要经过引发剂引发、丙烯腈单体接枝两步之后,才能进行偕胺肟化。

Chelate fiber with amidoxime group,which is obtained from chemical modification of PAN fiber,is treated with mercury nitrate to prepare anion-exchange fiber.The optimum conditions of the anion-exchange fiber absorption of the thiocyanate ion,such as ion concentration,time,the pH value were studied.

以聚丙烯腈纤维进行NH2OH化学改性制得的含有偕胺肟基的螯合纤维为原料,经Hg(NO3)2化学处理,制得阴离子交换纤维;并以硫氰酸根离子为研究对象,系统地探讨和研究了阴离子交换纤维吸附硫氰酸根离子的最佳条件参数:离子浓度、时间、pH值等。

The yield was 84%. With OP-10, NPE as the the catalyzer for the diazo reaction, the use of hydrolyzed propenenitrile instead of propenoic acid, and OP-10 as the catalyzers of the aminate reaction, these experiments showed the feasibility of industralization, due to the much reduced costs, shortened reaction time and a higher yield.

采用壬基酚聚氧乙烯醚(OP-10)、萘磺酸甲醛缩合物作重氮化反应催化剂,丙烯腈加成、水解替代丙烯酸,OP-10做氨化反应催化剂,通过四因子三水平正交试验法实验,得到较佳反应参数,反应时间、收率、成本都大大降低,适宜工业化生产。

The PVp-4 show a two-peak phenomena in melting process indicating every polymer consists of two components with different thermal property.〓CNMR spectrums embody a atactic chain structure.

在对催化4-乙烯基吡啶和丙烯腈的均聚合研究中,考察了新型催化剂中Ti/Co配比、β-二酮种类以及助催化剂、溶剂种类、载体化方法等因素在不同反应条件下对聚合的影响。

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中,2-甲基吡啶配位的钌卡宾配合物62的催化活性最高,在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1);催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明,催化剂中吡啶衍生物配体越易解离,其初活性越高,催化活性越好。

The influence of microwave radiation on Ullmann reaction has been investigated by three Ullmann reactions, including triphenylamine formed by treating the diphenylamine with bromobenzene or Chlorobenzene which substitutes Iodobenzene; 4,4\'-dimethyltriphenylamine formed by treating 4,4\'-dimethyldiphenylamine with bromobenzene which substitutes Iodobenzene; 4,4\',4-trinitrotriphenylamine formed by treating 4-chloronitrobenzene with p-nitroaniline in this paper.

实验表明,在微波辐射条件下,顺式比反式迈克尔反应活性高;若在丁烯二酸的双键上引入甲基后,降低了进行迈克尔加成反应的活性;引入酯基对双键的影响比腈基有利于进行迈克尔反应,丙烯酸甲酯较丙烯腈的迈克尔反应活性高。

Grafting polymerization of acrylic acid onto flax initiated by ceric salt has been studied.

研究了利用铈盐引发丙烯腈与亚麻接枝共聚反应。

By using ceric ammonium nitrate as the initiator, a superabsorbent polymer was prepared from graft copolymer of corn starch and acrylonitrile.

用硝酸铈铵作引发剂,通过水溶液聚合法制得了玉米淀粉接枝丙烯腈高吸水性树脂。

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