丙烯基

Diallyl trisulfide was synthesized with a yield of 76.4% based on sodium thiosulfate, allyl bromide and sodium sulfide. And diallyl tetrasulfide was synthesized by the reaction of sulfur monochloride with ally1 mercaptan with a yield of 81.0%.

以硫代硫酸钠、烯丙基澳和硫化钠为原料，合成了二烯丙基三硫，产率为76.4%；以一氯化硫和烯丙硫醇为原料合成了二烯丙基四硫，产率为81.0%。

Two special structural features of the sulfonium salt were proved to stabilize its corresponding ylide and depress the 2,3-sigma rearrangement. One is that there is a trimethylsilyl in the end of the allylic double band. This silicon atom can stabilize a α-carbon anion and the corresponding ylide. Another is that there is hydroxy group in the beta-position of sulfonium atom. The oxygen of this hydroxy group may stabilize the sulfonium cation.

为了稳定生成的烯丙基硫叶立德，并抑制它的2， 3-sigma 重排反应，在硫叶立德结构上做了两方面的考虑：一是在烯丙基双键的未端引入硅基，利用硅原子对 a -碳负离子的稳定作用来稳定烯丙基硫叶立德；二是在硫原子的 b -位引入羟基，利用羟基氧对硫正离子的作用来稳定硫叶立德。

Chiral homoallylic alcohol was prepared in this paper from asymmetric allylation of aldehyde with enantiomerically pure allylboronate tartramides such as chiral N,N'-diphenyl tartramide and N,N'-di...

本文以手性烯硼酸丙基酒石酸酰胺酯(如烯丙基硼酸-N，N'-二苯基酒石酸酰胺酯)为辅基，进行醛的不对称烯丙基化反应研究。

Because of the rapid development of allylation reaction in aqueous media, allylation reaction mediated by new metal systems or metal systems, and its mechanism are reported increasingly.

水相烯丙基化反应由于其发展速度较快，新的金属及金属体系参与的烯丙基化反应以及水相烯丙基化反应的机理研究不断被报道。

The asymmetric allylation of aldehydes is one of the most important methods for preparation of chiral homoallylic alcohol, which is the building block in organic synthesis of fine chemistry and drugs.

手性烯丙基醇是一类重要医药中间体，合成手性烯丙基醇的常见方法是醛的不对称烯丙基化反应。

E. value of productions were detected by high performance liquid chromatography. Results The chiral aminoalcohol ligand compound Ⅰ can promote the asymmetric allylation of acylhydrazones and the yield was 57%; The highest values of e. e. obtained for this reaction was 22%.

结果 手性氨基醇配体化合物Ⅰ能够促进烯丙基三氯硅烷和酰腙的烯丙基化加成反应，在它的辅助作用下，烯丙基化加成产物的产率可达到57%，对映体过量值最高达到22%。

Grasp the electron delocolization theory; be capable of judging the relative stability of allylic and benzylic free radicals and carbocations, know the relative stability of dienes and other multiple unsaturated hydrocarbons; grasp the characteristics for the nucleophilic substitution reactions of allyl halides and benzyl halides, and the addition reactions of conjugate dienes.

掌握电子非定域化理论；能够分析判断烯丙基、苄基自由基和正离子的稳定性和二烯及多重不饱和碳氢化合物的稳定性；掌握烯丙基、苄基卤代物的亲核取代反应特性和共轭二烯的加成反应。

The studies of radiation chemistry of three main components of garlic oil-diallyl sulfide, diallyl ...

本论文分别研究了大蒜油主要成份二烯丙基一硫、二烯丙基二硫和二烯丙基三硫化物乙醇溶液的辐射化学。

The studies of radiation chemistry of three main components of garlic oil-diallyl sulfide, diallyl disulfide and diallyl trisulfide were performed in ethanol.

本论文分别研究了大蒜油主要成份二烯丙基一硫、二烯丙基二硫和二烯丙基三硫化物乙醇溶液的辐射化学。

In this study,diallyl sulfides in garlic powder were identified via the introduction of Ag induced-ionization.

烯丙基硫化物由于弱极性不电离，本实验利用Ag+柱后诱导电离对大蒜粉剂中的含硫化合物进行质谱定性，并以二烯丙基三硫醚为参比，对各种二烯丙基含硫化合物进行定量测定。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。