丙烯基

The originalprocedure has subsequently been replaced by milder and more environmentallyfriendly conditions. We tried to alkylate 3,4,5-trimethoxytoluene by2-allylphenylbenzyl ether in the presence of N-bromosuccinimide.

本实验是在溴代琥珀酰亚胺的作用下使2-烯丙基苯基苄基醚产生苄正离子，苄正离子亲电进攻3，4，5-三甲氧基甲苯从而进行傅氏烷基化反应的。

Allyl glycidyl ether was synthesized from allyl alcohol and epichlorohydrin by phase transfer catalysis.

以烯丙醇和环氧氯丙烷为原料，采用相转移催化法，合成了烯丙基缩水甘油醚。

The yield of allyl glycidyl ether can reach up to 96% at 30 ℃ for 3 h at a molar ratio of 1 to 1.5 of sodium allylate to epichlorohydrin.

醚化反应中固体烯丙醇钠与环氧氯丙烷摩尔比为1：1.5，在无水条件下于30℃反应3 h，烯丙基缩水甘油醚的收率达96%以上。

Of these end groups those having an allylic chlorine might be expected to show the highest activity.

在这些端基中，带有烯丙基氯原子的端基活性最高。

For most of the enones and allylic alcohols, the reaction could be completed within several hours with good yields.

反应无需有机溶剂，对于大部分的烯酮和烯丙基醇反应可以在数小时内完成，产率良好。

Then Doripenem came into the market in the July ,2005. We studied the synthesis of Doripemen.Firstly, we synthesized the chemical 2 from the starting material------o-hydroxylphenylacylamine through Reformastky reaction, alkylation, Diekmann reaction, enolization, esterification and etc. Secondly, we synthesized the chemical 3 from L — hydroxylproline through the protection of carboxyl, amidogen and hydroxyl group, reduction by NaBr, SN_2 substitution and Mitsumobu reaction.

我们以水杨酰胺为起始原料，经Reformatsky反应、烷基化、Diekmann环合、烯醇化、酯化等反应合成双环母核2；再从L-羟基脯氨酸出发，经酯化保护羧基、保护氨基、保护羟基、硼氢化还原酯得醇、Sn2取代和Mitsumobu反应等合成巯基侧链3；最后由化合物3经脱保护、水解得硫醇，和化合物2在二异丙基乙基胺的作用下缩合，最后Pd／C催化脱保护，历经16步反应最终得到产物多尼培南。

Moreover, the polymeric arsine palladium(0) complex is an efficient catalyst for the carbonyl allylation of aldehydes and the coupling reaction of aryl halides with terminal alkynes or Grignard reagent.

该聚合物负载的胂钯(0)配合物还是醛的羰基烯丙基化及芳基卤化物与端炔、Grignard试剂的交叉偶联反应的有效催化剂。

Three kinds of novel N-heterocyclic carbene allyl palladium complexes (Catalyst 1, 2 and 3) were synthesized. Norbornene polymerizations were carried out using three catalysts activated with methylaluminoxane in toluene.

研究了以3种N-杂环卡宾螯合烯丙基钯配合物1、2和3为催化剂，甲苯为溶剂，甲基铝氧烷为助催化剂催化降冰片烯的聚合。

This thesis reported the research of carbonyl allylation and benzylation carded out in aqueous media.

该论文主要研究了纯水作为反应介质时，羰基化合物的烯丙基化和苄基化反应。

Thestercoselectivity of the reaction of propargylide was different completely from that of the reactionof telluronium 3-trimethylsilylalltide with α,β-unsaturaled ketones and trans-trimethysilylacetylenyl-l-benzoyleyelopropane derivatives were obtained.

发现这一反应的立体化学与同样条件下含硅烯丙基碲叶立德和α，β-不饱和酮反应的立体化学完全不同，得到的是又式-2-三甲基硅基乙炔基-1-酮基环丙烷衍生物。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。