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The method has been used to determine Phthalic esters in drinking water and seawater sample. 3. Single drop microextraction, followed by gas chromatography with flame ionization detection has been applied to determine Formaldehyde, Acetaldehyde and Acraldehyde in water based on 2,4-Dinitrophenylhydrazine derivatization. Extraction solvent, extraction time and stirrer speed were optimized. Optimal experimental conditions were as follows: 1.6μL toluene microdrop exposed for 30 min in a 3ml aqueous sample placed in 4ml vial and stirred at 600 rpm/min.

以2,4-二硝基苯肼衍生,单滴液相微萃取与气相色谱火焰光度检测器联用测定水样中的甲醛、乙醛、丙烯醛,考察了萃取溶剂、液滴大小、萃取时间、搅拌速度、盐效应等对该方法的影响,并对影响液相微萃取的各种因素进行了系统的阐述,确定了该体系的最佳实验条件,实现了甲醛、乙醛、丙烯醛的提取和富集。

Methacrylic acid-acraldehyde/ montmorillonite nanocomposites were prepared using Na+- montmorillonite via in-situ polymerization of methacrylic acid and acraldehyde in aqueous medium.

采用水溶性聚合单体甲基丙烯酸和丙烯醛在钠基蒙脱土层间直接原位插层聚合制备水溶性MAA-AL/MMT纳米复合材料,通过XRD和TEM对纳米复合材料的结构进行表征,采用TGA、DSC研究了纳米复合材料的热性能,同时考察了甲基丙烯酸与丙烯醛配比及体系pH值对纳米复合材料结构及应用性能的影响。

Optimization of polyester condensation process and reactor design;2. The Structure Characters of the Sulfonated Condensation Polymer Series High Performance;3. The pH value of the solution was adjusted,and the co- condensation reaction was taken place between the hydroxy groups forming transparent organic-inorganic hybrid films on polycarbonate.

以甲基丙烯酰氧基丙基三甲氧基硅烷(KH-570)水解聚合产物作为主要成膜物质,引入正硅酸乙酯水解产物硅溶胶作为无机增强物,调节两种混合溶液pH值,利用两者羟基之间的共缩聚反应在聚碳酸酯板表面制备有机/无机复合透明耐磨薄膜;采用TG/DTA、FT-IR、SEM及UV-V IS对成膜过程、薄膜性能与结构进行表征。

Template copolymerization of acrylamide with acylic acid was carried out in the presence of polyallylammonium chloride as matrix in aqueous solutions.The various influences on the rate of polymerization were studied by dilatometer and electrical conductivity measurements.

丙烯酰胺和丙烯酸模板共聚合是以聚烯丙基氯化铵模板存在下,在水溶液中进行,在这体系中,模板PAAC和单体AA有很强的相互作用,而单体AM与模板则没有作用。

In this paper the surface charge density of cationic kraft pulp was chosen as response variable and the preparation conditions of cationic kraft pulp by the in-situ grafting copolymeration of acrylamide and cationic monomer, [2- ethyl] trimethyl-ammonium chloride were optimized by central composite design.

摘 要:以阳离子硫酸盐浆的表面电荷密度为评价指标,采用中心复合设计法对丙烯酰胺和甲基丙烯酰氧基乙基三甲基氯化铵接枝共聚制备阳离子硫酸盐浆的工艺进行了优化。

According to the properties of acrylic acid series polymer of scale inhibition. A kind of amphiprotic tercopolymer of acrylic acid, acrylamide and dimethyldiallylammonium chloride is synthesised, with water as solvent, persulfate and hypophosphate as initiator. Through the tests, the copolymer can show the good scale inhibiting effect and bactericidal action, and become a multifunctional scale inhibition.

本研究根据丙烯酸聚合物阻垢剂的特点,使用过硫酸铵(NH_4_2S_2O_8、次亚磷酸钠(Na_2PO_3)构成的氧化——还原型引发剂,水为溶剂,合成了新型可用于处理工业循环冷却水的丙烯酸—丙烯酰胺—二甲基二烯丙基氯化铵两性型三元共聚物。

Pyrene has been used as a fluorescence probe to investigate the associative behaviors of hydrophobically modified water-soluble terpolymers Poly(acrylamide/sodium acrylate/octylacrylamide) \[P(AM/NaAA/C_8AM)\].

采用胶束共聚共水解方法合成疏水改性水溶性聚合物聚(丙烯酰胺/丙烯酸钠/N 辛基丙烯酰胺)[P(AM/NaAA/C8AM)],并以芘为荧光探针,应用稳态荧光光谱法研究了它的疏水缔合行为。

In searching for novel and high active fungicides with pyridyl moiety, with Dimethomorph as a model compound and isonicotinic acid as the main starting material, twenty-seven title compounds were designed and synthesized through chlorination, Friedel-Crafts acylation, Wittig-Horner reaction and other steps. All the target structures were confirmed via 1H NMR and elementary analysis.

为了寻找具有高活性的含吡啶杂环杀菌剂,以烯酸吗啉为模板化合物,以异烟酸为起始原料,通过卤代反应、Friedel-Crafts酰基化反应、Wittig-Homer反应等,将吡啶-4-基或2-氯吡啶-4-基引入到模板结构中,设计合成了27个4-[3-(吡啶-4-基)-3-取代苯基丙烯酰]吗啉类化合物,其结构通过1H NMR和元素分析确证。

A series of tri-block copolymers of styrene/tetradecyl methyl acrylate/3-methacryloxyl-propyl thimethoxyl silane was synthesized by atom transfer radical polymerization. The structures of those copolymers were characterized by means of gel permeation chromatography, infrared spectrum, and nuclear magnetic resonance (1H-NMR). Effect of tri-block copolymers on the mechanical properties of glass fiber/polypropylene composites was also investigated.

采用原子转移自由基聚合法合成了一系列新的三嵌段共聚物大分子偶联剂聚苯乙烯-b-聚甲基丙烯酸十四酯-b-聚3-甲基丙烯酰氧基丙基三甲氧基硅烷,通过凝胶渗透色谱、红外光谱和核磁共振(1H-NMR)证实了其结构,并研究了其对玻璃纤维/聚丙烯复合材料力学性能的影响。

MS results revealed that 3- propionaldehyde was transferred into 3- propanol, 3- propanoic acid, 3 ethanol, 3- timonacic.

质谱鉴定其转化产物有甲硫基丙醇、甲硫基丙酸、甲硫基乙醇、甲硫基丙烯。

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