丙烯基

Application of 1, 1'-Planar chiral P, N -ligands into palladium-catalyzed allylic substitution

1， 1'-平面手性二茂铁膦氮配体在钯催化烯丙基取代反应中的应用

It afforded a practical method to synthesize chiral allylic amines.

该方法是合成手性烯丙基胺类化合物的一个非常适用方法。

This paper reviews the recent advances in synthesis of chiral allylic amines, mainly discussing the effects of ligands on chemo-and regio-selectivities.

综述了近年来手性烯丙基胺的合成进展，重点介绍了催化剂配体对化学选择性和对映选择性的影响，并阐述了各种类型的反应机理

There were few successful examples of regioselectivity in reactions of unsymmetrically allylic derivatives, and enantioselectivities obtained with prochiral nucleophiles.

因而我们选用反应机理相对比较清楚的钯催化烯丙基取代反应来研究平面手性的作用。

Synthesis and application of 1, 1'-ferrocene P, N -ligands in enatio- and regio-selective palladium-catalyzed allylic substitution reactions

1， 1'-二茂铁膦氮配体的合成及其在不对称区域选择性钯催化烯丙基取代反应中的应用

Allylic side chain was modified to give six bayin analogs in which compound I has a free 7-hydroxy group.

修饰8-位烯丙基侧链，得到了六个黑豆素类似物，共中8的7-位为游离羟基。

Flexibilizing co-monomers were evaluated including both vinyl and allylic types.

Flexibilizing共同单体进行了评价，包括乙烯和烯丙基类型。

This thesis focused mainly on studying the role of planar chirality in asymmetric catalysis, synthesizing novel ferrocene ligands and applying them to palladium-catalyzed allylic substitution reactions.

本论文主要是研究二茂铁平面手性在不对称催化反应中的作用，设计合成新型二茂铁配体及其在钯催化烯丙基取代反应中的应用。

It revealed that the gaseous oxygen was related to the deep oxidation of hydrocarbon, since the breakage of C-C bond in allylic intermediate didn＇t exist during the process of reaction. This is due to the weak ability of lattice oxygen to attack hydrocarbon molecular.

实验结果指出，烃类的深度氧化反应与气相氧的存在有关，晶格氧对烃分子中碳碳键的攻击较弱，反应中烯丙基中间体几乎不发生碳碳键的断裂。

But, there is no an example of the application of allylsamarium bromide as a single electron transfer reagent.

我们用不同的方法合成了一系列的卤代酮，考察了这些卤代酮与烯丙基溴化钐试剂的反应。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。