丙烯基

In this study, we carried out the allylation of anilines with allylic acetates in PEG-H2O system in the presence of palladium as catalyst. N-allylation of anilines was achieved.

在本研究中，我们完成利用钯催化剂，在水及聚乙二醇系统中，使苯胺类和乙酸烯丙酯类进行烯丙基化反应，并探讨各苯胺类反应物之结果。

Compareing with essential oil of the steam distillation method and the bensine solvent extraction method through GC-MS analysis .The result showed that:the essential oil principal constituent extracted by benzine is camphene,a-pinene,bornyl acetate, limonene, 1-methyl-4-(1-methylethyl)-1,4-cyclohexadiene, myrcene, caryophyllene, borneol.

对巴山冷杉针叶水蒸气蒸馏和石油醚萃取所得精油的GC-MS 分析对比研究结果表明：石油醚萃取精油主要成分为：莰烯，a-蒎烯，乙酸龙脑酯，柠檬烯，1-甲基-4-异丙基-1，4-环己二烯，月桂烯，石竹烯，龙脑。

This invention applies mild condition uses substituent group triphenylamine aldehyde or triphenylamine dialdehyde as raw material to react by heating with 2-(5,5-dimethyl-3-vinylcyclohexenyl-2-enylidene)propanedinitrile group to produce the intermolecular charge transfer chromogen with high decomposition temperature, non-coplanar structure, and triphenylamine group.

本发明采用温和的手段，将取代基三苯胺单醛或取代基三苯胺双醛为原料与2-(3，5，5-三甲基环己烯-2-烯亚基)丙二腈共热生成具有高的热分解温度、非共平面空间结构的含三苯胺基团的分子内电荷转移生色团。

Water,caprylic/capric triglyceride,mineral oil,butylene glycol,stearic acid,acetylated lanolin,glycerin,ethylhexyl methoxycinnamate,dimethicone,polyisoprene,triethanolamine,cyclopentasiloxane,butyl methoxydibenzoylmethane,titanium dioxide,persea gratissima oil unsaponifiables,sodium DNA,borago officinalis seed oil,oenothera biennis oil,simmondsia chinensisseed oil,hydrolyzed RNA,tocopheryl acetate,urea,hydrolyzed extensin,retinyl palmitate,sodium hyaluronate,helianthus annuusseed oil,tocopherol,ascorbyl palmitate,ascorbic acid,lanolin alcohol,c12-20 acid peg-8 ester,cyclotetrasiloxane,glyceryl stearate,dimethiconol,ceteareth-20,carbomer,magnesium aluminum silicate,propylene glycol,peg-8,silica,BHT,citric acid,phenoxyethanol,methylparaben,butylparaben,ethylparaben,isobutylparaben,propylparaben,chlorhexidine digluconate

水，辛酸/癸酸三酸甘油酯，矿物油，丁二醇，硬脂酸，乙醯化羊毛脂，甘油，4-甲氧基肉桂酸-2-乙基己基酯，地美司康，聚异戊烯，三乙醇胺，环戊硅氧烷，丁基甲氧基二苯甲醯基甲烷，二氧化钛，酪梨油，DNA 钠盐，琉璃苣種子植物油，月见草油，荷荷巴籽油，水解RNA，醋酸盐维他命E，尿素，水解伸展蛋白，维他命A酯，透明质酸钠，葵花籽油，维生素E，抗坏血酸棕榈酸酯，维生素C衍生物，羊毛脂醇，C12-20 酸 PEG-8酯，环四硅氧烷，甘油硬脂酸，聚二甲基硅氧烷醇，鲸蜡硬脂醇醚-20，卡波姆，硅酸镁铝，丙二醇，聚乙二醇-8，二氧化硅，二丁基羟基甲苯，柠檬酸，苯氧乙醇，羟苯甲酯，羟苯丁酯，羟苯乙酯，羟苯甲酸异丁酯，羟苯丙酯，洗必泰葡萄糖酸盐

A series of 3 - aryl - 3 -( 5,5 - dimethyl - 3 - hydroxy - 2 - cyclohexene - 1 - one - 2 - yl) propanoic ester s were synthesized by reaction between aromatic aldehydes ,5,5- dimethyl -1,3-cyclohexanedione and isopropylidene malonate catalyzed by KF - Al2O3 in alcohols.

在KF-Al_2O_3催化下，将芳香醛3，5-二甲基-1，3-环己二酮及丙二酸亚异丙酯在醇中反应，一锅式合成了一系列的3-芳基-3-(5，5-二甲基-3-羟基-2-环己烯-1-酮-2-基)丙酸酯。

Was applied to the AD reaction of eight olefins in PEG/NMO system according to the protocol of ligand 8. The yields and ees of the diols were 70～90% and 77～96%(except for trans-5-decene and ally naphthyl ether) respectively.

在与8相同的催化反应条件下，手性配体9催化八种烯烃的AD反应得到的化学产率和ee值分别为70～90％和77-96％（反式-5-癸烯和萘基烯丙基醚除外）。

The yields were 67～89% and 61～90% respectively, and the ees were 66～99. 9% and 68～99. 9% respectively (except for trans-5-decene and ally naphthyl ether). With trans-stilbene as the substrate, chiral ligands and OsO〓 could be recovered and reused five times in the AD reaction with high catalytic activity and stereoselectivity.

4在PF〓/NMO体系中，将配体8和10分别用于八种烯烃的AD反应，配体、OsO〓和底物的摩尔比为0.02/0.015/1时，化学产率分别为67～91％和61～90％，ee值分别为66～99.9％和68～99.9％（反式-5-癸烯和萘基烯丙基醚除外）。

A one-step method for the synthesis of aromatic indolizine derivatives byintramolecular 1,5-dipolar cyclization reaction of 2-(2-arylethenyl)pyridinium N-ylidesin the presence of an oxidant has been studied for the first time. In the presence ofelectron-deficient olefins, however, 2-(2-phenylethenyl)pyridinium N-ylides underwent1,3-dipolar cycloadditions and then aromatized in situ by TPCD to produce indolizinederivatives, indicating 1,3-dipolar cycloaddition proceed more readily than 1 ,5-dipolarcyclization in these conditions. Pyridinium disubstituted N-ylides, readily obtainedfrom corresponding pridinium and β-chlorovinyl ketone, underwent thermalintramolecular 1,5-dipolar cyclization to give indolizine derivatives easily.Indolizinecarbaldehyde derivatives were synthesized starting from 2-pyridinecarbaldehyde in four-steps involving 1,3-dipolar cycloaddition reaction.

本文首次研究了2-(2-芳基乙烯基)吡啶N-叶立德在氧化剂存在下的分子内1，5-偶极环化反应，采用一锅法合成了中氮茚衍生物；研究了这些N-叶立德的1，5-偶极环化和1，3-偶极环加成反应的选择性，发现当有缺电子烯烃存在时，优先进行1，3-偶极环加成反应，而不再发生分子内1，5-偶极环化反应；由β-氯乙烯酮方便地得到了烯丙基N-叶立德，他们在加热时进行分子内1，5-偶极环化反应而得到中氮茚衍生物；由2-吡啶甲醛为起始原料，通过1，3-偶极环加成反应等四步反应，得到了重要的中氮茚甲醛衍生物，这些反应都具有条件温和和操作简便的特点，是合成中氮茚衍生物的新方法。

The polymerization of preparing PDA could be impacted by allyl chloride, allyl alcohol and allyl aldehyde. The content of allyl chloride, allyl alcohol and allyl aldehyde in the DMDAAC monomer solution varied from 0mg/kg to 1000mg/kg, their intrinsic viscosity of PDA descended from 10.3dL/g to 8.0dL/g, 6.8dL/g and 8.8dL/g respectively. The polymerization of preparing PDA could be carried out well in the case the content of NaCl, active carbon, yellow residua and low molecular polymer of DMDAAC were less than 10000mg/kg, 1000mg/kg, 1000mg/kg and 50000mg/kg respectively.

单一杂质含量变化对聚合产物PDA特征粘度影响的研究结果表明：在DMDAAC单体溶液聚合反应过程中，当Fe~(3+)、Fe~(2+)和Cu~(2+)含量分别达到7mg／kg、9mg／kg和5mg／kg时无法得到聚合产物PDA胶体；当烯丙基氯、烯丙醇、烯丙醛含量分别从0mg／kg增加到1000mg／kg时，聚合产物PDA的特征粘度从10.3dL／g分别下降到8.0dL／g，6.8dL／g和8.8dL／g；活性炭和黄色物质含量在1000mg／kg以下，低聚物含量在50000mg／kg以下以及氯化钠含量在10000mg／kg以下时产物PDA的特征粘度降低变化量不超过0.2dL／g。

The results indicated the ally1 carbon of cyclohexene was catalytically oxidized by molecular oxygen at atmospheric pressure in the presence of the polymer complex and a trace of HOAc at 70℃, which afforded corresponding alcohol, ketone and hydroperoxide acting as intermediate.

结果表明，70℃时，以微量醋酸为添加剂，在催化剂的催化作用下，以常压氧气氧化环己烯，得到烯丙基位的氧化产物环己烯醇、环己烯酮和中间产物环己烯过氧化氢。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。