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B3LYP/6-311++G** calculations were carried out to study the trimethylamine catalyzed Baylis-Hillman reaction between acraldehyde and formaldehyde.

采用密度泛函DFT-B3LYP方法在6-311++G**基组下计算研究了三甲胺催化的丙烯醛和甲醛的Baylis-Hillman反应的微观过程,获得了两种反应通道(分别对应于顺式-丙烯醛和反式-丙烯醛)的势能面。

Dimethyldiallylammonium chloride and copolymer comprising DMDAAC and acrylamide have been synthesized from dimethylamine ,allylchloride and AM.

以二甲胺、氯丙烯等为原料合成二甲基二烯丙基氯化铵,再与丙烯酰胺共聚生成共聚物。

A novel liquid crystalline compound named p-phenylenediamine di 4-[2- benzamide] was synthesized from allyl 2-hydroxyethylether, ethyl 4-hydroxybenzoate and p-phenylenediamine.

以乙二醇单烯丙基醚、对羟基苯甲酸乙酯、对苯二胺为原料合成了末端为不饱和双键的芳香聚酰胺溶致型液晶化合物——二对烯丙氧基乙氧基苯甲酰对苯二胺,最佳合成的摩尔比为∶羧酸∶对苯二胺∶吡啶=2。

A salt or ester of carbamic acid, especially one used as an insecticide.

丙烯酰胺、甲代烯丙基磺酸钠等为原料,采用溶液聚合法合成出兼含膦酰基和磺酸基的四元聚合阻垢剂PMAAS,。。。

In this regard, our goal is to develop a glow-discharge method to functionalize titanium surfaces by the covalent immobilization of bioactive organic molecules.

钛金属圆片先以氩气电浆去除表面污染物,来产生可重复取得的清洁表面,接著用丙烯胺电浆处理,使丙烯胺聚合在钛金属表面,再以交链剂戊二醛将白蛋白与丙烯胺的胺基(-NH2)键结。

As a useful fluorinated product,hexafluoropropene trimers can be prepared from hexafluoropropene oligomerization by gas phase-and liquid phase-methods,and many fluorocarbon surfactants such as full-fluoride nonene oxygen benzene sodium can be derived from perfluorinated nonene.

六氟丙烯可通过气相和液相法进行聚合制得六氟丙烯三聚物,即全氟壬烯,全氟壬烯可以进一步衍生出如全氟壬烯氧基苯磺酸钠等多种氟碳表面活性剂,是一种比较有用的含氟产品。

To obtain a flocculant which could effectively remove dyes from dyeing wastewater , the amphoteric polymer was prepared by copolymerization of acrylamide, acrylic acid, cationic monomer and dmethyldiallylammonium chloride or acryloyl oxyethyl trimethyl ammonium chloride.

为制备一种对染色废水有显著脱色效果的絮凝剂,采用溶液聚合法,将两种阳离子单体二甲基二烯丙基氯化铵和丙烯酰氧乙基三甲基氯化铵分别与丙烯酰胺,丙烯酸共聚,合成了两性聚合物。

The copolymer of N isopropylacrylamide and acrylamido azobenzene was synthesized for the study of the effect of the photoisomerization of a water soluble copolymer containing azobenzene groups on the photocontrolled release behavior of liposomes.

为了研究侧链含有偶氮苯基的水溶性共聚物的光异构化对脂质体内包容物的光控释放的影响,设计合成了N-异丙基丙烯酰胺和丙烯酰胺基偶氮苯的共聚物。

A series of pH- and temperature-sensitive hydrogels carrying pendant phosphategroups have been synthesized by copolymerizing 2-methacryloyloxyethyl dihydrogenphosphate with N-isopropylacrylamide. The swelling ratio, swelling and deswellingkinetics have been investigated. High loading percentage of lysozyme into hydrogelshas been achieved and the release profile has been studied.

通过N-异丙基丙烯酰胺和含磷酸基团的单体2-甲基丙烯酰乙氧基二氢磷酸酯的共聚合,合成了一类含磷酸基团的既对温度敏感又对pH敏感的水凝胶,研究了它们在不同pH及温度时的溶胀率及溶胀动力学,并初步研究了其对溶菌酶的释放行为。

A novel polymeric organic thermal stabilizer for PVC was designed and synthesized by acryloylthiourea grafting on polystyrene which was nitrified by HNO3 and then reducted by Sn powder to amine.

以经部分硝化和还原的低分子量聚苯乙烯为母链,利用其胺基和丙烯酰基异硫氰酸酯加成,合成了一种新型有机高分子型PVC 热稳定剂——丙烯酰基硫脲接枝聚苯乙烯,其结构经IR和元素分析表征。

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